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The simplest construction of single-site catalysts by the synergism of micropore trapping and nitrogen anchoring
Zhang, Zhiqi1,2; Chen, Yugang1,2; Zhou, Liqi3,4; Chen, Chi5; Han, Zhen3,4; Zhang, Bingsen6; Wu, Qiang1,2; Yang, Lijun1,2; Du, Lingyu1,2; Bu, Yongfeng1,2; Wang, Peng3,4,7; Wang, Xizhang1,2; Yang, Hui5; Hu, Zheng1,2
Corresponding AuthorWu, Qiang(wqchem@nju.edu.cn) ; Wang, Peng(wangpeng@nju.edu.cn) ; Hu, Zheng(zhenghu@nju.edu.cn)
2019-04-10
Source PublicationNATURE COMMUNICATIONS
ISSN2041-1723
Volume10Pages:7
AbstractSingle-site catalysts feature high catalytic activity but their facile construction and durable utilization are highly challenging. Herein, we report a simple impregnation-adsorption method to construct platinum single-site catalysts by synergic micropore trapping and nitrogen anchoring on hierarchical nitrogen-doped carbon nanocages. The optimal catalyst exhibits a record-high electrocatalytic hydrogen evolution performance with low overpotential, high mass activity and long stability, much superior to the platinum-based catalysts to date. Theoretical simulations and experiments reveal that the micropores with edge-nitrogendopants favor the formation of isolated platinum atoms by the micropore trapping and nitrogen anchoring of [PtCI6](2-), followed by the spontaneous dechlorination. The platinum-nitrogen bonds are more stable than the platinum-carbon ones in the presence of adsorbed hydrogen atoms, leading to the superior hydrogen evolution stability of platinum single-atoms on nitrogen-doped carbon. This method has been successfully applied to construct the single-site catalysts of other precious metals such as palladium, gold and iridium.
Funding OrganizationNational Key Research and Development Program of China ; National Natural Science Foundation of China ; National Basic Research Program of China
DOI10.1038/s41467-019-09596-x
Indexed BySCI
Language英语
Funding ProjectNational Key Research and Development Program of China[2017YFA0206500] ; National Key Research and Development Program of China[2018YFA0209103] ; National Natural Science Foundation of China[21832003] ; National Natural Science Foundation of China[21773111] ; National Natural Science Foundation of China[51571110] ; National Natural Science Foundation of China[21573107] ; National Natural Science Foundation of China[11474147] ; National Natural Science Foundation of China[11874199] ; National Basic Research Program of China[2015CB654901]
WOS Research AreaScience & Technology - Other Topics
WOS SubjectMultidisciplinary Sciences
WOS IDWOS:000463984400006
PublisherNATURE PUBLISHING GROUP
Citation statistics
Cited Times:66[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/133010
Collection中国科学院金属研究所
Corresponding AuthorWu, Qiang; Wang, Peng; Hu, Zheng
Affiliation1.Nanjing Univ, Key Lab Mesoscop Chem, MOE, Nanjing 210023, Jiangsu, Peoples R China
2.Nanjing Univ, Jiangsu Prov Lab Nanotechnol, Sch Chem & Chem Engn, Nanjing 210023, Jiangsu, Peoples R China
3.Nanjing Univ, Natl Lab Solid State Microstruct, Coll Engn & Appl Sci, Nanjing 210093, Jiangsu, Peoples R China
4.Nanjing Univ, Collaborat Innovat Ctr Adv Microstruct, Nanjing 210093, Jiangsu, Peoples R China
5.Chinese Acad Sci, Shanghai Adv Res Inst, Shanghai 201210, Peoples R China
6.Chinese Acad Sci, Shenyang Natl Lab Mat Sci, Inst Met Res, Shenyang 110016, Liaoning, Peoples R China
7.Nanjing Univ, Res Ctr Environm Nanotechnol ReCENT, Nanjing 210023, Jiangsu, Peoples R China
Recommended Citation
GB/T 7714
Zhang, Zhiqi,Chen, Yugang,Zhou, Liqi,et al. The simplest construction of single-site catalysts by the synergism of micropore trapping and nitrogen anchoring[J]. NATURE COMMUNICATIONS,2019,10:7.
APA Zhang, Zhiqi.,Chen, Yugang.,Zhou, Liqi.,Chen, Chi.,Han, Zhen.,...&Hu, Zheng.(2019).The simplest construction of single-site catalysts by the synergism of micropore trapping and nitrogen anchoring.NATURE COMMUNICATIONS,10,7.
MLA Zhang, Zhiqi,et al."The simplest construction of single-site catalysts by the synergism of micropore trapping and nitrogen anchoring".NATURE COMMUNICATIONS 10(2019):7.
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