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Microstructure tuning of epitaxial BaTiO3 (-) (x) thin films grown using laser molecular-beam epitaxy by varying the oxygen pressure
Zhu, Y. L.; Zheng, S. J.; Chen, D.; Ma, X. L.
通讯作者Zhu, Y. L.(ylzhu@imr.ac.cn)
2010-05-03
发表期刊THIN SOLID FILMS
ISSN0040-6090
卷号518期号:14页码:3669-3673
摘要Microstructural properties are found to be variant in the BaTiO3 (- x) films grown on SrTiO3(001) substrate under various oxygen pressures from 2 x 10(-2) Pa to 2 x 10(-5) Pa by laser molecular-beam epitaxy. Transmission electron microscopic studies reveal that the predominant defects in the films change from threading dislocations into (111) planar defects (i.e. stacking faults and nanotwins) by lowering the oxygen pressure. High density of these defects was observed in the BaTiO3 (-) (x) film prepared at the oxygen pressure of 2 x 10(-5) Pa, which shows metallic behavior. The relationships between oxygen pressure, microstructure, and electrical properties are established on the basis of oxygen deficiency. The formation of nanotwins in highly oxygen-deficient BaTiO3 - x epitaxial thin films results from accommodating excess oxygen vacancies induced by lowering oxygen pressure. (C) 2009 Elsevier B.V. All rights reserved.
关键词BaTiO3-x, oxides Thin films, oxygen pressure, {111} twins, microstructure X-ray diffraction Laser molecular beam epitaxy Transmission electron microscopy
资助者Chinese Academy of Sciences ; National Natural Science Foundation of China
DOI10.1016/j.tsf.2009.09.103
收录类别SCI
语种英语
资助项目Chinese Academy of Sciences ; National Natural Science Foundation of China[50871115]
WOS研究方向Materials Science ; Physics
WOS类目Materials Science, Multidisciplinary ; Materials Science, Coatings & Films ; Physics, Applied ; Physics, Condensed Matter
WOS记录号WOS:000278064600013
出版者ELSEVIER SCIENCE SA
引用统计
被引频次:12[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/102587
专题中国科学院金属研究所
通讯作者Zhu, Y. L.
作者单位Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China
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GB/T 7714
Zhu, Y. L.,Zheng, S. J.,Chen, D.,et al. Microstructure tuning of epitaxial BaTiO3 (-) (x) thin films grown using laser molecular-beam epitaxy by varying the oxygen pressure[J]. THIN SOLID FILMS,2010,518(14):3669-3673.
APA Zhu, Y. L.,Zheng, S. J.,Chen, D.,&Ma, X. L..(2010).Microstructure tuning of epitaxial BaTiO3 (-) (x) thin films grown using laser molecular-beam epitaxy by varying the oxygen pressure.THIN SOLID FILMS,518(14),3669-3673.
MLA Zhu, Y. L.,et al."Microstructure tuning of epitaxial BaTiO3 (-) (x) thin films grown using laser molecular-beam epitaxy by varying the oxygen pressure".THIN SOLID FILMS 518.14(2010):3669-3673.
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