| INVESTIGATIONS ON THE g FACTORS AND THE SUPERHYPERFINE PARAMETERS FOR THE TETRAGONAL Pd3+ CENTERS IN AgX (X = Cl, Br) | |
| Zhang, Hua-Ming1; Wu, Shao-Yi1,2; Wang, Xue-Feng1; Hu, Yue-Xia1 | |
| Corresponding Author | Zhang, Hua-Ming() |
| 2011-05-20 | |
| Source Publication | INTERNATIONAL JOURNAL OF MODERN PHYSICS B
 |
| ISSN | 0217-9792 |
| Volume | 25Issue:13Pages:1833-1843 |
| Abstract | The g factors and the superhyperfine parameters for the tetragonal Pd3+ centers in AgX (X = Cl, Br) are theoretically investigated from the perturbation formulas of these parameters for a 4d(7) ion in tetragonally elongated octahedra In the calculations, the related molecular or coefficients and the unpaired spin densities of the ligands are determined quantitatively from the cluster approach in a uniform way. Both centers originate from substitutional Pd3+ on Ag+ site in AgX, with no charge compensator (silver vacancy) nearby. The [PdX6](3-) clusters suffer a relative elongation of 0.01 angstrom (or 0.06 angstrom) along [1 0 0] (or C-4) axis for X = Cl (or Br) due to the Jahn-Teller effect The calculated g factors and the superhyperfine parameters based on the above Jahn-Teller elongations show good agreement with the experimental data. |
| Keyword | Electron paramagnetic resonance crystal and ligand fields Pd3+ AgCl AgBr |
| DOI | 10.1142/S0217979211058961 |
| Indexed By | SCI |
| Language | 英语 |
| WOS Research Area | Physics |
| WOS Subject | Physics, Applied ; Physics, Condensed Matter ; Physics, Mathematical |
| WOS ID | WOS:000291310300010 |
| Publisher | WORLD SCIENTIFIC PUBL CO PTE LTD |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.imr.ac.cn/handle/321006/106242 |
| Collection | 中国科学院金属研究所 |
| Corresponding Author | Zhang, Hua-Ming |
| Affiliation | 1.Univ Elect Sci & Technol China, Dept Appl Phys, Chengdu 610054, Peoples R China 2.Chinese Acad Sci, Int Ctr Mat Phys, Shenyang 110016, Peoples R China |
| Recommended Citation GB/T 7714 | Zhang, Hua-Ming,Wu, Shao-Yi,Wang, Xue-Feng,et al. INVESTIGATIONS ON THE g FACTORS AND THE SUPERHYPERFINE PARAMETERS FOR THE TETRAGONAL Pd3+ CENTERS IN AgX (X = Cl, Br)[J]. INTERNATIONAL JOURNAL OF MODERN PHYSICS B,2011,25(13):1833-1843. |
| APA | Zhang, Hua-Ming,Wu, Shao-Yi,Wang, Xue-Feng,&Hu, Yue-Xia.(2011).INVESTIGATIONS ON THE g FACTORS AND THE SUPERHYPERFINE PARAMETERS FOR THE TETRAGONAL Pd3+ CENTERS IN AgX (X = Cl, Br).INTERNATIONAL JOURNAL OF MODERN PHYSICS B,25(13),1833-1843. |
| MLA | Zhang, Hua-Ming,et al."INVESTIGATIONS ON THE g FACTORS AND THE SUPERHYPERFINE PARAMETERS FOR THE TETRAGONAL Pd3+ CENTERS IN AgX (X = Cl, Br)".INTERNATIONAL JOURNAL OF MODERN PHYSICS B 25.13(2011):1833-1843. |
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