| Ultra-Small Platinum Nanoparticles Encapsulated in Sub-50 nm Hollow Titania Nanospheres for Low-Temperature Water-Gas Shift Reaction | |
| Zhao, Hongyu1,2; Yao, Siyu4; Zhang, Mengtao4; Huang, Fei3; Fan, Qikui1,2; Zhang, Shumeng1,2; Liu, Hongyang3; Ma, Ding4; Gao, Chuanbo1,2 | |
| Corresponding Author | Liu, Hongyang(liuhy@imr.ac.cn) ; Ma, Ding(dma@pku.edu.cn) ; Gao, Chuanbo(gaochuanbo@mail.xjtu.edu.cn) |
| 2018-10-31 | |
| Source Publication | ACS APPLIED MATERIALS & INTERFACES
 |
| ISSN | 1944-8244 |
| Volume | 10Issue:43Pages:36954-36960 |
| Abstract | Ultra-small platinum nanoparticles loaded over titania is a promising catalyst for the low-temperature water gas shift (WGS) reaction and shows the potential to work in a mobile hydrogen fuel cell system. Their precise size engineering (<3 nm) and reliable stabilization remain challenging. To address these issues, we report a reverse-micelle synthesis approach, which affords uniform ultra-small platinum nano particles (tunable in similar to 1.0-2.6 nm) encapsulated in hollow titania nanospheres with a shell thickness of only similar to 3-5 nm and an overall diameter of only similar to 32 nm. The Pt@TiO2 yolk/shell nanostructured catalysts display extraordinary stability and monotonically increasing activity with the decreasing size of the Pt nanoparticles in the WGS. The size-dependent variation in the electronic property of the Pt nanoparticles and the reducible oxide encapsulation that prevents the Pt nanoparticles from sintering are ascribed as the main reasons for the excellent catalytic performance. |
| Keyword | ultra-small platinum nanoparticles hollow titania nanospheres encapsulation water-gas shift size-dependent catalysis |
| Funding Organization | National Natural Science Foundation of China ; Cyrus Tang Foundation ; Ministry of Science and Technology (MOST) ; Youth Innovation Promotion Association Chinese Academy of Sciences |
| DOI | 10.1021/acsami.8b12192 |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | National Natural Science Foundation of China[21671156] ; National Natural Science Foundation of China[21301138] ; National Natural Science Foundation of China[91545110] ; National Natural Science Foundation of China[21573254] ; Cyrus Tang Foundation ; Ministry of Science and Technology (MOST)[2016YFA0204100] ; Youth Innovation Promotion Association Chinese Academy of Sciences |
| WOS Research Area | Science & Technology - Other Topics ; Materials Science |
| WOS Subject | Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary |
| WOS ID | WOS:000449239600040 |
| Publisher | AMER CHEMICAL SOC |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.imr.ac.cn/handle/321006/130234 |
| Collection | 中国科学院金属研究所 |
| Corresponding Author | Liu, Hongyang; Ma, Ding; Gao, Chuanbo |
| Affiliation | 1.Xi An Jiao Tong Univ, Frontier Inst Sci & Technol, Xian 710054, Shaanxi, Peoples R China 2.Xi An Jiao Tong Univ, State Key Lab Multiphase Flow Power Engn, Xian 710054, Shaanxi, Peoples R China 3.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Liaoning, Peoples R China 4.Peking Univ, Coll Chem & Mol Engn, Beijing 100871, Peoples R China |
| Recommended Citation GB/T 7714 | Zhao, Hongyu,Yao, Siyu,Zhang, Mengtao,et al. Ultra-Small Platinum Nanoparticles Encapsulated in Sub-50 nm Hollow Titania Nanospheres for Low-Temperature Water-Gas Shift Reaction[J]. ACS APPLIED MATERIALS & INTERFACES,2018,10(43):36954-36960. |
| APA | Zhao, Hongyu.,Yao, Siyu.,Zhang, Mengtao.,Huang, Fei.,Fan, Qikui.,...&Gao, Chuanbo.(2018).Ultra-Small Platinum Nanoparticles Encapsulated in Sub-50 nm Hollow Titania Nanospheres for Low-Temperature Water-Gas Shift Reaction.ACS APPLIED MATERIALS & INTERFACES,10(43),36954-36960. |
| MLA | Zhao, Hongyu,et al."Ultra-Small Platinum Nanoparticles Encapsulated in Sub-50 nm Hollow Titania Nanospheres for Low-Temperature Water-Gas Shift Reaction".ACS APPLIED MATERIALS & INTERFACES 10.43(2018):36954-36960. |
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