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INVESTIGATIONS ON THE g FACTORS AND THE SUPERHYPERFINE PARAMETERS FOR THE TETRAGONAL Pd3+ CENTERS IN AgX (X = Cl, Br)
Zhang, Hua-Ming1; Wu, Shao-Yi1,2; Wang, Xue-Feng1; Hu, Yue-Xia1
Corresponding AuthorZhang, Hua-Ming()
2011-05-20
Source PublicationINTERNATIONAL JOURNAL OF MODERN PHYSICS B
ISSN0217-9792
Volume25Issue:13Pages:1833-1843
AbstractThe g factors and the superhyperfine parameters for the tetragonal Pd3+ centers in AgX (X = Cl, Br) are theoretically investigated from the perturbation formulas of these parameters for a 4d(7) ion in tetragonally elongated octahedra In the calculations, the related molecular or coefficients and the unpaired spin densities of the ligands are determined quantitatively from the cluster approach in a uniform way. Both centers originate from substitutional Pd3+ on Ag+ site in AgX, with no charge compensator (silver vacancy) nearby. The [PdX6](3-) clusters suffer a relative elongation of 0.01 angstrom (or 0.06 angstrom) along [1 0 0] (or C-4) axis for X = Cl (or Br) due to the Jahn-Teller effect The calculated g factors and the superhyperfine parameters based on the above Jahn-Teller elongations show good agreement with the experimental data.
KeywordElectron paramagnetic resonance crystal and ligand fields Pd3+ AgCl AgBr
DOI10.1142/S0217979211058961
Indexed BySCI
Language英语
WOS Research AreaPhysics
WOS SubjectPhysics, Applied ; Physics, Condensed Matter ; Physics, Mathematical
WOS IDWOS:000291310300010
PublisherWORLD SCIENTIFIC PUBL CO PTE LTD
Citation statistics
Cited Times:1[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/106246
Collection中国科学院金属研究所
Corresponding AuthorZhang, Hua-Ming
Affiliation1.Univ Elect Sci & Technol China, Dept Appl Phys, Chengdu 610054, Peoples R China
2.Chinese Acad Sci, Int Ctr Mat Phys, Shenyang 110016, Peoples R China
Recommended Citation
GB/T 7714
Zhang, Hua-Ming,Wu, Shao-Yi,Wang, Xue-Feng,et al. INVESTIGATIONS ON THE g FACTORS AND THE SUPERHYPERFINE PARAMETERS FOR THE TETRAGONAL Pd3+ CENTERS IN AgX (X = Cl, Br)[J]. INTERNATIONAL JOURNAL OF MODERN PHYSICS B,2011,25(13):1833-1843.
APA Zhang, Hua-Ming,Wu, Shao-Yi,Wang, Xue-Feng,&Hu, Yue-Xia.(2011).INVESTIGATIONS ON THE g FACTORS AND THE SUPERHYPERFINE PARAMETERS FOR THE TETRAGONAL Pd3+ CENTERS IN AgX (X = Cl, Br).INTERNATIONAL JOURNAL OF MODERN PHYSICS B,25(13),1833-1843.
MLA Zhang, Hua-Ming,et al."INVESTIGATIONS ON THE g FACTORS AND THE SUPERHYPERFINE PARAMETERS FOR THE TETRAGONAL Pd3+ CENTERS IN AgX (X = Cl, Br)".INTERNATIONAL JOURNAL OF MODERN PHYSICS B 25.13(2011):1833-1843.
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