EPR studies for [Mn(H2O)(6)](2+) complex in MSnF6 center dot 6H(2)O:Mn2+ ( M = Zn, Co) and Cd(BF4)(2)center dot 6H(2)O:Mn2+ systems at different temperature

doi:10.1016/j.cplett.2010.01.018

IMR OpenIR

	EPR studies for [Mn(H2O)(6)](2+) complex in MSnF6 center dot 6H(2)O:Mn2+ ( M = Zn, Co) and Cd(BF4)(2)center dot 6H(2)O:Mn2+ systems at different temperature
	Li, Ying 1; Kuang, Xiao-yu 1,2; Mao, Ai-jie 1; Li, Hui-li 1; Chai, Rui-peng 1
通讯作者	Kuang, Xiao-yu(scu_kxy@163.com)
	2010-03-05
发表期刊	CHEMICAL PHYSICS LETTERS
ISSN	0009-2614
卷号	487 期号:4-6 页码:307-311
摘要	The relationship between the local structure and EPR spectrum is studied by diagonalizing the complete energy matrices for Mn2+ in a trigonal ligand-field. The results show that the degree of distortion increases with temperature increasing whether it is compressed or elongate distortion, and the distorted tendency of the local structure is different according to the sign of D. Meanwhile, the distortion of Cd(BF4)(2)center dot 6H(2)O:Mn2+ system is more sensitive to temperature than that of ZnSnF6 center dot 6H(2)O:Mn2+ system. Moreover, the EPR parameter D is closely associated with the local structure parameters R and h while (a - F) is mainly concerned with R. (C) 2010 Elsevier B. V. All rights reserved.
资助者	National Natural Science Foundation of China
DOI	10.1016/j.cplett.2010.01.018
收录类别	SCI
语种	英语
资助项目	National Natural Science Foundation of China[10774103] ; National Natural Science Foundation of China[10974138]
WOS研究方向	Chemistry ; Physics
WOS类目	Chemistry, Physical ; Physics, Atomic, Molecular & Chemical
WOS记录号	WOS:000274587900028
出版者	ELSEVIER SCIENCE BV
引用统计	被引频次：6[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/102217
专题	中国科学院金属研究所
通讯作者	Kuang, Xiao-yu
作者单位	1.Sichuan Univ, Inst Atom & Mol Phys, Chengdu 610065, Peoples R China 2.Acad Sinica, Int Ctr Mat Phys, Shenyang 110016, Peoples R China
推荐引用方式 GB/T 7714	Li, Ying,Kuang, Xiao-yu,Mao, Ai-jie,et al. EPR studies for [Mn(H2O)(6)](2+) complex in MSnF6 center dot 6H(2)O:Mn2+ ( M = Zn, Co) and Cd(BF4)(2)center dot 6H(2)O:Mn2+ systems at different temperature[J]. CHEMICAL PHYSICS LETTERS,2010,487(4-6):307-311.
APA	Li, Ying,Kuang, Xiao-yu,Mao, Ai-jie,Li, Hui-li,&Chai, Rui-peng.(2010).EPR studies for [Mn(H2O)(6)](2+) complex in MSnF6 center dot 6H(2)O:Mn2+ ( M = Zn, Co) and Cd(BF4)(2)center dot 6H(2)O:Mn2+ systems at different temperature.CHEMICAL PHYSICS LETTERS,487(4-6),307-311.
MLA	Li, Ying,et al."EPR studies for [Mn(H2O)(6)](2+) complex in MSnF6 center dot 6H(2)O:Mn2+ ( M = Zn, Co) and Cd(BF4)(2)center dot 6H(2)O:Mn2+ systems at different temperature".CHEMICAL PHYSICS LETTERS 487.4-6(2010):307-311.