Relationships between structures and hydrolytic stability of silazane compounds

IMR OpenIR

	Relationships between structures and hydrolytic stability of silazane compounds
	Jiang, J; Peng, WQ; Zheng, ZM; Xu, CH; Xie, ZM
通讯作者	Xie, ZM()
	2002-06-01
发表期刊	CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
ISSN	0251-0790
卷号	23 期号:6 页码:1189-1192
摘要	Relationships between structures of a series of silazane compounds and their hydrolytic stability were investigated by contacting silazane compounds directly with water vapor. It was indicated that steric hindrance of substituents strongly influenced hydrolytic stability of silazane compounds. Compounds with bigger substituents had better hydrolytic stability. As for cyclosilazanes, hydrolytic stability was also dependent on ring strength. However, steric hindrance played more dominant roles. Cyclosilazanes with phenyl substituents, hexaphenylcyclotrisilazane and polymeric compounds containing Si-N bond were of excellent hydrolytic stability due to high steric hindrance.
关键词	silazane compound hydrolytic stability steric hindrance ring strength
收录类别	SCI
语种	英语
WOS研究方向	Chemistry
WOS类目	Chemistry, Multidisciplinary
WOS记录号	WOS:000176272300054
出版者	HIGHER EDUCATION PRESS
引用统计	被引频次：2[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/115766
专题	中国科学院金属研究所
通讯作者	Xie, ZM
作者单位	Chinese Acad Sci, Ctr Mat Sci, Inst Chem, Beijing 100080, Peoples R China
推荐引用方式 GB/T 7714	Jiang, J,Peng, WQ,Zheng, ZM,et al. Relationships between structures and hydrolytic stability of silazane compounds[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2002,23(6):1189-1192.
APA	Jiang, J,Peng, WQ,Zheng, ZM,Xu, CH,&Xie, ZM.(2002).Relationships between structures and hydrolytic stability of silazane compounds.CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,23(6),1189-1192.
MLA	Jiang, J,et al."Relationships between structures and hydrolytic stability of silazane compounds".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 23.6(2002):1189-1192.