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EPR studies for [Mn(H2O)(6)](2+) complex in MSnF6 center dot 6H(2)O:Mn2+ ( M = Zn, Co) and Cd(BF4)(2)center dot 6H(2)O:Mn2+ systems at different temperature
Li, Ying1; Kuang, Xiao-yu1,2; Mao, Ai-jie1; Li, Hui-li1; Chai, Rui-peng1
Corresponding AuthorKuang, Xiao-yu(scu_kxy@163.com)
2010-03-05
Source PublicationCHEMICAL PHYSICS LETTERS
ISSN0009-2614
Volume487Issue:4-6Pages:307-311
AbstractThe relationship between the local structure and EPR spectrum is studied by diagonalizing the complete energy matrices for Mn2+ in a trigonal ligand-field. The results show that the degree of distortion increases with temperature increasing whether it is compressed or elongate distortion, and the distorted tendency of the local structure is different according to the sign of D. Meanwhile, the distortion of Cd(BF4)(2)center dot 6H(2)O:Mn2+ system is more sensitive to temperature than that of ZnSnF6 center dot 6H(2)O:Mn2+ system. Moreover, the EPR parameter D is closely associated with the local structure parameters R and h while (a - F) is mainly concerned with R. (C) 2010 Elsevier B. V. All rights reserved.
Funding OrganizationNational Natural Science Foundation of China
DOI10.1016/j.cplett.2010.01.018
Indexed BySCI
Language英语
Funding ProjectNational Natural Science Foundation of China[10774103] ; National Natural Science Foundation of China[10974138]
WOS Research AreaChemistry ; Physics
WOS SubjectChemistry, Physical ; Physics, Atomic, Molecular & Chemical
WOS IDWOS:000274587900028
PublisherELSEVIER SCIENCE BV
Citation statistics
Cited Times:5[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/102217
Collection中国科学院金属研究所
Corresponding AuthorKuang, Xiao-yu
Affiliation1.Sichuan Univ, Inst Atom & Mol Phys, Chengdu 610065, Peoples R China
2.Acad Sinica, Int Ctr Mat Phys, Shenyang 110016, Peoples R China
Recommended Citation
GB/T 7714
Li, Ying,Kuang, Xiao-yu,Mao, Ai-jie,et al. EPR studies for [Mn(H2O)(6)](2+) complex in MSnF6 center dot 6H(2)O:Mn2+ ( M = Zn, Co) and Cd(BF4)(2)center dot 6H(2)O:Mn2+ systems at different temperature[J]. CHEMICAL PHYSICS LETTERS,2010,487(4-6):307-311.
APA Li, Ying,Kuang, Xiao-yu,Mao, Ai-jie,Li, Hui-li,&Chai, Rui-peng.(2010).EPR studies for [Mn(H2O)(6)](2+) complex in MSnF6 center dot 6H(2)O:Mn2+ ( M = Zn, Co) and Cd(BF4)(2)center dot 6H(2)O:Mn2+ systems at different temperature.CHEMICAL PHYSICS LETTERS,487(4-6),307-311.
MLA Li, Ying,et al."EPR studies for [Mn(H2O)(6)](2+) complex in MSnF6 center dot 6H(2)O:Mn2+ ( M = Zn, Co) and Cd(BF4)(2)center dot 6H(2)O:Mn2+ systems at different temperature".CHEMICAL PHYSICS LETTERS 487.4-6(2010):307-311.
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