The Development of Yolk-Shell-Structured Pd&ZnO@Carbon Submicroreactors with High Selectivity and Stability

doi:10.1002/adfm.201801737

IMR OpenIR

	The Development of Yolk-Shell-Structured Pd&ZnO@Carbon Submicroreactors with High Selectivity and Stability
	Tian, Hao 1,2; Huang, Fei 3; Zhu, Yihan 4,5; Liu, Shaomin 2; Han, Yu 4; Jaroniec, Mietek 6; Yang, Qihua 1; Liu, Hongyang 3; Lu, Gao Qing Max 7; Liu, Jian 1,2,8
通讯作者	Liu, Hongyang(liuhy@imr.ac.cn) ; Liu, Jian(jianliu@dicp.ac.cn)
	2018-08-08
发表期刊	ADVANCED FUNCTIONAL MATERIALS
ISSN	1616-301X
卷号	28 期号:32 页码:10
摘要	Design of multicomponent yolk-shell structures is crucial for the fabrication of micro/nanoreactors for a variety of applications. This work reports the rational design and synthesis of yolk-shell-structured submicroreactors with loaded metal nanoparticles into ZnO-microporous carbon core-shell structures. The solvothermal treatment and carbonization process of uniform zeolitic imidazolate framework-8 (ZIF-8)@resin polymer core-shell structures leads to the generation of yolk-shell-structured ZnO@carbon. The synthesis conditions are optimized to track the evolution of ZIF-8 in a confined space of resin polymer as a submicroreactor itself. It is found that nanoribbon evolution occurs via the formation of the intermediate needle-like particles. The Pd&ZnO@carbon submicroreactor is shown to be a highly selective catalyst (selectivity >99%) for hydrogenation of phenylacetylene to phenylethylene. The excellent performance of Pd&ZnO@carbon particles is evidenced by higher conversion and selectivity than that of Pd/ZnO and Pd/C with similar Pd loading. Furthermore, Pd&ZnO@carbon submicroreactors show superior catalytic stability, and no deactivation after 25 h of reaction. The proposed strategy is promising for the design of multifunctional micro/nanoreactors or nanocontainers for construction of artificial cells.
关键词	metal-organic frameworks phenylacetylene hydrogenation submicroreactors yolk-shell particles zeolite imidazolate frameworks
资助者	Australian Research Council (ARC) ; Chinese Government 1000 young talent plan ; Curtin Strategic International Research Scholarship ; Curtin University Mobility Scholarship ; Chinese Government Award for Outstanding Self-Financed Students Abroad ; Ministry of Science and Technology ; National Natural Science Foundation of China ; Youth Innovation Promotion Association(CAS) ; Sinopec China
DOI	10.1002/adfm.201801737
收录类别	SCI
语种	英语
资助项目	Australian Research Council (ARC)[DP180100568] ; Australian Research Council (ARC)[LP150101158] ; Chinese Government 1000 young talent plan ; Curtin Strategic International Research Scholarship ; Curtin University Mobility Scholarship ; Chinese Government Award for Outstanding Self-Financed Students Abroad ; Ministry of Science and Technology[2016YFA0204100] ; National Natural Science Foundation of China[21573254] ; National Natural Science Foundation of China[91545110] ; Youth Innovation Promotion Association(CAS) ; Sinopec China
WOS研究方向	Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics
WOS类目	Chemistry, Multidisciplinary ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter
WOS记录号	WOS:000440810500010
出版者	WILEY-V C H VERLAG GMBH
引用统计	被引频次：98[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/128893
专题	中国科学院金属研究所
通讯作者	Liu, Hongyang; Liu, Jian
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, iChEM, State Key Lab Catalysis, 457 Zhongshan Rd, Dalian 116023, Peoples R China 2.Curtin Univ, Dept Chem Engn, Perth, WA 6845, Australia 3.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, 72 Wenhua Rd, Shenyang 110016, Liaoning, Peoples R China 4.King Abdullah Univ Sci & Technol, Chem & Life Sci & Engn Div, Adv Membranes & Porous Mat Ctr, Thuwal 239556900, Saudi Arabia 5.Zhejiang Univ Technol, Dept Chem Engn, Hangzhou 310014, Zhejiang, Peoples R China 6.Kent State Univ, Dept Chem & Biochem, Kent, OH 44242 USA 7.Univ Surrey, Vice Chancellors Off, Guildford GU2 7XH, Surrey, England 8.Univ Surrey, Dept Chem & Proc Engn, Guildford GU2 7XH, Surrey, England
推荐引用方式 GB/T 7714	Tian, Hao,Huang, Fei,Zhu, Yihan,et al. The Development of Yolk-Shell-Structured Pd&ZnO@Carbon Submicroreactors with High Selectivity and Stability[J]. ADVANCED FUNCTIONAL MATERIALS,2018,28(32):10.
APA	Tian, Hao.,Huang, Fei.,Zhu, Yihan.,Liu, Shaomin.,Han, Yu.,...&Liu, Jian.(2018).The Development of Yolk-Shell-Structured Pd&ZnO@Carbon Submicroreactors with High Selectivity and Stability.ADVANCED FUNCTIONAL MATERIALS,28(32),10.
MLA	Tian, Hao,et al."The Development of Yolk-Shell-Structured Pd&ZnO@Carbon Submicroreactors with High Selectivity and Stability".ADVANCED FUNCTIONAL MATERIALS 28.32(2018):10.