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The Development of Yolk-Shell-Structured Pd&ZnO@Carbon Submicroreactors with High Selectivity and Stability
Tian, Hao1,2; Huang, Fei3; Zhu, Yihan4,5; Liu, Shaomin2; Han, Yu4; Jaroniec, Mietek6; Yang, Qihua1; Liu, Hongyang3; Lu, Gao Qing Max7; Liu, Jian1,2,8
Corresponding AuthorLiu, Hongyang(liuhy@imr.ac.cn) ; Liu, Jian(jianliu@dicp.ac.cn)
2018-08-08
Source PublicationADVANCED FUNCTIONAL MATERIALS
ISSN1616-301X
Volume28Issue:32Pages:10
AbstractDesign of multicomponent yolk-shell structures is crucial for the fabrication of micro/nanoreactors for a variety of applications. This work reports the rational design and synthesis of yolk-shell-structured submicroreactors with loaded metal nanoparticles into ZnO-microporous carbon core-shell structures. The solvothermal treatment and carbonization process of uniform zeolitic imidazolate framework-8 (ZIF-8)@resin polymer core-shell structures leads to the generation of yolk-shell-structured ZnO@carbon. The synthesis conditions are optimized to track the evolution of ZIF-8 in a confined space of resin polymer as a submicroreactor itself. It is found that nanoribbon evolution occurs via the formation of the intermediate needle-like particles. The Pd&ZnO@carbon submicroreactor is shown to be a highly selective catalyst (selectivity >99%) for hydrogenation of phenylacetylene to phenylethylene. The excellent performance of Pd&ZnO@carbon particles is evidenced by higher conversion and selectivity than that of Pd/ZnO and Pd/C with similar Pd loading. Furthermore, Pd&ZnO@carbon submicroreactors show superior catalytic stability, and no deactivation after 25 h of reaction. The proposed strategy is promising for the design of multifunctional micro/nanoreactors or nanocontainers for construction of artificial cells.
Keywordmetal-organic frameworks phenylacetylene hydrogenation submicroreactors yolk-shell particles zeolite imidazolate frameworks
Funding OrganizationAustralian Research Council (ARC) ; Chinese Government 1000 young talent plan ; Curtin Strategic International Research Scholarship ; Curtin University Mobility Scholarship ; Chinese Government Award for Outstanding Self-Financed Students Abroad ; Ministry of Science and Technology ; National Natural Science Foundation of China ; Youth Innovation Promotion Association(CAS) ; Sinopec China
DOI10.1002/adfm.201801737
Indexed BySCI
Language英语
Funding ProjectAustralian Research Council (ARC)[DP180100568] ; Australian Research Council (ARC)[LP150101158] ; Chinese Government 1000 young talent plan ; Curtin Strategic International Research Scholarship ; Curtin University Mobility Scholarship ; Chinese Government Award for Outstanding Self-Financed Students Abroad ; Ministry of Science and Technology[2016YFA0204100] ; National Natural Science Foundation of China[21573254] ; National Natural Science Foundation of China[91545110] ; Youth Innovation Promotion Association(CAS) ; Sinopec China
WOS Research AreaChemistry ; Science & Technology - Other Topics ; Materials Science ; Physics
WOS SubjectChemistry, Multidisciplinary ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter
WOS IDWOS:000440810500010
PublisherWILEY-V C H VERLAG GMBH
Citation statistics
Cited Times:44[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/128893
Collection中国科学院金属研究所
Corresponding AuthorLiu, Hongyang; Liu, Jian
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, iChEM, State Key Lab Catalysis, 457 Zhongshan Rd, Dalian 116023, Peoples R China
2.Curtin Univ, Dept Chem Engn, Perth, WA 6845, Australia
3.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, 72 Wenhua Rd, Shenyang 110016, Liaoning, Peoples R China
4.King Abdullah Univ Sci & Technol, Chem & Life Sci & Engn Div, Adv Membranes & Porous Mat Ctr, Thuwal 239556900, Saudi Arabia
5.Zhejiang Univ Technol, Dept Chem Engn, Hangzhou 310014, Zhejiang, Peoples R China
6.Kent State Univ, Dept Chem & Biochem, Kent, OH 44242 USA
7.Univ Surrey, Vice Chancellors Off, Guildford GU2 7XH, Surrey, England
8.Univ Surrey, Dept Chem & Proc Engn, Guildford GU2 7XH, Surrey, England
Recommended Citation
GB/T 7714
Tian, Hao,Huang, Fei,Zhu, Yihan,et al. The Development of Yolk-Shell-Structured Pd&ZnO@Carbon Submicroreactors with High Selectivity and Stability[J]. ADVANCED FUNCTIONAL MATERIALS,2018,28(32):10.
APA Tian, Hao.,Huang, Fei.,Zhu, Yihan.,Liu, Shaomin.,Han, Yu.,...&Liu, Jian.(2018).The Development of Yolk-Shell-Structured Pd&ZnO@Carbon Submicroreactors with High Selectivity and Stability.ADVANCED FUNCTIONAL MATERIALS,28(32),10.
MLA Tian, Hao,et al."The Development of Yolk-Shell-Structured Pd&ZnO@Carbon Submicroreactors with High Selectivity and Stability".ADVANCED FUNCTIONAL MATERIALS 28.32(2018):10.
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