SiC foam based structured catalyst for process intensification in oxidative dehydrogenation of 1-butene to butadiene

doi:10.1016/j.cep.2019.02.010

IMR OpenIR

	SiC foam based structured catalyst for process intensification in oxidative dehydrogenation of 1-butene to butadiene
	Jiang, Renzheng 1,2; Jiao, Yilai 2; Xie, Yingpeng 1; Yang, Zhenming 2; Zhang, Jinsong 2
通讯作者	Jiang, Renzheng(jshzhang@imr.ac.cn) ; Zhang, Jinsong(jiangrenzheng@syuct.edu.cn)
	2019-03-01
发表期刊	CHEMICAL ENGINEERING AND PROCESSING-PROCESS INTENSIFICATION
ISSN	0255-2701
卷号	137 页码:108-115
摘要	Oxidative dehydrogenation of butenes to butadiene is a highly exothermic and diffusion-controlled reaction. The problems of high adiabatic temperature rise and pressure drop, low gas velocity and conversion, as well as high consumption of water exist in the conventional reactors. In order to ease these problems, SiC foam supporting ZnFe2O4-alpha-Fe2O3 (ZnFe2O4-alpha-Fe2O3/SiC foam) structured catalyst was prepared by a slurry-coating method. Its performance was systematically studied with varied reaction temperature, oxygen/1-butene molar ratio, steam/1-butene molar ratio and 1-butene gaseous hourly space velocity (GHSV), respectively. The results showed that the 1-butene conversion and butadiene selectivity over the structured catalyst could reach about 87% and 91%, respectively, at a 1-butene GHSV of 300 h(-1), and even at a 1-butene GHSV of 600 h(-1), the conversion could still maintain at 78%, which was much better than that of the particulate catalysts. In addition, compared to the particle packed bed, the structured bed showed lower temperature rise and nearly isothermic, could lower the consumption of water and allowed to be operated with a wider range of O-2/1-butene molar ratio and a much higher 1-butene GHSV, due to its better process intensification capacity.
关键词	Structured catalyst Process intensification SiC foam Butenes oxidative dehydrogenation Ferrite
DOI	10.1016/j.cep.2019.02.010
收录类别	SCI
语种	英语
WOS研究方向	Energy & Fuels ; Engineering
WOS类目	Energy & Fuels ; Engineering, Chemical
WOS记录号	WOS:000464089000013
出版者	ELSEVIER SCIENCE SA
引用统计	被引频次：10[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/132700
专题	中国科学院金属研究所
通讯作者	Jiang, Renzheng; Zhang, Jinsong
作者单位	1.Shenyang Univ Chem Technol, Coll Chem Engn, Shenyang 110142, Liaoning, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang 110016, Liaoning, Peoples R China
推荐引用方式 GB/T 7714	Jiang, Renzheng,Jiao, Yilai,Xie, Yingpeng,et al. SiC foam based structured catalyst for process intensification in oxidative dehydrogenation of 1-butene to butadiene[J]. CHEMICAL ENGINEERING AND PROCESSING-PROCESS INTENSIFICATION,2019,137:108-115.
APA	Jiang, Renzheng,Jiao, Yilai,Xie, Yingpeng,Yang, Zhenming,&Zhang, Jinsong.(2019).SiC foam based structured catalyst for process intensification in oxidative dehydrogenation of 1-butene to butadiene.CHEMICAL ENGINEERING AND PROCESSING-PROCESS INTENSIFICATION,137,108-115.
MLA	Jiang, Renzheng,et al."SiC foam based structured catalyst for process intensification in oxidative dehydrogenation of 1-butene to butadiene".CHEMICAL ENGINEERING AND PROCESSING-PROCESS INTENSIFICATION 137(2019):108-115.