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Hydrogen sorption kinetics of MgH2 catalyzed with titanium compounds
Ma, Lai-Peng; Wang, Ping; Cheng, Hui-Ming
Corresponding AuthorWang, Ping(pingwang@imr.ac.cn)
2010-04-01
Source PublicationINTERNATIONAL JOURNAL OF HYDROGEN ENERGY
ISSN0360-3199
Volume35Issue:7Pages:3046-3050
AbstractIdentification of effective catalyst is a subject of great interest in developing MgH2 system as a potential hydrogen storage medium. In this work, the effects of typical titanium compounds (TiF3, TiCl3, TiO2, TiN and TiH2) on MgH2 were systematically investigated with regard to hydrogen sorption kinetics. Among them, adding TiF3 leads to the most pronounced improvement on both absorption and desorption rates. Comparative studies indicate that the TiH2 and MgF2 phases in situ introduced by TiF3 fail to explain the superior catalytic activity. However, a positive interaction between TiH2 and MgF2 is observed. Detailed comparison between the effect of TiF3 and TiCl3 additive suggests the catalytic role of F anion. XPS examination reveals that new bonding state(s) of F anion is formed in the MgH2 + TiF3 system. On the basis of these results, we propose that the substantial participation of F anion in the catalytic function contributes to the superior activity of TiF3. (C) 2009 Professor T. Nejat Veziroglu. Published by Elsevier Ltd. All rights reserved.
KeywordHydrogen storage Kinetics Hydride Catalyst
DOI10.1016/j.ijhydene.2009.07.014
Indexed BySCI
Language英语
WOS Research AreaChemistry ; Electrochemistry ; Energy & Fuels
WOS SubjectChemistry, Physical ; Electrochemistry ; Energy & Fuels
WOS IDWOS:000276692800087
PublisherPERGAMON-ELSEVIER SCIENCE LTD
Citation statistics
Cited Times:62[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/99931
Collection中国科学院金属研究所
Corresponding AuthorWang, Ping
AffiliationChinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China
Recommended Citation
GB/T 7714
Ma, Lai-Peng,Wang, Ping,Cheng, Hui-Ming. Hydrogen sorption kinetics of MgH2 catalyzed with titanium compounds[J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,2010,35(7):3046-3050.
APA Ma, Lai-Peng,Wang, Ping,&Cheng, Hui-Ming.(2010).Hydrogen sorption kinetics of MgH2 catalyzed with titanium compounds.INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,35(7),3046-3050.
MLA Ma, Lai-Peng,et al."Hydrogen sorption kinetics of MgH2 catalyzed with titanium compounds".INTERNATIONAL JOURNAL OF HYDROGEN ENERGY 35.7(2010):3046-3050.
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