| The Development of Yolk-Shell-Structured Pd&ZnO@Carbon Submicroreactors with High Selectivity and Stability | |
| Tian, Hao1,2; Huang, Fei3; Zhu, Yihan4,5; Liu, Shaomin2; Han, Yu4; Jaroniec, Mietek6; Yang, Qihua1; Liu, Hongyang3; Lu, Gao Qing Max7; Liu, Jian1,2,8 | |
| Corresponding Author | Liu, Hongyang(liuhy@imr.ac.cn) ; Liu, Jian(jianliu@dicp.ac.cn) |
| 2018-08-08 | |
| Source Publication | ADVANCED FUNCTIONAL MATERIALS
 |
| ISSN | 1616-301X |
| Volume | 28Issue:32Pages:10 |
| Abstract | Design of multicomponent yolk-shell structures is crucial for the fabrication of micro/nanoreactors for a variety of applications. This work reports the rational design and synthesis of yolk-shell-structured submicroreactors with loaded metal nanoparticles into ZnO-microporous carbon core-shell structures. The solvothermal treatment and carbonization process of uniform zeolitic imidazolate framework-8 (ZIF-8)@resin polymer core-shell structures leads to the generation of yolk-shell-structured ZnO@carbon. The synthesis conditions are optimized to track the evolution of ZIF-8 in a confined space of resin polymer as a submicroreactor itself. It is found that nanoribbon evolution occurs via the formation of the intermediate needle-like particles. The Pd&ZnO@carbon submicroreactor is shown to be a highly selective catalyst (selectivity >99%) for hydrogenation of phenylacetylene to phenylethylene. The excellent performance of Pd&ZnO@carbon particles is evidenced by higher conversion and selectivity than that of Pd/ZnO and Pd/C with similar Pd loading. Furthermore, Pd&ZnO@carbon submicroreactors show superior catalytic stability, and no deactivation after 25 h of reaction. The proposed strategy is promising for the design of multifunctional micro/nanoreactors or nanocontainers for construction of artificial cells. |
| Keyword | metal-organic frameworks phenylacetylene hydrogenation submicroreactors yolk-shell particles zeolite imidazolate frameworks |
| Funding Organization | Australian Research Council (ARC) ; Chinese Government 1000 young talent plan ; Curtin Strategic International Research Scholarship ; Curtin University Mobility Scholarship ; Chinese Government Award for Outstanding Self-Financed Students Abroad ; Ministry of Science and Technology ; National Natural Science Foundation of China ; Youth Innovation Promotion Association(CAS) ; Sinopec China |
| DOI | 10.1002/adfm.201801737 |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | Australian Research Council (ARC)[DP180100568] ; Australian Research Council (ARC)[LP150101158] ; Chinese Government 1000 young talent plan ; Curtin Strategic International Research Scholarship ; Curtin University Mobility Scholarship ; Chinese Government Award for Outstanding Self-Financed Students Abroad ; Ministry of Science and Technology[2016YFA0204100] ; National Natural Science Foundation of China[21573254] ; National Natural Science Foundation of China[91545110] ; Youth Innovation Promotion Association(CAS) ; Sinopec China |
| WOS Research Area | Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics |
| WOS Subject | Chemistry, Multidisciplinary ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter |
| WOS ID | WOS:000440810500010 |
| Publisher | WILEY-V C H VERLAG GMBH |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.imr.ac.cn/handle/321006/128893 |
| Collection | 中国科学院金属研究所 |
| Corresponding Author | Liu, Hongyang; Liu, Jian |
| Affiliation | 1.Chinese Acad Sci, Dalian Inst Chem Phys, iChEM, State Key Lab Catalysis, 457 Zhongshan Rd, Dalian 116023, Peoples R China 2.Curtin Univ, Dept Chem Engn, Perth, WA 6845, Australia 3.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, 72 Wenhua Rd, Shenyang 110016, Liaoning, Peoples R China 4.King Abdullah Univ Sci & Technol, Chem & Life Sci & Engn Div, Adv Membranes & Porous Mat Ctr, Thuwal 239556900, Saudi Arabia 5.Zhejiang Univ Technol, Dept Chem Engn, Hangzhou 310014, Zhejiang, Peoples R China 6.Kent State Univ, Dept Chem & Biochem, Kent, OH 44242 USA 7.Univ Surrey, Vice Chancellors Off, Guildford GU2 7XH, Surrey, England 8.Univ Surrey, Dept Chem & Proc Engn, Guildford GU2 7XH, Surrey, England |
| Recommended Citation GB/T 7714 | Tian, Hao,Huang, Fei,Zhu, Yihan,et al. The Development of Yolk-Shell-Structured Pd&ZnO@Carbon Submicroreactors with High Selectivity and Stability[J]. ADVANCED FUNCTIONAL MATERIALS,2018,28(32):10. |
| APA | Tian, Hao.,Huang, Fei.,Zhu, Yihan.,Liu, Shaomin.,Han, Yu.,...&Liu, Jian.(2018).The Development of Yolk-Shell-Structured Pd&ZnO@Carbon Submicroreactors with High Selectivity and Stability.ADVANCED FUNCTIONAL MATERIALS,28(32),10. |
| MLA | Tian, Hao,et al."The Development of Yolk-Shell-Structured Pd&ZnO@Carbon Submicroreactors with High Selectivity and Stability".ADVANCED FUNCTIONAL MATERIALS 28.32(2018):10. |
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