Ultra-thin anatase TiO2 nanosheets dominated with {001} facets: thickness-controlled synthesis, growth mechanism and water-splitting properties

doi:10.1039/c0ce00233j

IMR OpenIR

	Ultra-thin anatase TiO2 nanosheets dominated with {001} facets: thickness-controlled synthesis, growth mechanism and water-splitting properties
	Yang, Xiao Hua 1; Li, Zhen 2,3; Liu, Gang 4; Xing, Jun 1; Sun, Chenghua 2,3; Yang, Hua Gui 1; Li, Chunzhong 1
通讯作者	Yang, Hua Gui(hgyang@ecust.edu.cn)
	2011
发表期刊	CRYSTENGCOMM
ISSN	1466-8033
卷号	13 期号:5 页码:1378-1383
摘要	Ultra-thin anatase TiO2 nanosheets with dominant {001} facets (similar to 82%) and controllable thickness (1.6-2.7 nm) were synthesized by using a modified one-pot hydrothermal route. As a morphology controlling agent, the concentration of hydrofluoric acid has a significant impact on the thickness of the as-synthesized TiO2 nanosheets. In addition, according to the XRD patterns and TEM images of the products on different reaction stages, the growth process of TiO2 nanosheets was clarified for the first time. We further measured the efficiency for H-2 evolution of the ultra-thin anatase TiO2 nanosheets loaded with 1 wt% Pt from photochemical reduction of water in the presence of methanol as a scavenger. The TiO2 nanosheets exhibited a H-2 evolution rate as high as 7381 mu mol h(-1) g(-1) under UV-vis light irradiation, attributing to their exposed reactive {001} facets and high crystallinity.
资助者	Scientific Research Foundation of East China University of Science and Technology ; Science and Technology Commission of Shanghai Municipality ; Education Commission of Shanghai Municipality ; National Natural Science Foundation of China ; Fundamental Research Funds for the Central Universities ; Program for New Century Excellent Talents in University
DOI	10.1039/c0ce00233j
收录类别	SCI
语种	英语
资助项目	Scientific Research Foundation of East China University of Science and Technology[YD0142125] ; Science and Technology Commission of Shanghai Municipality[09PJ1402800] ; Education Commission of Shanghai Municipality[09SG27] ; National Natural Science Foundation of China[20925621] ; National Natural Science Foundation of China[20973059] ; National Natural Science Foundation of China[91022023] ; National Natural Science Foundation of China[21076076] ; Fundamental Research Funds for the Central Universities[WJ0913001] ; Program for New Century Excellent Talents in University[NCET-09-0347]
WOS研究方向	Chemistry ; Crystallography
WOS类目	Chemistry, Multidisciplinary ; Crystallography
WOS记录号	WOS:000287458500018
出版者	ROYAL SOC CHEMISTRY
引用统计	被引频次：195[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/104770
专题	中国科学院金属研究所
通讯作者	Yang, Hua Gui
作者单位	1.E China Univ Sci & Technol, Sch Mat Sci & Engn, Minist Educ, Key Lab Ultrafine Mat, Shanghai 200237, Peoples R China 2.Univ Queensland, ARC Ctr Excellence Funct Nanomat, Sch Engn, Brisbane, Qld 4072, Australia 3.Australian Inst Bioengn & Nanotechnol, Brisbane, Qld 4072, Australia 4.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China
推荐引用方式 GB/T 7714	Yang, Xiao Hua,Li, Zhen,Liu, Gang,et al. Ultra-thin anatase TiO2 nanosheets dominated with {001} facets: thickness-controlled synthesis, growth mechanism and water-splitting properties[J]. CRYSTENGCOMM,2011,13(5):1378-1383.
APA	Yang, Xiao Hua.,Li, Zhen.,Liu, Gang.,Xing, Jun.,Sun, Chenghua.,...&Li, Chunzhong.(2011).Ultra-thin anatase TiO2 nanosheets dominated with {001} facets: thickness-controlled synthesis, growth mechanism and water-splitting properties.CRYSTENGCOMM,13(5),1378-1383.
MLA	Yang, Xiao Hua,et al."Ultra-thin anatase TiO2 nanosheets dominated with {001} facets: thickness-controlled synthesis, growth mechanism and water-splitting properties".CRYSTENGCOMM 13.5(2011):1378-1383.