A Desolvated Solid-Solid-Solid Interface for a High-Capacitance Electric Double Layer

doi:10.1002/aenm.201803715

IMR OpenIR

	A Desolvated Solid-Solid-Solid Interface for a High-Capacitance Electric Double Layer
	Wang, Yu-Zuo 1,2; Shan, Xu-Yi 1; Ma, Li-Po 3; Wang, Jia-Wei 3; Wang, Da-Wei 4; Peng, Zhang-Quan 3; Cheng, Hui-Ming 1,5,6; Li, Feng 1,7
通讯作者	Wang, Da-Wei(da-wei.wang@unsw.edu.au) ; Li, Feng(fli@imr.ac.cn)
	2019-03-27
发表期刊	ADVANCED ENERGY MATERIALS
ISSN	1614-6832
卷号	9 期号:12 页码:6
摘要	Understanding the electric double layer is essential for achieving efficient electrochemical energy storage technologies. A conventional solid-liquid electrode interface suffers from serious self-discharge and a narrow voltage window, which makes the development of a solid-solid interface imperative. However, an in-depth understanding of the electric double layer with a solid- solid interface is lacking. Here, a solid-solid interfacial electric double layer is proposed with excellent electrochemical performance. The solid layer is constructed by the electrochemical decomposition of lithium difluora(oxalate) borate, which provides a desolvated environment for the establishment of a electric double layer. This makes a stronger interaction between the electrode surface and the ions. Based on this unique property, it is found that the solid- solid interfacial electric double layer has an increased capacitance, which suggests a way to develop high-energy electrochemical capacitors.
关键词	capacitance electric double layers solid-solid interfaces
资助者	National Science Foundation of China ; Ministry of Science and Technology of China ; Key Research Program of the Chinese Academy of Sciences
DOI	10.1002/aenm.201803715
收录类别	SCI
语种	英语
资助项目	National Science Foundation of China[51525206] ; National Science Foundation of China[51521091] ; National Science Foundation of China[51372253] ; Ministry of Science and Technology of China[2016YFA0200100] ; Ministry of Science and Technology of China[2016YFB0100100] ; Key Research Program of the Chinese Academy of Sciences[KGZD-EW-T06]
WOS研究方向	Chemistry ; Energy & Fuels ; Materials Science ; Physics
WOS类目	Chemistry, Physical ; Energy & Fuels ; Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter
WOS记录号	WOS:000463288400011
出版者	WILEY-V C H VERLAG GMBH
引用统计	被引频次：39[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/132644
专题	中国科学院金属研究所
通讯作者	Wang, Da-Wei; Li, Feng
作者单位	1.Chinese Acad Sci, Shenyang Natl Lab Mat Sci, Inst Met Res, Shenyang 110016, Liaoning, Peoples R China 2.Northeastern Univ, Key Lab Anisotropy & Texture Mat, Shenyang 110819, Liaoning, Peoples R China 3.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Electroanalyt Chem, Changchun 130022, Jilin, Peoples R China 4.Univ New South Wales, Sch Chem Engn, Sydney, NSW 2052, Australia 5.Tsinghua Univ, Tsinghua Berkeley Shenzhen Inst, Shenzhen 518055, Peoples R China 6.King Abdulaziz Univ, Ctr Excellence Environm Studies, Jeddah 21589, Saudi Arabia 7.Univ Sci & Technol China, Sch Mat Sci & Engn, Hefei 230026, Anhui, Peoples R China
推荐引用方式 GB/T 7714	Wang, Yu-Zuo,Shan, Xu-Yi,Ma, Li-Po,et al. A Desolvated Solid-Solid-Solid Interface for a High-Capacitance Electric Double Layer[J]. ADVANCED ENERGY MATERIALS,2019,9(12):6.
APA	Wang, Yu-Zuo.,Shan, Xu-Yi.,Ma, Li-Po.,Wang, Jia-Wei.,Wang, Da-Wei.,...&Li, Feng.(2019).A Desolvated Solid-Solid-Solid Interface for a High-Capacitance Electric Double Layer.ADVANCED ENERGY MATERIALS,9(12),6.
MLA	Wang, Yu-Zuo,et al."A Desolvated Solid-Solid-Solid Interface for a High-Capacitance Electric Double Layer".ADVANCED ENERGY MATERIALS 9.12(2019):6.