Polarized Raman scattering study of blue bronze Tl0.3MoO3 | |
Yin, Di1; Zhang, Qingming2; Oiler, Jonathon3; Li, Changzhen1; Xiong, Rui1; Shi, Jing1,4 | |
通讯作者 | Shi, Jing(niuniuyin@yahoo.com.cn) |
2010-09-01 | |
发表期刊 | PHYSICA B-CONDENSED MATTER
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ISSN | 0921-4526 |
卷号 | 405期号:17页码:3782-3786 |
摘要 | Temperature dependent polarized Raman spectra of quasi-one dimensional blue bronze Tl0.3MoO3 are reported on a frequency range 100-1100 cm(-1). Frequency shift and splitting in some modes were observed, revealing the role of the alkali atom. Many new modes emerge at 170 K accompanied by charge density wave (CDW) formation, and show gradual temperature dependent intensity and line-width, implying the second order nature of CDW transition. A frequency "jump" is found for many Raman vibrational modes in Tl0.3MoO3 near 110 K, confirming that the transition from an incommensurate to commensurate state occurs around this temperature. In addition, only three stretching vibration modes of terminal Mo-O bonds are observed for (xx) polarizations from 800 to 1100 cm(-1) at 300 K; new modes appear only when the temperature drops below 110 K and are ascribed to the splitting of the mode at 931 cm(-1) due to commensurate state formation. (C) 2010 Elsevier B.V. All rights reserved. |
关键词 | Blue bronze Tl0.3MoO3 Charge density wave Raman spectra Transition |
资助者 | Chinese National Foundation of Natural Science ; 973 Program |
DOI | 10.1016/j.physb.2010.05.086 |
收录类别 | SCI |
语种 | 英语 |
资助项目 | Chinese National Foundation of Natural Science[10674105] ; 973 Program[200903939700] |
WOS研究方向 | Physics |
WOS类目 | Physics, Condensed Matter |
WOS记录号 | WOS:000280897500053 |
出版者 | ELSEVIER SCIENCE BV |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.imr.ac.cn/handle/321006/103190 |
专题 | 中国科学院金属研究所 |
通讯作者 | Shi, Jing |
作者单位 | 1.Wuhan Univ, Dept Phys, Key Lab Acoust & Photon Mat & Devices, Minist Educ,Hubei Key Lab Organ & Polymer Optoele, Wuhan 430072, Peoples R China 2.Renmin Univ China, Dept Phys, Beijing 100872, Peoples R China 3.Arizona State Univ, Sch Earth & Space Explorat, Tempe, AZ 85281 USA 4.Chinese Acad Sci, Int Ctr Mat Phys, Shenyang 110016, Peoples R China |
推荐引用方式 GB/T 7714 | Yin, Di,Zhang, Qingming,Oiler, Jonathon,et al. Polarized Raman scattering study of blue bronze Tl0.3MoO3[J]. PHYSICA B-CONDENSED MATTER,2010,405(17):3782-3786. |
APA | Yin, Di,Zhang, Qingming,Oiler, Jonathon,Li, Changzhen,Xiong, Rui,&Shi, Jing.(2010).Polarized Raman scattering study of blue bronze Tl0.3MoO3.PHYSICA B-CONDENSED MATTER,405(17),3782-3786. |
MLA | Yin, Di,et al."Polarized Raman scattering study of blue bronze Tl0.3MoO3".PHYSICA B-CONDENSED MATTER 405.17(2010):3782-3786. |
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