| Ratio of total acidity to pH value of coating bath: A new strategy towards phosphate conversion coatings with optimized corrosion resistance for magnesium alloys | |
| Zhang, Chunyan1,3; Liao, Shangju3; Yu, Baoxing3; Lu, Xiaopeng2; Chen, Xiao-Bo4; Zhang, Tao1,2,3; Wang, Fuhui2 | |
| Corresponding Author | Lu, Xiaopeng(luxiaopeng@mail.neu.edu.cn) ; Zhang, Tao(zhangtao@mail.neu.edu.cn) |
| 2019-04-15 | |
| Source Publication | CORROSION SCIENCE
 |
| ISSN | 0010-938X |
| Volume | 150Pages:279-295 |
| Abstract | In this work, with the aid of thermodynamic equilibrium calculations, a crucial contributor, i.e. total acidity/pH value (TA/pH), was proposed for the first time to guide the design of the chemical formulation of metal phosphate-based conversion coatings having excellent corrosion resistance for Mg alloys. The present study and published works were compared to validate the proposed theory and correlation between the TA/pH and corrosion resistance of the resulting coatings. A significant contribution of this work was the elucidation of the kinetic role of the buffering nature of chemical bath in regulating the formation of corrosion resistant phosphate conversion coatings. |
| Keyword | Magnesium XRD polarization curves SEM interfaces oxide coatings |
| Funding Organization | National Natural Science Foundation of China ; Young Elite Scientists Sponsorship Program by CAST ; National program for the Young Top-notch Professionals ; Fundamental Research Funds for the Central Universities ; Program of Hundred Talents of Chinese Academy of Sciences ; Key Laboratory of Superlight Material and Surface Technology (Harbin Engineering University), Ministry of Education |
| DOI | 10.1016/j.corsci.2019.01.046 |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | National Natural Science Foundation of China[51531007] ; National Natural Science Foundation of China[51771050] ; National Natural Science Foundation of China[U1737102] ; Young Elite Scientists Sponsorship Program by CAST[2017QNRC001] ; National program for the Young Top-notch Professionals ; Fundamental Research Funds for the Central Universities[N170205002] ; Fundamental Research Funds for the Central Universities[N170203006] ; Program of Hundred Talents of Chinese Academy of Sciences ; Key Laboratory of Superlight Material and Surface Technology (Harbin Engineering University), Ministry of Education |
| WOS Research Area | Materials Science ; Metallurgy & Metallurgical Engineering |
| WOS Subject | Materials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering |
| WOS ID | WOS:000462108000026 |
| Publisher | PERGAMON-ELSEVIER SCIENCE LTD |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.imr.ac.cn/handle/321006/132555 |
| Collection | 中国科学院金属研究所 |
| Corresponding Author | Lu, Xiaopeng; Zhang, Tao |
| Affiliation | 1.Harbin Engn Univ, Minist Educ, Key Lab Superlight Mat & Surface Technol, Corros & Protect Lab, Nantong ST 145, Harbin 150001, Heilongjiang, Peoples R China 2.Northeastern Univ, Shenyang Natl Lab Mat Sci, Corros & Protect Div, 3-11 Wenhua RD, Shenyang 110819, Liaoning, Peoples R China 3.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Corros & Protect Div, Wencui RD 62, Shenyang 110016, Liaoning, Peoples R China 4.RMIT Univ, Sch Engn, Carlton, Vic 3053, Australia |
| Recommended Citation GB/T 7714 | Zhang, Chunyan,Liao, Shangju,Yu, Baoxing,et al. Ratio of total acidity to pH value of coating bath: A new strategy towards phosphate conversion coatings with optimized corrosion resistance for magnesium alloys[J]. CORROSION SCIENCE,2019,150:279-295. |
| APA | Zhang, Chunyan.,Liao, Shangju.,Yu, Baoxing.,Lu, Xiaopeng.,Chen, Xiao-Bo.,...&Wang, Fuhui.(2019).Ratio of total acidity to pH value of coating bath: A new strategy towards phosphate conversion coatings with optimized corrosion resistance for magnesium alloys.CORROSION SCIENCE,150,279-295. |
| MLA | Zhang, Chunyan,et al."Ratio of total acidity to pH value of coating bath: A new strategy towards phosphate conversion coatings with optimized corrosion resistance for magnesium alloys".CORROSION SCIENCE 150(2019):279-295. |
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