Conjugated polymers with defined chemical structure as model carbon catalysts for nitro reduction

doi:10.1039/c6ra18201a

IMR OpenIR

	Conjugated polymers with defined chemical structure as model carbon catalysts for nitro reduction
	Guo, Xiaoling 1,2; Qi, Wei 2; Liu, Wei 2; Liang, Changhai 1; Zheng, Anmin 3; Yi, Xianfeng 3; Su, Dangsheng 2
通讯作者	Su, Dangsheng(dssu@imr.ac.cn)
	2016
发表期刊	RSC ADVANCES
ISSN	2046-2069
卷号	6 期号:101 页码:99570-99576
摘要	A series of conjugated polymers (YPB-x) with designated chemical structure are synthesized as model carbon catalysts for mechanistic and kinetic studies of nitroaromatic reduction reactions. The reaction kinetics show that ketonic carbonyl groups are active sites for the nitrobenzene (NB) reduction. A catalytic reaction mechanism involving the activation of hydrazine with carbon catalysts and the subsequent reduction of NB is proposed to describe the catalytic process molecularly. The turnover frequency of heterogeneous carbon catalysts in the liquid phase is reported for the fair comparison of the intrinsic activity among different carbon catalysts.
资助者	NSFC of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Youth Innovation Promotion Association of CAS
DOI	10.1039/c6ra18201a
收录类别	SCI
语种	英语
资助项目	NSFC of China[21303226] ; NSFC of China[21133010] ; NSFC of China[21573256] ; NSFC of China[51221264] ; NSFC of China[21261160487] ; Strategic Priority Research Program of the Chinese Academy of Sciences[XDA09030103] ; Youth Innovation Promotion Association of CAS
WOS研究方向	Chemistry
WOS类目	Chemistry, Multidisciplinary
WOS记录号	WOS:000387427800121
出版者	ROYAL SOC CHEMISTRY
引用统计	被引频次：7[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/123154
专题	中国科学院金属研究所
通讯作者	Su, Dangsheng
作者单位	1.Dalian Univ Technol, Sch Chem Engn, Lab Adv Mat & Catalyt Engn, Dalian 116024, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 3.Chinese Acad Sci, Wuhan Inst Phys & Math, Natl Ctr Magnet Resonance Wuhan, Wuhan 430071, Peoples R China
推荐引用方式 GB/T 7714	Guo, Xiaoling,Qi, Wei,Liu, Wei,et al. Conjugated polymers with defined chemical structure as model carbon catalysts for nitro reduction[J]. RSC ADVANCES,2016,6(101):99570-99576.
APA	Guo, Xiaoling.,Qi, Wei.,Liu, Wei.,Liang, Changhai.,Zheng, Anmin.,...&Su, Dangsheng.(2016).Conjugated polymers with defined chemical structure as model carbon catalysts for nitro reduction.RSC ADVANCES,6(101),99570-99576.
MLA	Guo, Xiaoling,et al."Conjugated polymers with defined chemical structure as model carbon catalysts for nitro reduction".RSC ADVANCES 6.101(2016):99570-99576.