| Hierarchical Fe-ZSM-5/SiC foam catalyst as the foam bed catalytic reactor (FBCR) for catalytic wet peroxide oxidation (CWPO) | |
| Ou, Xiaoxia1; Pilitsis, Fotios1; Jiao, Yilai1,2; Zhang, Yong3; Xu, Shaojun1; Jennings, Martin4; Yang, Yi3; Taylor, S. F. Rebecca1; Garforth, Arthur1; Zhang, Huiping3; Hardacre, Christopher1; Yan, Ying3; Fan, Xiaolei1 | |
| Corresponding Author | Hardacre, Christopher(c.hardacre@manchester.ac.uk) ; Yan, Ying(yingyan@scut.edu.cn) ; Fan, Xiaolei(xiaolei.fan@manchester.ac.uk) |
| 2019-04-15 | |
| Source Publication | CHEMICAL ENGINEERING JOURNAL
 |
| ISSN | 1385-8947 |
| Volume | 362Pages:53-62 |
| Abstract | Structured Fe-ZSM-5 zeolite supported on silicon carbide (SiC) foam catalyst was develop and applied as the packed foam bed catalytic reactor (FBCR) to the liquid phase catalytic wet peroxide oxidation (CWPO) of phenol under flow conditions. Fe catalysts were uniformly incorporated into ZSM-5 coatings using chemical vapour deposition (CVD). Fluid flow analysis of FBCR was performed by varying liquid flow rate, showing the transition of reactor type from the plug flow reactor to the continuous stirred tank reactor at about 1 ml min(-1). Systematic investigation of CWPO within Fe-ZSM-5/SiC FBCRs identified the optimum condition of operating the FBCR (80 mm bed length) as at 60 degrees C and 1 ml min(-1) with the turnover frequency (TOF) of 95 h(-1) for phenol degradation (apparent activation energy = 3.4 kJ mol(-1)) and total organic carbon (TOC) conversion of 45.5%. It was believed that the enhanced macromixing promoted by cellular foam supports was accountable for the observed catalytic performance. The longevity of FBCR under flow conditions was also assessed, showing its good stability over 24 h, as well as the potential for practical adoption. |
| Keyword | SiC foam Structured catalyst Chemical vapour deposition (CVD) Catalytic wet peroxide oxidation (CWPO) Macromixing |
| Funding Organization | Engineering and Physical Sciences Research Council ; Guangzhou Elite Project scholarship ; CEAS postgraduate research scholarship, The University of Manchester ; Liaoning Provincial Natural Science Foundation of China ; China Scholarship Council (CSC) ; Higher Education Innovation Funded 'Knowledge and Innovation Hub for Environmental Sustainability' at The University of Manchester ; National Natural Science Foundation of China ; Pearl River S&T Nova Program of Guangzhou |
| DOI | 10.1016/j.cej.2019.01.019 |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | Engineering and Physical Sciences Research Council[EP/R000670/1] ; Guangzhou Elite Project scholarship ; CEAS postgraduate research scholarship, The University of Manchester ; Liaoning Provincial Natural Science Foundation of China[20180510012] ; China Scholarship Council (CSC)[201604910181] ; Higher Education Innovation Funded 'Knowledge and Innovation Hub for Environmental Sustainability' at The University of Manchester ; National Natural Science Foundation of China[21776106] ; National Natural Science Foundation of China[21376101] ; Pearl River S&T Nova Program of Guangzhou[201610010171] |
| WOS Research Area | Engineering |
| WOS Subject | Engineering, Environmental ; Engineering, Chemical |
| WOS ID | WOS:000457863500006 |
| Publisher | ELSEVIER SCIENCE SA |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.imr.ac.cn/handle/321006/131504 |
| Collection | 中国科学院金属研究所 |
| Corresponding Author | Hardacre, Christopher; Yan, Ying; Fan, Xiaolei |
| Affiliation | 1.Univ Manchester, Sch Chem Engn & Analyt Sci, Oxford Rd, Manchester, Lancs, England 2.Chinese Acad Sci, Shenyang Natl Lab Mat Sci, Inst Met Res, 72 Wenhua Rd, Shenyang 110016, Peoples R China 3.South China Univ Technol, Sch Chem & Chem Engn, Guangzhou 510640, Guangdong, Peoples R China 4.Univ Manchester, Sch Chem, Oxford Rd, Manchester, Lancs, England |
| Recommended Citation GB/T 7714 | Ou, Xiaoxia,Pilitsis, Fotios,Jiao, Yilai,et al. Hierarchical Fe-ZSM-5/SiC foam catalyst as the foam bed catalytic reactor (FBCR) for catalytic wet peroxide oxidation (CWPO)[J]. CHEMICAL ENGINEERING JOURNAL,2019,362:53-62. |
| APA | Ou, Xiaoxia.,Pilitsis, Fotios.,Jiao, Yilai.,Zhang, Yong.,Xu, Shaojun.,...&Fan, Xiaolei.(2019).Hierarchical Fe-ZSM-5/SiC foam catalyst as the foam bed catalytic reactor (FBCR) for catalytic wet peroxide oxidation (CWPO).CHEMICAL ENGINEERING JOURNAL,362,53-62. |
| MLA | Ou, Xiaoxia,et al."Hierarchical Fe-ZSM-5/SiC foam catalyst as the foam bed catalytic reactor (FBCR) for catalytic wet peroxide oxidation (CWPO)".CHEMICAL ENGINEERING JOURNAL 362(2019):53-62. |
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