Study on Microbiologically Influenced Corrosion Behavior of Novel Cu-Bearing Pipeline Steels

doi:10.11900/0412.1961.2016.00143

IMR OpenIR

	Study on Microbiologically Influenced Corrosion Behavior of Novel Cu-Bearing Pipeline Steels
	Shi Xianbo 1,2; Xu Dake 1; Yan Maocheng 1; Yan Wei 1; Shan Yiyin 1; Yang Ke 1
通讯作者	Yang Ke(kyang@imr.ac.cn)
	2017-02-01
发表期刊	ACTA METALLURGICA SINICA
ISSN	0412-1961
卷号	53 期号:2 页码:153-162
摘要	Microbiologically influenced corrosion (MIC) is a major corrosion related problem for steel pipelines. The great loss caused by microbiologically influenced corrosion (MIC) on buried pipelines has been paid considerable attention domestically and internationally. Various physical, chemical or biological strategies have been used for MIC control, including biocides, coatings, cathodic protection and biocompetitive exclusion. These strategies have limitations of being expensive, subject to environmental restrictions, and sometimes inefficient. There is an urgent need for oil industry to develop environmentally friendly strategies for microbial corrosion control. Cu could play many benefical effects in steels, such as exerting a vigorous effect on hardenability, enhancing strength via precipitation strengthening, improving fatigue resistance, reducing susceptibility of hydrogen embrittlement, promoting formation protective layer etc.. Cu is well known for its inherent antimicrobial properties and is the focus of interest for potential application as a component in antibacterial materials. The Cu-bearing antibacterial stainless steel, characterized by continuous release of Cu ions with antibacterial function, provides analogy to develop a new type of MIC resistance pipeline steel. In this work, three different Cu contents (1.06Cu, 1.46Cu, 2.00Cu, mass fraction, %) pipeline steels, named 1.0Cu, 1.5Cu and 2.0Cu, were fabricated by making proper Cu alloying designs for X80 steel that currently used in oil/gas industry. Study on antibacterial performance and MIC behavior of novel Cu-bearing pipeline steels against Escherichiacoli (E.coli), Staphylococcusaureus (S.aureus) and Sulphate reducing bacteria (SRB) was carried out by antibacterial tests, electrochemistrical monitor, corrosion product analyses and confocal laser scanning microscope (CLSM). The results showed that Cu-bearing pipeline steels had strong antibacterial performance against E.coli and S.aureus compared with X80 steel. 1.0Cu steel with the microstructure of polygonal ferrite showed excellent resistance to SRB with remarkable strength enhancement by nano-scale Cu-rich precipitates and good impact toughness compared with X80 steel. Cu-rich precipitates in Cu-bearing pipeline steels were found to be responsible for the antibacterial capability. The linear polarization resistances (R-LPR) of both X80 and 1.0Cu steels in the soil-extract solution with SRB were dramatically decreased after 2 d, leading to the corrosion current density (i(oorr).) value of X80 steel was much higher than that of 1.0Cu steel. The corrosion product analysis results showed that much biofilm produced by SRB was the reason that many pits and larger pit depth on X80 steel than that of 1.0Cu steel.
关键词	pipeline steel Cu microbiologically influenced corrosion Cu-rich phase antibacterial performance
资助者	National Key Technology Support Program ; National Natural Science Foundation of China
DOI	10.11900/0412.1961.2016.00143
收录类别	SCI
语种	英语
资助项目	National Key Technology Support Program[2011BAE25B03] ; National Natural Science Foundation of China[51271175]
WOS研究方向	Metallurgy & Metallurgical Engineering
WOS类目	Metallurgy & Metallurgical Engineering
WOS记录号	WOS:000395966800003
出版者	SCIENCE PRESS
引用统计	被引频次：17[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/123964
专题	中国科学院金属研究所
通讯作者	Yang Ke
作者单位	1.Chinese Acad Sci, Inst Met Res, Shenyang 110016, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Shi Xianbo,Xu Dake,Yan Maocheng,et al. Study on Microbiologically Influenced Corrosion Behavior of Novel Cu-Bearing Pipeline Steels[J]. ACTA METALLURGICA SINICA,2017,53(2):153-162.
APA	Shi Xianbo,Xu Dake,Yan Maocheng,Yan Wei,Shan Yiyin,&Yang Ke.(2017).Study on Microbiologically Influenced Corrosion Behavior of Novel Cu-Bearing Pipeline Steels.ACTA METALLURGICA SINICA,53(2),153-162.
MLA	Shi Xianbo,et al."Study on Microbiologically Influenced Corrosion Behavior of Novel Cu-Bearing Pipeline Steels".ACTA METALLURGICA SINICA 53.2(2017):153-162.