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Ceramic phases with one-dimensional long-range order
Yin, Deqiang1,2; Chen, Chunlin1,3; Saito, Mitsuhiro1,4; Inoue, Kazutoshi1; Ikuhara, Yuichi1,4,5
通讯作者Chen, Chunlin(clchen@imr.ac.cn) ; Ikuhara, Yuichi(ikuhara@sigma.t.u-tokyo.ac.jp)
2019
发表期刊NATURE MATERIALS
ISSN1476-1122
卷号18期号:1页码:19-+
摘要Solids are generally classified into three categories based on their atomic arrangement: crystalline, quasicrystalline and amorphous(1-4). Here we report MgO and Nd2O3 ceramic phases with special atomic arrangements that should belong to a category of solids different from these three well known categories by combining state-of-the-art atomic-resolution scanning transmission electron microscopy and first-principles calculations. The reported solid structure exhibits a one-dimensional (1D) long-range order with a translational periodicity and is composed of structural units that individually have atomic arrangements similar to those observed in coincidence-site lattice configurations present at grain boundaries. Regardless of the insulating nature of the bulk MgO, the bandgap of which is measured to be 7.4 eV, the MgO 1D ordered structure is a wide-bandgap semiconductor with a bandgap of 3.2 eV owing to this special atomic arrangement. The discovery of 1D ordered structures suggests that the structural categories of solids could be more abundant, with physical properties distinct from their regular counterparts.
资助者Japan Society for the Promotion of Science (JSPS) ; MEXT ; Key Research Program of Frontier Sciences, CAS ; National Natural Sciences Foundation of China ; 'Thousand Youth Talents Plan' of China ; National Natural Science Foundation of China
DOI10.1038/s41563-018-0240-0
收录类别SCI
语种英语
资助项目Japan Society for the Promotion of Science (JSPS)[JP17H06094] ; MEXT[12024046] ; Key Research Program of Frontier Sciences, CAS[QYZDY-SSW-JSC027] ; National Natural Sciences Foundation of China[51771200] ; 'Thousand Youth Talents Plan' of China ; National Natural Science Foundation of China[11332013]
WOS研究方向Chemistry ; Materials Science ; Physics
WOS类目Chemistry, Physical ; Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter
WOS记录号WOS:000452876200010
出版者NATURE PUBLISHING GROUP
引用统计
被引频次:19[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/130850
专题中国科学院金属研究所
通讯作者Chen, Chunlin; Ikuhara, Yuichi
作者单位1.Tohoku Univ, Adv Inst Mat Res, Aoba Ku, Sendai, Miyagi, Japan
2.Chongqing Univ, Coll Aerosp Engn, Chongqing, Peoples R China
3.Chinese Acad Sci, Shenyang Natl Lab Mat Sci, Inst Met Res, Shenyang, Liaoning, Peoples R China
4.Univ Tokyo, Inst Engn Innovat, Bunkyo Ku, Tokyo, Japan
5.Japan Fine Ceram Ctr, Nanostruct Res Lab, Atsuta Ku, Nagoya, Aichi, Japan
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GB/T 7714
Yin, Deqiang,Chen, Chunlin,Saito, Mitsuhiro,et al. Ceramic phases with one-dimensional long-range order[J]. NATURE MATERIALS,2019,18(1):19-+.
APA Yin, Deqiang,Chen, Chunlin,Saito, Mitsuhiro,Inoue, Kazutoshi,&Ikuhara, Yuichi.(2019).Ceramic phases with one-dimensional long-range order.NATURE MATERIALS,18(1),19-+.
MLA Yin, Deqiang,et al."Ceramic phases with one-dimensional long-range order".NATURE MATERIALS 18.1(2019):19-+.
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