| Conjugated polymers with defined chemical structure as model carbon catalysts for nitro reduction | |
| Guo, Xiaoling1,2; Qi, Wei2; Liu, Wei2; Liang, Changhai1; Zheng, Anmin3; Yi, Xianfeng3; Su, Dangsheng2 | |
| Corresponding Author | Su, Dangsheng(dssu@imr.ac.cn) |
| 2016 | |
| Source Publication | RSC ADVANCES
 |
| ISSN | 2046-2069 |
| Volume | 6Issue:101Pages:99570-99576 |
| Abstract | A series of conjugated polymers (YPB-x) with designated chemical structure are synthesized as model carbon catalysts for mechanistic and kinetic studies of nitroaromatic reduction reactions. The reaction kinetics show that ketonic carbonyl groups are active sites for the nitrobenzene (NB) reduction. A catalytic reaction mechanism involving the activation of hydrazine with carbon catalysts and the subsequent reduction of NB is proposed to describe the catalytic process molecularly. The turnover frequency of heterogeneous carbon catalysts in the liquid phase is reported for the fair comparison of the intrinsic activity among different carbon catalysts. |
| Funding Organization | NSFC of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Youth Innovation Promotion Association of CAS |
| DOI | 10.1039/c6ra18201a |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | NSFC of China[21303226] ; NSFC of China[21133010] ; NSFC of China[21573256] ; NSFC of China[51221264] ; NSFC of China[21261160487] ; Strategic Priority Research Program of the Chinese Academy of Sciences[XDA09030103] ; Youth Innovation Promotion Association of CAS |
| WOS Research Area | Chemistry |
| WOS Subject | Chemistry, Multidisciplinary |
| WOS ID | WOS:000387427800121 |
| Publisher | ROYAL SOC CHEMISTRY |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.imr.ac.cn/handle/321006/123154 |
| Collection | 中国科学院金属研究所 |
| Corresponding Author | Su, Dangsheng |
| Affiliation | 1.Dalian Univ Technol, Sch Chem Engn, Lab Adv Mat & Catalyt Engn, Dalian 116024, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 3.Chinese Acad Sci, Wuhan Inst Phys & Math, Natl Ctr Magnet Resonance Wuhan, Wuhan 430071, Peoples R China |
| Recommended Citation GB/T 7714 | Guo, Xiaoling,Qi, Wei,Liu, Wei,et al. Conjugated polymers with defined chemical structure as model carbon catalysts for nitro reduction[J]. RSC ADVANCES,2016,6(101):99570-99576. |
| APA | Guo, Xiaoling.,Qi, Wei.,Liu, Wei.,Liang, Changhai.,Zheng, Anmin.,...&Su, Dangsheng.(2016).Conjugated polymers with defined chemical structure as model carbon catalysts for nitro reduction.RSC ADVANCES,6(101),99570-99576. |
| MLA | Guo, Xiaoling,et al."Conjugated polymers with defined chemical structure as model carbon catalysts for nitro reduction".RSC ADVANCES 6.101(2016):99570-99576. |
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