Methanol to Propylene over Foam SiC-Supported ZSM-5 Catalyst: Performance of Multiple Reaction-Regeneration Cycles

doi:10.1021/acs.iecr.8b02114

IMR OpenIR

	Methanol to Propylene over Foam SiC-Supported ZSM-5 Catalyst: Performance of Multiple Reaction-Regeneration Cycles
	Liao, Zuwei 1; Xu, Ting 2; Jiang, Yuntao 2; Jiang, Binbo 2; Wang, Jingdai 1; Yang, Yongrong 1; Jiao, Yilai 3; Yang, Zhenming 3; Zhang, Jinsong 3
通讯作者	Yang, Yongrong(yangyr@zju.edu.cn)
	2019-01-09
发表期刊	INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
ISSN	0888-5885
卷号	58 期号:1 页码:27-33
摘要	Due to the superior performance in thermal conductivity and mechanical strength, the foam SiC-supported ZSM-S catalyst is favorable in fixed bed methanol-to-propylene (MTP) reactions, where the temperature distribution and pressure drop are strictly controlled. However, its performance and service life in multiple reaction-regeneration cycles has not been proved yet. Both the activity and selectivity of the catalyst will be tested in six reaction-regeneration cycles in a fixed bed reactor. In addition, the properties of the catalyst during the fourth cycle were characterized by various techniques (scanning electron microscopy, Brunauer-Emmett-Teller, Al-27 nuclear magnetic resonance). The results show that, as the reaction progresses, the catalyst continuously deposits carbon, and the local high temperature of carbon burning during regeneration leads to the removal of aluminum from the zeolite framework. Therefore, the catalyst life in one single process increases first and then decreases. At the same time, the propylene selectivity also experiences rapid rising, steady rising, and rapid descent periods; the steady rising period is the best MTP reaction period of operation.
资助者	National Natural Science Foundation of China ; National Science Fund for Distinguished Young Scholars
DOI	10.1021/acs.iecr.8b02114
收录类别	SCI
语种	英语
资助项目	National Natural Science Foundation of China[21822809] ; National Natural Science Foundation of China[61590925] ; National Science Fund for Distinguished Young Scholars[21525627]
WOS研究方向	Engineering
WOS类目	Engineering, Chemical
WOS记录号	WOS:000455690400005
出版者	AMER CHEMICAL SOC
引用统计	被引频次：16[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/131419
专题	中国科学院金属研究所
通讯作者	Yang, Yongrong
作者单位	1.Zhejiang Univ, Coll Chem & Biol Engn, State Key Lab Chem Engn, Hangzhou 310027, Zhejiang, Peoples R China 2.Zhejiang Univ, Zhejiang Prov Key Lab Adv Chem Engn Manufacture T, Coll Chem & Biol Engn, Hangzhou 310027, Zhejiang, Peoples R China 3.Chinese Acad Sci, Shenyang Natl Lab Mat Sci, Inst Met Res, 72 Wenhua Rd, Shenyang 110016, Liaoning, Peoples R China
推荐引用方式 GB/T 7714	Liao, Zuwei,Xu, Ting,Jiang, Yuntao,et al. Methanol to Propylene over Foam SiC-Supported ZSM-5 Catalyst: Performance of Multiple Reaction-Regeneration Cycles[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2019,58(1):27-33.
APA	Liao, Zuwei.,Xu, Ting.,Jiang, Yuntao.,Jiang, Binbo.,Wang, Jingdai.,...&Zhang, Jinsong.(2019).Methanol to Propylene over Foam SiC-Supported ZSM-5 Catalyst: Performance of Multiple Reaction-Regeneration Cycles.INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,58(1),27-33.
MLA	Liao, Zuwei,et al."Methanol to Propylene over Foam SiC-Supported ZSM-5 Catalyst: Performance of Multiple Reaction-Regeneration Cycles".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 58.1(2019):27-33.