| Biomass-Derived Graphene-like Carbon: Efficient Metal-Free Carbocatalysts for Epoxidation | |
| Wen, Guodong1; Gu, Qingqing1; Liu, Yuefeng2; Schloegl, Robert3; Wang, Congxin2; Tian, Zhijian2; Su, Dang Sheng1,2 | |
| Corresponding Author | Wen, Guodong(wengd@imr.ac.cn) ; Su, Dang Sheng(dssu@imr.ac.cn) |
| 2018-12-17 | |
| Source Publication | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
 |
| ISSN | 1433-7851 |
| Volume | 57Issue:51Pages:16898-16902 |
| Abstract | N-doped graphene-like layered carbon (NG) could be synthesized via a metal-free pyrolysis route from glucose, fructose, and 5-hydroxymethylfurfural (5-HMF), which are cheap and widely available biomass or biomass derivatives. A well-developed thin-layer structure with large lateral dimensions could be obtained when 5-HMF was used as the precursor. More importantly, the 5-HMF-derived NG gave superior performance in epoxidation reactions compared with the conventional carbon catalysts and the performance of 5-HMF derived NG was even similar to that of a cobalt catalyst. Characterizations by TEM and XPS accompanied by EPR analysis revealed that the enhanced catalytic properties for NG arise from its high activation ability for both alkenes and O-2, which are attributed to the graphitic layered structure and graphitic N species, respectively. |
| Keyword | biomass carbocatalysts epoxidations graphene metal-free processes |
| Funding Organization | National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences |
| DOI | 10.1002/anie.201809970 |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | National Natural Science Foundation of China[21503241] ; National Natural Science Foundation of China[21411130120] ; National Natural Science Foundation of China[51521091] ; National Natural Science Foundation of China[21473223] ; Strategic Priority Research Program of the Chinese Academy of Sciences[XDA09030103] |
| WOS Research Area | Chemistry |
| WOS Subject | Chemistry, Multidisciplinary |
| WOS ID | WOS:000453348900057 |
| Publisher | WILEY-V C H VERLAG GMBH |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.imr.ac.cn/handle/321006/130749 |
| Collection | 中国科学院金属研究所 |
| Corresponding Author | Wen, Guodong; Su, Dang Sheng |
| Affiliation | 1.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, 72 Wenhua Rd, Shenyang 110016, Liaoning, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, 457 Zhongshan Rd, Dalian 116023, Peoples R China 3.Max Planck Gesell, Fritz Haber Inst, Faradayweg 4-6, D-14195 Berlin, Germany |
| Recommended Citation GB/T 7714 | Wen, Guodong,Gu, Qingqing,Liu, Yuefeng,et al. Biomass-Derived Graphene-like Carbon: Efficient Metal-Free Carbocatalysts for Epoxidation[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2018,57(51):16898-16902. |
| APA | Wen, Guodong.,Gu, Qingqing.,Liu, Yuefeng.,Schloegl, Robert.,Wang, Congxin.,...&Su, Dang Sheng.(2018).Biomass-Derived Graphene-like Carbon: Efficient Metal-Free Carbocatalysts for Epoxidation.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,57(51),16898-16902. |
| MLA | Wen, Guodong,et al."Biomass-Derived Graphene-like Carbon: Efficient Metal-Free Carbocatalysts for Epoxidation".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 57.51(2018):16898-16902. |
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