| Relationships between structures and hydrolytic stability of silazane compounds | |
| Jiang, J; Peng, WQ; Zheng, ZM; Xu, CH; Xie, ZM | |
| Corresponding Author | Xie, ZM() |
| 2002-06-01 | |
| Source Publication | CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
 |
| ISSN | 0251-0790 |
| Volume | 23Issue:6Pages:1189-1192 |
| Abstract | Relationships between structures of a series of silazane compounds and their hydrolytic stability were investigated by contacting silazane compounds directly with water vapor. It was indicated that steric hindrance of substituents strongly influenced hydrolytic stability of silazane compounds. Compounds with bigger substituents had better hydrolytic stability. As for cyclosilazanes, hydrolytic stability was also dependent on ring strength. However, steric hindrance played more dominant roles. Cyclosilazanes with phenyl substituents, hexaphenylcyclotrisilazane and polymeric compounds containing Si-N bond were of excellent hydrolytic stability due to high steric hindrance. |
| Keyword | silazane compound hydrolytic stability steric hindrance ring strength |
| Indexed By | SCI |
| Language | 英语 |
| WOS Research Area | Chemistry |
| WOS Subject | Chemistry, Multidisciplinary |
| WOS ID | WOS:000176272300054 |
| Publisher | HIGHER EDUCATION PRESS |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.imr.ac.cn/handle/321006/115766 |
| Collection | 中国科学院金属研究所 |
| Corresponding Author | Xie, ZM |
| Affiliation | Chinese Acad Sci, Ctr Mat Sci, Inst Chem, Beijing 100080, Peoples R China |
| Recommended Citation GB/T 7714 | Jiang, J,Peng, WQ,Zheng, ZM,et al. Relationships between structures and hydrolytic stability of silazane compounds[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2002,23(6):1189-1192. |
| APA | Jiang, J,Peng, WQ,Zheng, ZM,Xu, CH,&Xie, ZM.(2002).Relationships between structures and hydrolytic stability of silazane compounds.CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,23(6),1189-1192. |
| MLA | Jiang, J,et al."Relationships between structures and hydrolytic stability of silazane compounds".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 23.6(2002):1189-1192. |
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