| A theoretical study of EPR g factors for the rhombic CuCl64- clusters in (3-chloroanilinium)(8)[CdCl6]Cl-4:Cu2+ crystal | |
| Zhang Dong-Ting1; He Lv2; Yang Wei-Qing1,3; Zheng Wen-Chen1,4 | |
| Corresponding Author | Zheng Wen-Chen(zhengwc1@163.com) |
| 2010-09-01 | |
| Source Publication | PHYSICA B-CONDENSED MATTER
 |
| ISSN | 0921-4526 |
| Volume | 405Issue:17Pages:3642-3644 |
| Abstract | In this paper, the third-order perturbation formulas of EPR g factors g(i) (i=x, y, z) for d(9) ions in rhombic symmetry where the ground state being an vertical bar d(x2-y2)> admixture of and vertical bar d(z2)> states are derived. These formulas are based on a two-spin-orbit-parameter model in which the contributions to g factors due to both the spin-orbit parameter of the central 3d(n) ion and that of ligand ion are included. From these formulas, the g factors g(i) for the rhombic CuCl64- clusters in (3-chloroanilinium)(8)[CdCl6]CL4:Cu2+ crystal are calculated. The calculated values are in good agreement with those obtained by the complete diagonalization (of energy matrix) method and experimental values. Results are discussed. (C) 2010 Elsevier B.V. All rights reserved. |
| Keyword | Electron paramagnetic resonance Crystal and ligand field theory Optical spectrum (3-chloroanilinium)(8)[CdCl6]Cl-4:Cu2+ |
| DOI | 10.1016/j.physb.2010.05.057 |
| Indexed By | SCI |
| Language | 英语 |
| WOS Research Area | Physics |
| WOS Subject | Physics, Condensed Matter |
| WOS ID | WOS:000280897500026 |
| Publisher | ELSEVIER SCIENCE BV |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.imr.ac.cn/handle/321006/102798 |
| Collection | 中国科学院金属研究所 |
| Corresponding Author | Zheng Wen-Chen |
| Affiliation | 1.Sichuan Univ, Dept Mat Sci, Chengdu 610064, Peoples R China 2.Zhejiang Normal Univ, Dept Phys, Jinhua 321004, Peoples R China 3.Chengdu Univ Informat Technol, Dept Opt & Elect, Chengdu 610225, Peoples R China 4.Chinese Acad Sci, Int Ctr Mat Phys, Shenyang 110016, Peoples R China |
| Recommended Citation GB/T 7714 | Zhang Dong-Ting,He Lv,Yang Wei-Qing,et al. A theoretical study of EPR g factors for the rhombic CuCl64- clusters in (3-chloroanilinium)(8)[CdCl6]Cl-4:Cu2+ crystal[J]. PHYSICA B-CONDENSED MATTER,2010,405(17):3642-3644. |
| APA | Zhang Dong-Ting,He Lv,Yang Wei-Qing,&Zheng Wen-Chen.(2010).A theoretical study of EPR g factors for the rhombic CuCl64- clusters in (3-chloroanilinium)(8)[CdCl6]Cl-4:Cu2+ crystal.PHYSICA B-CONDENSED MATTER,405(17),3642-3644. |
| MLA | Zhang Dong-Ting,et al."A theoretical study of EPR g factors for the rhombic CuCl64- clusters in (3-chloroanilinium)(8)[CdCl6]Cl-4:Cu2+ crystal".PHYSICA B-CONDENSED MATTER 405.17(2010):3642-3644. |
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