Comparative study of EPR spectra and crystal field effect on local structure for (NiF6)(4-) coordination complex in Ni2+:ZnF2, NiF2, and Ni2+:MgF2 systems

doi:10.1002/pssb.200945261

IMR OpenIR

	Comparative study of EPR spectra and crystal field effect on local structure for (NiF6)(4-) coordination complex in Ni2+:ZnF2, NiF2, and Ni2+:MgF2 systems
	Wang, Su-Juan 1; Kuang, Xiao-Yu 1,2; Duan, Mei-Ling 1; Zhang, Cai-Xia 1; Lu, Cheng 1
通讯作者	Kuang, Xiao-Yu(scu_wsj@163.com)
	2010-02-01
发表期刊	PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS
ISSN	0370-1972
卷号	247 期号:2 页码:416-421
摘要	The present work employs the complete energy matrices for a d(8) configuration ion in a D-2h symmetry ligand field at first time to study the relationship between electron paramagnetic resonance (EPR) spectra and local structure of (NiF6)(4-) coordination complex in Ni2+:ZnF2, NiF2, and Ni2+:MgF2 systems, respectively. The crystal field effect on the local structure of the three systems is investigated contrastively by calculating the values of vertical bar partial derivative D'/partial derivative theta vertical bar and vertical bar partial derivative E'/partial derivative theta vertical bar around the (NiF6)(4-) coordination complex. Moreover, the theoretical values of the g factors of Ni2+:ZnF2, NiF2, and Ni2+:MgF2 systems are reported. Simultaneously, the calculated energy levels are in good agreement with the experimental absorption spectra. (C) 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
资助者	National Natural Science Foundation of China ; Education Ministry of China
DOI	10.1002/pssb.200945261
收录类别	SCI
语种	英语
资助项目	National Natural Science Foundation of China[10774103] ; Education Ministry of China[20050610011]
WOS研究方向	Physics
WOS类目	Physics, Condensed Matter
WOS记录号	WOS:000274607500029
出版者	WILEY-BLACKWELL
引用统计	被引频次：5[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/100905
专题	中国科学院金属研究所
通讯作者	Kuang, Xiao-Yu
作者单位	1.Sichuan Univ, Inst Atom & Mol Phys, Chengdu 610065, Peoples R China 2.Acad Sinica, Int Ctr Mat Phys, Shenyang 110016, Peoples R China
推荐引用方式 GB/T 7714	Wang, Su-Juan,Kuang, Xiao-Yu,Duan, Mei-Ling,et al. Comparative study of EPR spectra and crystal field effect on local structure for (NiF6)(4-) coordination complex in Ni2+:ZnF2, NiF2, and Ni2+:MgF2 systems[J]. PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS,2010,247(2):416-421.
APA	Wang, Su-Juan,Kuang, Xiao-Yu,Duan, Mei-Ling,Zhang, Cai-Xia,&Lu, Cheng.(2010).Comparative study of EPR spectra and crystal field effect on local structure for (NiF6)(4-) coordination complex in Ni2+:ZnF2, NiF2, and Ni2+:MgF2 systems.PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS,247(2),416-421.
MLA	Wang, Su-Juan,et al."Comparative study of EPR spectra and crystal field effect on local structure for (NiF6)(4-) coordination complex in Ni2+:ZnF2, NiF2, and Ni2+:MgF2 systems".PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS 247.2(2010):416-421.