Facile-fabricated iron oxide nanorods as a catalyst for hydrogenation of nitrobenzene | |
Ma, Yanshuang1,2; Zhang, Liyun1; Shi, Wen1,2; Niu, Yiming1,2; Zhang, Bingsen1; Su, Dangsheng1 | |
通讯作者 | Zhang, Bingsen(bszhang@imr.ac.cn) ; Su, Dangsheng(dssu@imr.ac.cn) |
2019 | |
发表期刊 | CHINESE CHEMICAL LETTERS
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ISSN | 1001-8417 |
卷号 | 30期号:1页码:183-186 |
摘要 | beta-FeOOH nanorods were prepared by a poly ethylene glycol (PEG) assisted precipitation of FeCl3 center dot 6H(2)O aqueous solution with urea. Na2CO3 aqueous solution was introduced to maintain their shapes under annealing. The one-dimensional porous iron oxide nanorods were synthesized successfully. The asprepared catalysts were characterized by X-ray diffraction, transmission electron microscopy, N-2 adsorption-desorption isotherms and X-ray photoelectron spectroscopy. The hydrogenation of nitrobenzene to aniline was taken as probe reaction to evaluate their catalytic performance. FeOOH (iron oxides hydroxide) nanorods, fabricated by annealing beta-FeOOH nanorods at 250 degrees C in Ar atmosphere for 4 h, exhibited high catalytic activity for the transfer hydrogenation of nitrobenzene to aniline with hydrazine hydrate as hydrogen donors. (C) 2018 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved. |
关键词 | Microstructure beta-FeOOH Iron oxide hydroxide Transfer hydrogenation Oxygen species |
资助者 | National Natural Science Foundation of China ; Youth Innovation Promotion Association CAS ; Strategic Priority Research Program of the Chinese Academy of Sciences |
DOI | 10.1016/j.cclet.2018.04.034 |
收录类别 | SCI |
语种 | 英语 |
资助项目 | National Natural Science Foundation of China[91545119] ; National Natural Science Foundation of China[21761132025] ; National Natural Science Foundation of China[21773269] ; National Natural Science Foundation of China[21703262] ; National Natural Science Foundation of China[51521091] ; Youth Innovation Promotion Association CAS[2015152] ; Strategic Priority Research Program of the Chinese Academy of Sciences[XDA09030103] |
WOS研究方向 | Chemistry |
WOS类目 | Chemistry, Multidisciplinary |
WOS记录号 | WOS:000458344400042 |
出版者 | ELSEVIER SCIENCE INC |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.imr.ac.cn/handle/321006/131555 |
专题 | 中国科学院金属研究所 |
通讯作者 | Zhang, Bingsen; Su, Dangsheng |
作者单位 | 1.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Liaoning, Peoples R China 2.Univ Sci & Technol China, Sch Mat Sci & Engn, Hefei 230026, Anhui, Peoples R China |
推荐引用方式 GB/T 7714 | Ma, Yanshuang,Zhang, Liyun,Shi, Wen,et al. Facile-fabricated iron oxide nanorods as a catalyst for hydrogenation of nitrobenzene[J]. CHINESE CHEMICAL LETTERS,2019,30(1):183-186. |
APA | Ma, Yanshuang,Zhang, Liyun,Shi, Wen,Niu, Yiming,Zhang, Bingsen,&Su, Dangsheng.(2019).Facile-fabricated iron oxide nanorods as a catalyst for hydrogenation of nitrobenzene.CHINESE CHEMICAL LETTERS,30(1),183-186. |
MLA | Ma, Yanshuang,et al."Facile-fabricated iron oxide nanorods as a catalyst for hydrogenation of nitrobenzene".CHINESE CHEMICAL LETTERS 30.1(2019):183-186. |
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