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Self-Assembly of CoPt Magnetic Nanoparticle Arrays and its Underlying Forces
Bian, Baoru1; Chen, Guoxin1; Zheng, Qiang1; Du, Juan1; Lu, Huanming1; Liu, J. Ping2; Hu, Yong3; Zhang, Zhidong4
通讯作者Du, Juan(dujuan@nimte.ac.cn) ; Lu, Huanming(hmlu@nimte.ac.cn) ; Hu, Yong(huyong@mail.neu.edu.cn)
2018-08-23
发表期刊SMALL
ISSN1613-6810
卷号14期号:34页码:8
摘要Nanoparticles covered with surfactants are often used to study particle motion patterns and self-assembly processes in solutions. Surfactants have influence on the interparticle interactions and therefore on the particle motion tracks and final patterns. In this study, CoPt nanoparticles are synthesized in aqueous solution without any surfactant. In situ transmission electron microscopy observation is performed to monitor the self-assemble process. Two types of magnetic nanoparticle superlattice arrays are formed: hexagonal equal distance superlattice arrays when particle size is 3 nm, and tight unequal distance superlattice arrays when particle size is 4.5 nm. It is interesting to observe that two small arrays merge into a large one through rotational and translational movements. A Monte Carlo simulation is carried out which successfully restores the whole process. It is identified that the underlying forces are van der Waals and magnetic dipolar interactions. The latter is responsible for orientation of each particle during the whole process. This investigation leads to a better understanding of the formation mechanism of magnetic nanoparticle superlattice arrays.
关键词CoPt nanoparticle superlattice driving force in situ TEM self-assembly
资助者National Natural Science Foundation of China ; Natural Science Foundation of Ningbo ; China Scholarship Council
DOI10.1002/smll.201801184
收录类别SCI
语种英语
资助项目National Natural Science Foundation of China[51771219] ; National Natural Science Foundation of China[51771220] ; National Natural Science Foundation of China[51771095] ; National Natural Science Foundation of China[51590883] ; National Natural Science Foundation of China[51422106] ; Natural Science Foundation of Ningbo[2017A610030] ; China Scholarship Council[201606085010]
WOS研究方向Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics
WOS类目Chemistry, Multidisciplinary ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter
WOS记录号WOS:000442501500004
出版者WILEY-V C H VERLAG GMBH
引用统计
被引频次:19[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/129071
专题中国科学院金属研究所
通讯作者Du, Juan; Lu, Huanming; Hu, Yong
作者单位1.Chinese Acad Sci, Key Lab Magnet Mat & Devices, Ningbo Inst Mat Technol & Engn, Ningbo 315201, Zhejiang, Peoples R China
2.Univ Texas Arlington, Dept Phys, POB 19059, Arlington, TX 76019 USA
3.Northeastern Univ, Coll Sci, Shenyang 110819, Liaoning, Peoples R China
4.Chinese Acad Sci, Shenyang Natl Lab Mat Sci, Inst Met Res, Shenyang 110011, Liaoning, Peoples R China
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GB/T 7714
Bian, Baoru,Chen, Guoxin,Zheng, Qiang,et al. Self-Assembly of CoPt Magnetic Nanoparticle Arrays and its Underlying Forces[J]. SMALL,2018,14(34):8.
APA Bian, Baoru.,Chen, Guoxin.,Zheng, Qiang.,Du, Juan.,Lu, Huanming.,...&Zhang, Zhidong.(2018).Self-Assembly of CoPt Magnetic Nanoparticle Arrays and its Underlying Forces.SMALL,14(34),8.
MLA Bian, Baoru,et al."Self-Assembly of CoPt Magnetic Nanoparticle Arrays and its Underlying Forces".SMALL 14.34(2018):8.
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