| Methanol to Propylene over Foam SiC-Supported ZSM-5 Catalyst: Performance of Multiple Reaction-Regeneration Cycles | |
| Liao, Zuwei1; Xu, Ting2; Jiang, Yuntao2; Jiang, Binbo2; Wang, Jingdai1; Yang, Yongrong1; Jiao, Yilai3; Yang, Zhenming3; Zhang, Jinsong3 | |
| Corresponding Author | Yang, Yongrong(yangyr@zju.edu.cn) |
| 2019-01-09 | |
| Source Publication | INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
 |
| ISSN | 0888-5885 |
| Volume | 58Issue:1Pages:27-33 |
| Abstract | Due to the superior performance in thermal conductivity and mechanical strength, the foam SiC-supported ZSM-S catalyst is favorable in fixed bed methanol-to-propylene (MTP) reactions, where the temperature distribution and pressure drop are strictly controlled. However, its performance and service life in multiple reaction-regeneration cycles has not been proved yet. Both the activity and selectivity of the catalyst will be tested in six reaction-regeneration cycles in a fixed bed reactor. In addition, the properties of the catalyst during the fourth cycle were characterized by various techniques (scanning electron microscopy, Brunauer-Emmett-Teller, Al-27 nuclear magnetic resonance). The results show that, as the reaction progresses, the catalyst continuously deposits carbon, and the local high temperature of carbon burning during regeneration leads to the removal of aluminum from the zeolite framework. Therefore, the catalyst life in one single process increases first and then decreases. At the same time, the propylene selectivity also experiences rapid rising, steady rising, and rapid descent periods; the steady rising period is the best MTP reaction period of operation. |
| Funding Organization | National Natural Science Foundation of China ; National Science Fund for Distinguished Young Scholars |
| DOI | 10.1021/acs.iecr.8b02114 |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | National Natural Science Foundation of China[21822809] ; National Natural Science Foundation of China[61590925] ; National Science Fund for Distinguished Young Scholars[21525627] |
| WOS Research Area | Engineering |
| WOS Subject | Engineering, Chemical |
| WOS ID | WOS:000455690400005 |
| Publisher | AMER CHEMICAL SOC |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.imr.ac.cn/handle/321006/131419 |
| Collection | 中国科学院金属研究所 |
| Corresponding Author | Yang, Yongrong |
| Affiliation | 1.Zhejiang Univ, Coll Chem & Biol Engn, State Key Lab Chem Engn, Hangzhou 310027, Zhejiang, Peoples R China 2.Zhejiang Univ, Zhejiang Prov Key Lab Adv Chem Engn Manufacture T, Coll Chem & Biol Engn, Hangzhou 310027, Zhejiang, Peoples R China 3.Chinese Acad Sci, Shenyang Natl Lab Mat Sci, Inst Met Res, 72 Wenhua Rd, Shenyang 110016, Liaoning, Peoples R China |
| Recommended Citation GB/T 7714 | Liao, Zuwei,Xu, Ting,Jiang, Yuntao,et al. Methanol to Propylene over Foam SiC-Supported ZSM-5 Catalyst: Performance of Multiple Reaction-Regeneration Cycles[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2019,58(1):27-33. |
| APA | Liao, Zuwei.,Xu, Ting.,Jiang, Yuntao.,Jiang, Binbo.,Wang, Jingdai.,...&Zhang, Jinsong.(2019).Methanol to Propylene over Foam SiC-Supported ZSM-5 Catalyst: Performance of Multiple Reaction-Regeneration Cycles.INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,58(1),27-33. |
| MLA | Liao, Zuwei,et al."Methanol to Propylene over Foam SiC-Supported ZSM-5 Catalyst: Performance of Multiple Reaction-Regeneration Cycles".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 58.1(2019):27-33. |
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