| EPR studies for [Mn(H2O)(6)](2+) complex in MSnF6 center dot 6H(2)O:Mn2+ ( M = Zn, Co) and Cd(BF4)(2)center dot 6H(2)O:Mn2+ systems at different temperature | |
| Li, Ying1; Kuang, Xiao-yu1,2; Mao, Ai-jie1; Li, Hui-li1; Chai, Rui-peng1 | |
| Corresponding Author | Kuang, Xiao-yu(scu_kxy@163.com) |
| 2010-03-05 | |
| Source Publication | CHEMICAL PHYSICS LETTERS
 |
| ISSN | 0009-2614 |
| Volume | 487Issue:4-6Pages:307-311 |
| Abstract | The relationship between the local structure and EPR spectrum is studied by diagonalizing the complete energy matrices for Mn2+ in a trigonal ligand-field. The results show that the degree of distortion increases with temperature increasing whether it is compressed or elongate distortion, and the distorted tendency of the local structure is different according to the sign of D. Meanwhile, the distortion of Cd(BF4)(2)center dot 6H(2)O:Mn2+ system is more sensitive to temperature than that of ZnSnF6 center dot 6H(2)O:Mn2+ system. Moreover, the EPR parameter D is closely associated with the local structure parameters R and h while (a - F) is mainly concerned with R. (C) 2010 Elsevier B. V. All rights reserved. |
| Funding Organization | National Natural Science Foundation of China |
| DOI | 10.1016/j.cplett.2010.01.018 |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | National Natural Science Foundation of China[10774103] ; National Natural Science Foundation of China[10974138] |
| WOS Research Area | Chemistry ; Physics |
| WOS Subject | Chemistry, Physical ; Physics, Atomic, Molecular & Chemical |
| WOS ID | WOS:000274587900028 |
| Publisher | ELSEVIER SCIENCE BV |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.imr.ac.cn/handle/321006/102217 |
| Collection | 中国科学院金属研究所 |
| Corresponding Author | Kuang, Xiao-yu |
| Affiliation | 1.Sichuan Univ, Inst Atom & Mol Phys, Chengdu 610065, Peoples R China 2.Acad Sinica, Int Ctr Mat Phys, Shenyang 110016, Peoples R China |
| Recommended Citation GB/T 7714 | Li, Ying,Kuang, Xiao-yu,Mao, Ai-jie,et al. EPR studies for [Mn(H2O)(6)](2+) complex in MSnF6 center dot 6H(2)O:Mn2+ ( M = Zn, Co) and Cd(BF4)(2)center dot 6H(2)O:Mn2+ systems at different temperature[J]. CHEMICAL PHYSICS LETTERS,2010,487(4-6):307-311. |
| APA | Li, Ying,Kuang, Xiao-yu,Mao, Ai-jie,Li, Hui-li,&Chai, Rui-peng.(2010).EPR studies for [Mn(H2O)(6)](2+) complex in MSnF6 center dot 6H(2)O:Mn2+ ( M = Zn, Co) and Cd(BF4)(2)center dot 6H(2)O:Mn2+ systems at different temperature.CHEMICAL PHYSICS LETTERS,487(4-6),307-311. |
| MLA | Li, Ying,et al."EPR studies for [Mn(H2O)(6)](2+) complex in MSnF6 center dot 6H(2)O:Mn2+ ( M = Zn, Co) and Cd(BF4)(2)center dot 6H(2)O:Mn2+ systems at different temperature".CHEMICAL PHYSICS LETTERS 487.4-6(2010):307-311. |
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