Synthesis and crystal structure of [Cu(4-OOCC6H4CN)(2) (4-HOOCC6H4CN)(H2O)(2)] center dot 2(4-HOOCC6H4CN): a hydrogen bonded assembly of the first transition metal complex of 4-cyanobenzoic acid

doi:10.1016/S1387-7003(03)00121-7

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	Synthesis and crystal structure of [Cu(4-OOCC6H4CN)(2) (4-HOOCC6H4CN)(H2O)(2)] center dot 2(4-HOOCC6H4CN): a hydrogen bonded assembly of the first transition metal complex of 4-cyanobenzoic acid
	Wang, MS ; Cai, LZ ; Zhou, GW ; Guo, GC ; Huang, JS
通讯作者	Guo, GC()
	2003-07-01
发表期刊	INORGANIC CHEMISTRY COMMUNICATIONS
ISSN	1387-7003
卷号	6 期号:7 页码:855-858
摘要	The first transition metal complex of 4-cyanobenzoic acid, [Cu(4-OOCC6H4CN)(2)(4-HOOCC6H4CN)(H2O)(2)]. 2(4-HOOCC6H4CN), has been prepared in aqueous medium. X-ray single crystal structure analysis reveals that it is a monometallic complex. Five-coordination Cu(II) ion is approximately in a square based pyramidal environment. Three-dimensional network of this compound is formed through O-H...N, O-H...O, C-H...O and C-H...N hydrogen bonding interactions, yielding a grid framework containing dimers of 4-cyanobenzoic acid with carboxylic dimer 2synthons locating in the channels. (C) 2003 Elsevier Science B.V. All rights reserved.
关键词	4-cyanobenzoic acid Cu(II) complex hydrogen bonding carboxylic dimer synthon
DOI	10.1016/S1387-7003(03)00121-7
收录类别	SCI
语种	英语
WOS研究方向	Chemistry
WOS类目	Chemistry, Inorganic & Nuclear
WOS记录号	WOS:000183745800016
出版者	ELSEVIER SCIENCE BV
引用统计	被引频次：10[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/126926
专题	中国科学院金属研究所
通讯作者	Guo, GC
作者单位	1.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China 2.Grad Sch Chinese Acad Sci, Beijing, Peoples R China
推荐引用方式 GB/T 7714	Wang, MS,Cai, LZ,Zhou, GW,et al. Synthesis and crystal structure of [Cu(4-OOCC6H4CN)(2) (4-HOOCC6H4CN)(H2O)(2)] center dot 2(4-HOOCC6H4CN): a hydrogen bonded assembly of the first transition metal complex of 4-cyanobenzoic acid[J]. INORGANIC CHEMISTRY COMMUNICATIONS,2003,6(7):855-858.
APA	Wang, MS,Cai, LZ,Zhou, GW,Guo, GC,&Huang, JS.(2003).Synthesis and crystal structure of [Cu(4-OOCC6H4CN)(2) (4-HOOCC6H4CN)(H2O)(2)] center dot 2(4-HOOCC6H4CN): a hydrogen bonded assembly of the first transition metal complex of 4-cyanobenzoic acid.INORGANIC CHEMISTRY COMMUNICATIONS,6(7),855-858.
MLA	Wang, MS,et al."Synthesis and crystal structure of [Cu(4-OOCC6H4CN)(2) (4-HOOCC6H4CN)(H2O)(2)] center dot 2(4-HOOCC6H4CN): a hydrogen bonded assembly of the first transition metal complex of 4-cyanobenzoic acid".INORGANIC CHEMISTRY COMMUNICATIONS 6.7(2003):855-858.