2D titanium carbide (MXene) electrodes with lower-F surface for high performance lithium-ion batteries | |
Lu, Ming1,2; Li, Haojie2,3; Han, Wenjuan2,4; Chen, Junnan2; Shi, Wen2; Wang, Jiaheng3; Meng, Xiang-Min5; Qi, Jingang6; Li, Haibo4; Zhang, Bingsen2; Zhang, Wei1; Zheng, Weitao1 | |
Corresponding Author | Zhang, Bingsen(bszhang@imr.ac.cn) ; Zhang, Wei(weizhang@jlu.edu.cn) ; Zheng, Weitao(wtzheng@jlu.edu.cn) |
2019-04-01 | |
Source Publication | JOURNAL OF ENERGY CHEMISTRY
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ISSN | 2095-4956 |
Volume | 31Pages:148-153 |
Abstract | MXene has shown distinctive advantages as anode materials of lithium-ion batteries. However, local surface chemistry, which was confirmed that can block ion transfer and limit redox reaction, has a significant effect on electrochemical performance. Herein, annealing MXene under hydrogen was employed for removing -F and turning -OH to -O terminations. We demonstrate that it improves the kinetics of Li-ion transport between the electrolyte and electrode. As a result, a lower interfacial charge transfer impedance was obtained. The electrochemical measurement exhibited that a nearly 2-fold increase of specific capacity was achieved for the annealed MXene. (C) 2018 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. and Science Press. All rights reserved. |
Keyword | Ti3C2 MXene Li-ion Hydrogen -F content |
Funding Organization | National Key R&D Program of China ; Jilin Province/Jilin University co-Construction Project-Funds for New Materials ; National Natural Science Foundation of China ; Youth Innovation Promotion Association CAS ; Strategic Priority Research Program of the Chinese Academy of Sciences Chinese Academy of Sciences ; Program for JLU Science and Technology Innovative Research Team (JLUSTIRT) ; Double-First Class Discipline for Materials Science Engineering |
DOI | 10.1016/j.jechem.2018.05.017 |
Indexed By | SCI |
Language | 英语 |
Funding Project | National Key R&D Program of China[2016YFA0200400] ; Jilin Province/Jilin University co-Construction Project-Funds for New Materials[SXGJSF2017-3] ; Jilin Province/Jilin University co-Construction Project-Funds for New Materials[Branch-2/440050316A36] ; National Natural Science Foundation of China[91545119] ; National Natural Science Foundation of China[21761132025] ; National Natural Science Foundation of China[21773269] ; National Natural Science Foundation of China[51372095] ; Youth Innovation Promotion Association CAS[2015152] ; Strategic Priority Research Program of the Chinese Academy of Sciences Chinese Academy of Sciences[XDA09030103] ; Strategic Priority Research Program of the Chinese Academy of Sciences Chinese Academy of Sciences[XDA09040203] ; Program for JLU Science and Technology Innovative Research Team (JLUSTIRT) ; Double-First Class Discipline for Materials Science Engineering |
WOS Research Area | Chemistry ; Energy & Fuels ; Engineering |
WOS Subject | Chemistry, Applied ; Chemistry, Physical ; Energy & Fuels ; Engineering, Chemical |
WOS ID | WOS:000460174000018 |
Publisher | ELSEVIER SCIENCE BV |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.imr.ac.cn/handle/321006/132349 |
Collection | 中国科学院金属研究所 |
Corresponding Author | Zhang, Bingsen; Zhang, Wei; Zheng, Weitao |
Affiliation | 1.Jilin Univ, Electron Microscopy Ctr, Int Ctr Future Sci, Sch Mat Sci & Engn,Key Lab Automobile Mat MOE, Changchun 130012, Jilin, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Liaoning, Peoples R China 3.Hefei Univ Technol, Dept Mech Engn, Xuancheng 242000, Anhui, Peoples R China 4.Jilin Normal Univ, Minist Educ, Key Lab Funct Mat Phys & Chem, Siping 136000, Jilin, Peoples R China 5.Chinese Acad Sci, Tech Inst Phys & Chem, Key Lab Photochem Convers & Optoelect Mat, Beijing 100190, Peoples R China 6.Liaoning Univ Technol, Sch Mat Sci & Engn, Jinzhou 121001, Liaoning, Peoples R China |
Recommended Citation GB/T 7714 | Lu, Ming,Li, Haojie,Han, Wenjuan,et al. 2D titanium carbide (MXene) electrodes with lower-F surface for high performance lithium-ion batteries[J]. JOURNAL OF ENERGY CHEMISTRY,2019,31:148-153. |
APA | Lu, Ming.,Li, Haojie.,Han, Wenjuan.,Chen, Junnan.,Shi, Wen.,...&Zheng, Weitao.(2019).2D titanium carbide (MXene) electrodes with lower-F surface for high performance lithium-ion batteries.JOURNAL OF ENERGY CHEMISTRY,31,148-153. |
MLA | Lu, Ming,et al."2D titanium carbide (MXene) electrodes with lower-F surface for high performance lithium-ion batteries".JOURNAL OF ENERGY CHEMISTRY 31(2019):148-153. |
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