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Spin-Hamiltonian parameters for Dy3+ ion at the trigonal 12-fold coordinated La3+ site of La2Mg3(NO3)(12)center dot 24H(2)O
Yang, Wei-Qing1,2; Zheng, Wen-Chen1,3; Liu, Hong-Gang1
Corresponding AuthorZheng, Wen-Chen(zhengwc1@163.com)
2010-08-01
Source PublicationCRYSTAL RESEARCH AND TECHNOLOGY
ISSN0232-1300
Volume45Issue:8Pages:863-866
AbstractThe spin-Hamiltonian parameters (g factors g(parallel to), g(perpendicular to) and hyperfine structure constants (161)A(parallel to), (161)A(perpendicular to), (163)A(parallel to), (163)A(perpendicular to)) for Dy-161(3+) and Dy-163(3+) isotopes in the trigonal 12-fold coordinated La3+ site of La2Mg3(NO3)(12)center dot 24H(2)O crystal are calculated from a diagonalization (of energy matrix) method. In the method, the Zeeman and hyperfine interaction terms are added to the conventional Hamiltonian used in the studies of crystal-field energy levels, and a 66x66 energy matrix concerning the ground multiplet H-6(15/2) and the first to fifth excited multiplets H-6(13/2), H-6(11/2), H-6(9/2), H-6(7/2) and H-6(5/2) are applied. The calculated results are discussed. (C) 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Keywordelectron paramagnetic resonance crystal-field theory spin-Hamiltonian parameters Dy3+ La2Mg3(NO3)(12)center dot 24H(2)O
Funding OrganizationICMP, CAS
DOI10.1002/crat.201000231
Indexed BySCI
Language英语
Funding ProjectICMP, CAS[ICMP 2009001]
WOS Research AreaCrystallography
WOS SubjectCrystallography
WOS IDWOS:000280674600014
PublisherWILEY-BLACKWELL
Citation statistics
Cited Times:1[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/103012
Collection中国科学院金属研究所
Corresponding AuthorZheng, Wen-Chen
Affiliation1.Sichuan Univ, Dept Mat Sci, Chengdu 610064, Peoples R China
2.Chengdu Univ Informat Technol, Dept Opt & Elect, Chengdu 610225, Peoples R China
3.Chinese Acad Sci, Int Ctr Mat Phys, Shenyang 110016, Peoples R China
Recommended Citation
GB/T 7714
Yang, Wei-Qing,Zheng, Wen-Chen,Liu, Hong-Gang. Spin-Hamiltonian parameters for Dy3+ ion at the trigonal 12-fold coordinated La3+ site of La2Mg3(NO3)(12)center dot 24H(2)O[J]. CRYSTAL RESEARCH AND TECHNOLOGY,2010,45(8):863-866.
APA Yang, Wei-Qing,Zheng, Wen-Chen,&Liu, Hong-Gang.(2010).Spin-Hamiltonian parameters for Dy3+ ion at the trigonal 12-fold coordinated La3+ site of La2Mg3(NO3)(12)center dot 24H(2)O.CRYSTAL RESEARCH AND TECHNOLOGY,45(8),863-866.
MLA Yang, Wei-Qing,et al."Spin-Hamiltonian parameters for Dy3+ ion at the trigonal 12-fold coordinated La3+ site of La2Mg3(NO3)(12)center dot 24H(2)O".CRYSTAL RESEARCH AND TECHNOLOGY 45.8(2010):863-866.
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