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EPR investigation of local structure for [Mn(H2O)(6)](2+) cluster in [M(H2O)(6)]XCl6: Mn2+ (M = Zn, Mg, Cd, Ca; X = Pt, Sn) systems at different temperatures
Tian, Wen-Yan1; Kuang, Xiao-Yu1,2; Li, Hui-Fang1; Li, Yan-Fang1; Ying-Li1
Corresponding AuthorKuang, Xiao-Yu(scu_kuang@163.com)
2009-01-22
Source PublicationCHEMICAL PHYSICS LETTERS
ISSN0009-2614
Volume468Issue:4-6Pages:325-329
AbstractA theoretical method for studying the inter-relation between the local structure and EPR spectra is established by diagonalizing the complete energy matrices. For [M(H2O)(6)]XCl6: Mn2+ (M = Zn, Mg, Cd, Ca; X = Pt, Sn) systems, the calculated results demonstrate that the local structures around the octahedral Mn2+ centers in the doped systems are very similar despite of the host crystals being different. Furthermore, it is shown that the EPR zero-field parameter D depends simultaneously on the local structure parameters R and h while (a - F) depends mainly on R, whether the doped systems are at liquid-nitrogen temperature or room temperature. (C) 2008 Elsevier B.V. All rights reserved.
Funding OrganizationNational Natural Science Foundation of China ; Doctoral Education Fund of Education Ministry of China
DOI10.1016/j.cplett.2008.12.036
Indexed BySCI
Language英语
Funding ProjectNational Natural Science Foundation of China[10774103] ; Doctoral Education Fund of Education Ministry of China[20050610011]
WOS Research AreaChemistry ; Physics
WOS SubjectChemistry, Physical ; Physics, Atomic, Molecular & Chemical
WOS IDWOS:000262412100045
PublisherELSEVIER SCIENCE BV
Citation statistics
Cited Times:1[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/99128
Collection中国科学院金属研究所
Corresponding AuthorKuang, Xiao-Yu
Affiliation1.Sichuan Univ, Inst Atom & Mol Phys, Chengdu 610065, Peoples R China
2.Acad Sinica, Int Ctr Mat Phys, Shenyang 110016, Peoples R China
Recommended Citation
GB/T 7714
Tian, Wen-Yan,Kuang, Xiao-Yu,Li, Hui-Fang,et al. EPR investigation of local structure for [Mn(H2O)(6)](2+) cluster in [M(H2O)(6)]XCl6: Mn2+ (M = Zn, Mg, Cd, Ca; X = Pt, Sn) systems at different temperatures[J]. CHEMICAL PHYSICS LETTERS,2009,468(4-6):325-329.
APA Tian, Wen-Yan,Kuang, Xiao-Yu,Li, Hui-Fang,Li, Yan-Fang,&Ying-Li.(2009).EPR investigation of local structure for [Mn(H2O)(6)](2+) cluster in [M(H2O)(6)]XCl6: Mn2+ (M = Zn, Mg, Cd, Ca; X = Pt, Sn) systems at different temperatures.CHEMICAL PHYSICS LETTERS,468(4-6),325-329.
MLA Tian, Wen-Yan,et al."EPR investigation of local structure for [Mn(H2O)(6)](2+) cluster in [M(H2O)(6)]XCl6: Mn2+ (M = Zn, Mg, Cd, Ca; X = Pt, Sn) systems at different temperatures".CHEMICAL PHYSICS LETTERS 468.4-6(2009):325-329.
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