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Conjugated polymers with defined chemical structure as model carbon catalysts for nitro reduction
Guo, Xiaoling1,2; Qi, Wei2; Liu, Wei2; Liang, Changhai1; Zheng, Anmin3; Yi, Xianfeng3; Su, Dangsheng2
Corresponding AuthorSu, Dangsheng(dssu@imr.ac.cn)
2016
Source PublicationRSC ADVANCES
ISSN2046-2069
Volume6Issue:101Pages:99570-99576
AbstractA series of conjugated polymers (YPB-x) with designated chemical structure are synthesized as model carbon catalysts for mechanistic and kinetic studies of nitroaromatic reduction reactions. The reaction kinetics show that ketonic carbonyl groups are active sites for the nitrobenzene (NB) reduction. A catalytic reaction mechanism involving the activation of hydrazine with carbon catalysts and the subsequent reduction of NB is proposed to describe the catalytic process molecularly. The turnover frequency of heterogeneous carbon catalysts in the liquid phase is reported for the fair comparison of the intrinsic activity among different carbon catalysts.
Funding OrganizationNSFC of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Youth Innovation Promotion Association of CAS
DOI10.1039/c6ra18201a
Indexed BySCI
Language英语
Funding ProjectNSFC of China[21303226] ; NSFC of China[21133010] ; NSFC of China[21573256] ; NSFC of China[51221264] ; NSFC of China[21261160487] ; Strategic Priority Research Program of the Chinese Academy of Sciences[XDA09030103] ; Youth Innovation Promotion Association of CAS
WOS Research AreaChemistry
WOS SubjectChemistry, Multidisciplinary
WOS IDWOS:000387427800121
PublisherROYAL SOC CHEMISTRY
Citation statistics
Cited Times:5[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/123154
Collection中国科学院金属研究所
Corresponding AuthorSu, Dangsheng
Affiliation1.Dalian Univ Technol, Sch Chem Engn, Lab Adv Mat & Catalyt Engn, Dalian 116024, Peoples R China
2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China
3.Chinese Acad Sci, Wuhan Inst Phys & Math, Natl Ctr Magnet Resonance Wuhan, Wuhan 430071, Peoples R China
Recommended Citation
GB/T 7714
Guo, Xiaoling,Qi, Wei,Liu, Wei,et al. Conjugated polymers with defined chemical structure as model carbon catalysts for nitro reduction[J]. RSC ADVANCES,2016,6(101):99570-99576.
APA Guo, Xiaoling.,Qi, Wei.,Liu, Wei.,Liang, Changhai.,Zheng, Anmin.,...&Su, Dangsheng.(2016).Conjugated polymers with defined chemical structure as model carbon catalysts for nitro reduction.RSC ADVANCES,6(101),99570-99576.
MLA Guo, Xiaoling,et al."Conjugated polymers with defined chemical structure as model carbon catalysts for nitro reduction".RSC ADVANCES 6.101(2016):99570-99576.
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