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Investigation on the effect of Nb doping on the oxidation mechanism of Ti3SiC2
Zhenga, Lili1,2,3; Hua, Qingsong1,2; Li, Xichao3,4; Li, Meishuan3; Qian, Yuhai3; Xu, Jingjun3; Zhang, Jianmin1,2; Zheng, Zongmin1,2; Dai, Zuoqiang1,2; Zhang, Hongxin1,2; Zhang, Tiezhu1,2
通讯作者Zhenga, Lili(llzhengqdu@163.com) ; Li, Xichao(lixc@qibebt.ac.cn)
2018-08-01
发表期刊CORROSION SCIENCE
ISSN0010-938X
卷号140页码:374-378
摘要Nb doping substantially changes the oxidation mechanism and significantly enhances its oxidation resistance of Ti3SiC2 at 800 degrees C. After Nb doping, the oxidation of Ti3SiC2 is only controlled by the inward diffusion of O, while the outward diffusion of Ti is restrained totally. The oxide layer structure changes from a duplex-layer of TiO2 outer layer and TiO2+SiO2 mixture inner layer to a single TiO2+SiO2 mixture layer. It is proposed that Nb doping decreases the concentrations of oxygen vacancies and Ti interstitials in the formed TiO2, leading to the completely restrained outward diffusion of Ti and the decreased oxidation rate.
关键词Ti3SiC2Nb doping Oxidation mechanism Ion diffusion Defect concentration
资助者National Science Foundation of China ; National Key Research and Development Program of China ; Shandong Province Key Research and Development Program ; Qingdao postdoctoral research project ; Scientific Research Start-up Fund of Qingdao University
DOI10.1016/j.corsci.2018.05.028
收录类别SCI
语种英语
资助项目National Science Foundation of China[51271191] ; National Science Foundation of China[51571205] ; National Key Research and Development Program of China[2017YFB0102004] ; Shandong Province Key Research and Development Program[2017CXGC0502] ; Qingdao postdoctoral research project ; Scientific Research Start-up Fund of Qingdao University[41117010089]
WOS研究方向Materials Science ; Metallurgy & Metallurgical Engineering
WOS类目Materials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering
WOS记录号WOS:000440121100036
出版者PERGAMON-ELSEVIER SCIENCE LTD
引用统计
被引频次:19[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/128946
专题中国科学院金属研究所
通讯作者Zhenga, Lili; Li, Xichao
作者单位1.Qingdao Univ, Natl Engn Res Ctr Intelligent Elect Vehicle Power, 308 Ningxia Rd, Qingdao 266071, Peoples R China
2.Qingdao Univ, Coll Mech & Elect Engn, 308 Ningxia Rd, Qingdao 266071, Peoples R China
3.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Liaoning, Peoples R China
4.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China
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GB/T 7714
Zhenga, Lili,Hua, Qingsong,Li, Xichao,et al. Investigation on the effect of Nb doping on the oxidation mechanism of Ti3SiC2[J]. CORROSION SCIENCE,2018,140:374-378.
APA Zhenga, Lili.,Hua, Qingsong.,Li, Xichao.,Li, Meishuan.,Qian, Yuhai.,...&Zhang, Tiezhu.(2018).Investigation on the effect of Nb doping on the oxidation mechanism of Ti3SiC2.CORROSION SCIENCE,140,374-378.
MLA Zhenga, Lili,et al."Investigation on the effect of Nb doping on the oxidation mechanism of Ti3SiC2".CORROSION SCIENCE 140(2018):374-378.
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