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Ceramic phases with one-dimensional long-range order
Yin, Deqiang1,2; Chen, Chunlin1,3; Saito, Mitsuhiro1,4; Inoue, Kazutoshi1; Ikuhara, Yuichi1,4,5
Corresponding AuthorChen, Chunlin(clchen@imr.ac.cn) ; Ikuhara, Yuichi(ikuhara@sigma.t.u-tokyo.ac.jp)
2019
Source PublicationNATURE MATERIALS
ISSN1476-1122
Volume18Issue:1Pages:19-+
AbstractSolids are generally classified into three categories based on their atomic arrangement: crystalline, quasicrystalline and amorphous(1-4). Here we report MgO and Nd2O3 ceramic phases with special atomic arrangements that should belong to a category of solids different from these three well known categories by combining state-of-the-art atomic-resolution scanning transmission electron microscopy and first-principles calculations. The reported solid structure exhibits a one-dimensional (1D) long-range order with a translational periodicity and is composed of structural units that individually have atomic arrangements similar to those observed in coincidence-site lattice configurations present at grain boundaries. Regardless of the insulating nature of the bulk MgO, the bandgap of which is measured to be 7.4 eV, the MgO 1D ordered structure is a wide-bandgap semiconductor with a bandgap of 3.2 eV owing to this special atomic arrangement. The discovery of 1D ordered structures suggests that the structural categories of solids could be more abundant, with physical properties distinct from their regular counterparts.
Funding OrganizationJapan Society for the Promotion of Science (JSPS) ; MEXT ; Key Research Program of Frontier Sciences, CAS ; National Natural Sciences Foundation of China ; 'Thousand Youth Talents Plan' of China ; National Natural Science Foundation of China
DOI10.1038/s41563-018-0240-0
Indexed BySCI
Language英语
Funding ProjectJapan Society for the Promotion of Science (JSPS)[JP17H06094] ; MEXT[12024046] ; Key Research Program of Frontier Sciences, CAS[QYZDY-SSW-JSC027] ; National Natural Sciences Foundation of China[51771200] ; 'Thousand Youth Talents Plan' of China ; National Natural Science Foundation of China[11332013]
WOS Research AreaChemistry ; Materials Science ; Physics
WOS SubjectChemistry, Physical ; Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter
WOS IDWOS:000452876200010
PublisherNATURE PUBLISHING GROUP
Citation statistics
Cited Times:16[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/130850
Collection中国科学院金属研究所
Corresponding AuthorChen, Chunlin; Ikuhara, Yuichi
Affiliation1.Tohoku Univ, Adv Inst Mat Res, Aoba Ku, Sendai, Miyagi, Japan
2.Chongqing Univ, Coll Aerosp Engn, Chongqing, Peoples R China
3.Chinese Acad Sci, Shenyang Natl Lab Mat Sci, Inst Met Res, Shenyang, Liaoning, Peoples R China
4.Univ Tokyo, Inst Engn Innovat, Bunkyo Ku, Tokyo, Japan
5.Japan Fine Ceram Ctr, Nanostruct Res Lab, Atsuta Ku, Nagoya, Aichi, Japan
Recommended Citation
GB/T 7714
Yin, Deqiang,Chen, Chunlin,Saito, Mitsuhiro,et al. Ceramic phases with one-dimensional long-range order[J]. NATURE MATERIALS,2019,18(1):19-+.
APA Yin, Deqiang,Chen, Chunlin,Saito, Mitsuhiro,Inoue, Kazutoshi,&Ikuhara, Yuichi.(2019).Ceramic phases with one-dimensional long-range order.NATURE MATERIALS,18(1),19-+.
MLA Yin, Deqiang,et al."Ceramic phases with one-dimensional long-range order".NATURE MATERIALS 18.1(2019):19-+.
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