INVESTIGATION OF THE DEFECT STRUCTURE, OPTICAL AND EPR SPECTRA FOR CdS: Ti2+ AND CdSe: Ti2+ CRYSTAL | |
Feng Wen-Lin1; Zheng Wen-Chen2 | |
Corresponding Author | Feng Wen-Lin(wenlinfeng@126.com) |
2009-10-30 | |
Source Publication | INTERNATIONAL JOURNAL OF MODERN PHYSICS B
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ISSN | 0217-9792 |
Volume | 23Issue:27Pages:5325-5331 |
Abstract | The optical spectral band positions and spin-Hamiltonian parameters (g factors g(parallel to), g(perpendicular to) and zero-field splitting D) of CdS: Ti2+ and CdSe :Ti2+ crystals are calculated from the complete diagonalizaion (of energy matrix) method based on a two-spin-orbit parameter model for 3d(2) ions in trigonal symmetry. In the model,both the contribution to spin-Hamiltonian parameters due to the spin-orbit parameter of central 3d(2) ions and that of ligand ions are included. The crystal field parameters used in the calculations are obtained from the superposition model which enables correlation of the optical and EPR spectral data with the defect structure of the studied paramagnetic impurity centers in crystals. From the calculations, the defect structures of Ti2+ centers in CdS: Ti2+ and CdSe: Ti2+ are acquired, the signs of zero-field splittings D are suggested,and the optical band positions and spin-Hamiltonian parameters are explained. The results are discussed. |
Keyword | Optical and EPR spectra crystal- and ligand-field theory defect structure CdS CdSe Ti2+ |
DOI | 10.1142/S0217979209053503 |
Indexed By | SCI |
Language | 英语 |
WOS Research Area | Physics |
WOS Subject | Physics, Applied ; Physics, Condensed Matter ; Physics, Mathematical |
WOS ID | WOS:000272468100008 |
Publisher | WORLD SCIENTIFIC PUBL CO PTE LTD |
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Document Type | 期刊论文 |
Identifier | http://ir.imr.ac.cn/handle/321006/99604 |
Collection | 中国科学院金属研究所 |
Corresponding Author | Feng Wen-Lin |
Affiliation | 1.Sichuan Univ, Dept Mat Sci, Chengdu 610064, Peoples R China 2.Chinese Acad Sci, Int Ctr Mat Phys, Shenyang 110016, Peoples R China |
Recommended Citation GB/T 7714 | Feng Wen-Lin,Zheng Wen-Chen. INVESTIGATION OF THE DEFECT STRUCTURE, OPTICAL AND EPR SPECTRA FOR CdS: Ti2+ AND CdSe: Ti2+ CRYSTAL[J]. INTERNATIONAL JOURNAL OF MODERN PHYSICS B,2009,23(27):5325-5331. |
APA | Feng Wen-Lin,&Zheng Wen-Chen.(2009).INVESTIGATION OF THE DEFECT STRUCTURE, OPTICAL AND EPR SPECTRA FOR CdS: Ti2+ AND CdSe: Ti2+ CRYSTAL.INTERNATIONAL JOURNAL OF MODERN PHYSICS B,23(27),5325-5331. |
MLA | Feng Wen-Lin,et al."INVESTIGATION OF THE DEFECT STRUCTURE, OPTICAL AND EPR SPECTRA FOR CdS: Ti2+ AND CdSe: Ti2+ CRYSTAL".INTERNATIONAL JOURNAL OF MODERN PHYSICS B 23.27(2009):5325-5331. |
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