| Synthesis and crystal structure of [Cu(4-OOCC6H4CN)(2) (4-HOOCC6H4CN)(H2O)(2)] center dot 2(4-HOOCC6H4CN): a hydrogen bonded assembly of the first transition metal complex of 4-cyanobenzoic acid | |
| Wang, MS; Cai, LZ; Zhou, GW; Guo, GC; Huang, JS | |
| Corresponding Author | Guo, GC() |
| 2003-07-01 | |
| Source Publication | INORGANIC CHEMISTRY COMMUNICATIONS
 |
| ISSN | 1387-7003 |
| Volume | 6Issue:7Pages:855-858 |
| Abstract | The first transition metal complex of 4-cyanobenzoic acid, [Cu(4-OOCC6H4CN)(2)(4-HOOCC6H4CN)(H2O)(2)]. 2(4-HOOCC6H4CN), has been prepared in aqueous medium. X-ray single crystal structure analysis reveals that it is a monometallic complex. Five-coordination Cu(II) ion is approximately in a square based pyramidal environment. Three-dimensional network of this compound is formed through O-H...N, O-H...O, C-H...O and C-H...N hydrogen bonding interactions, yielding a grid framework containing dimers of 4-cyanobenzoic acid with carboxylic dimer 2synthons locating in the channels. (C) 2003 Elsevier Science B.V. All rights reserved. |
| Keyword | 4-cyanobenzoic acid Cu(II) complex hydrogen bonding carboxylic dimer synthon |
| DOI | 10.1016/S1387-7003(03)00121-7 |
| Indexed By | SCI |
| Language | 英语 |
| WOS Research Area | Chemistry |
| WOS Subject | Chemistry, Inorganic & Nuclear |
| WOS ID | WOS:000183745800016 |
| Publisher | ELSEVIER SCIENCE BV |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.imr.ac.cn/handle/321006/126926 |
| Collection | 中国科学院金属研究所 |
| Corresponding Author | Guo, GC |
| Affiliation | 1.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China 2.Grad Sch Chinese Acad Sci, Beijing, Peoples R China |
| Recommended Citation GB/T 7714 | Wang, MS,Cai, LZ,Zhou, GW,et al. Synthesis and crystal structure of [Cu(4-OOCC6H4CN)(2) (4-HOOCC6H4CN)(H2O)(2)] center dot 2(4-HOOCC6H4CN): a hydrogen bonded assembly of the first transition metal complex of 4-cyanobenzoic acid[J]. INORGANIC CHEMISTRY COMMUNICATIONS,2003,6(7):855-858. |
| APA | Wang, MS,Cai, LZ,Zhou, GW,Guo, GC,&Huang, JS.(2003).Synthesis and crystal structure of [Cu(4-OOCC6H4CN)(2) (4-HOOCC6H4CN)(H2O)(2)] center dot 2(4-HOOCC6H4CN): a hydrogen bonded assembly of the first transition metal complex of 4-cyanobenzoic acid.INORGANIC CHEMISTRY COMMUNICATIONS,6(7),855-858. |
| MLA | Wang, MS,et al."Synthesis and crystal structure of [Cu(4-OOCC6H4CN)(2) (4-HOOCC6H4CN)(H2O)(2)] center dot 2(4-HOOCC6H4CN): a hydrogen bonded assembly of the first transition metal complex of 4-cyanobenzoic acid".INORGANIC CHEMISTRY COMMUNICATIONS 6.7(2003):855-858. |
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