A theoretical study of EPR g factors for the rhombic CuCl64- clusters in (3-chloroanilinium)(8)[CdCl6]Cl-4:Cu2+ crystal

doi:10.1016/j.physb.2010.05.057

IMR OpenIR

	A theoretical study of EPR g factors for the rhombic CuCl64- clusters in (3-chloroanilinium)(8)[CdCl6]Cl-4:Cu2+ crystal
	Zhang Dong-Ting 1; He Lv 2; Yang Wei-Qing 1,3; Zheng Wen-Chen 1,4
通讯作者	Zheng Wen-Chen(zhengwc1@163.com)
	2010-09-01
发表期刊	PHYSICA B-CONDENSED MATTER
ISSN	0921-4526
卷号	405 期号:17 页码:3642-3644
摘要	In this paper, the third-order perturbation formulas of EPR g factors g(i) (i=x, y, z) for d(9) ions in rhombic symmetry where the ground state being an vertical bar d(x2-y2)> admixture of and vertical bar d(z2)> states are derived. These formulas are based on a two-spin-orbit-parameter model in which the contributions to g factors due to both the spin-orbit parameter of the central 3d(n) ion and that of ligand ion are included. From these formulas, the g factors g(i) for the rhombic CuCl64- clusters in (3-chloroanilinium)(8)[CdCl6]CL4:Cu2+ crystal are calculated. The calculated values are in good agreement with those obtained by the complete diagonalization (of energy matrix) method and experimental values. Results are discussed. (C) 2010 Elsevier B.V. All rights reserved.
关键词	Electron paramagnetic resonance Crystal and ligand field theory Optical spectrum (3-chloroanilinium)(8)[CdCl6]Cl-4:Cu2+
DOI	10.1016/j.physb.2010.05.057
收录类别	SCI
语种	英语
WOS研究方向	Physics
WOS类目	Physics, Condensed Matter
WOS记录号	WOS:000280897500026
出版者	ELSEVIER SCIENCE BV
引用统计	被引频次：13[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/102798
专题	中国科学院金属研究所
通讯作者	Zheng Wen-Chen
作者单位	1.Sichuan Univ, Dept Mat Sci, Chengdu 610064, Peoples R China 2.Zhejiang Normal Univ, Dept Phys, Jinhua 321004, Peoples R China 3.Chengdu Univ Informat Technol, Dept Opt & Elect, Chengdu 610225, Peoples R China 4.Chinese Acad Sci, Int Ctr Mat Phys, Shenyang 110016, Peoples R China
推荐引用方式 GB/T 7714	Zhang Dong-Ting,He Lv,Yang Wei-Qing,et al. A theoretical study of EPR g factors for the rhombic CuCl64- clusters in (3-chloroanilinium)(8)[CdCl6]Cl-4:Cu2+ crystal[J]. PHYSICA B-CONDENSED MATTER,2010,405(17):3642-3644.
APA	Zhang Dong-Ting,He Lv,Yang Wei-Qing,&Zheng Wen-Chen.(2010).A theoretical study of EPR g factors for the rhombic CuCl64- clusters in (3-chloroanilinium)(8)[CdCl6]Cl-4:Cu2+ crystal.PHYSICA B-CONDENSED MATTER,405(17),3642-3644.
MLA	Zhang Dong-Ting,et al."A theoretical study of EPR g factors for the rhombic CuCl64- clusters in (3-chloroanilinium)(8)[CdCl6]Cl-4:Cu2+ crystal".PHYSICA B-CONDENSED MATTER 405.17(2010):3642-3644.