| Modulation of terahertz properties of 3D ceramic photonic crystals via post-creation non-metal anion doping treatment | |
| Wang, Rong1,2; Yang, Weiyi1; Gao, Shuang2; Ju, Xiaojing1,3; Zhu, Pengfei1,3; Li, Bo2; Li, Qi1 | |
| Corresponding Author | Li, Qi(qili@imr.ac.cn) |
| 2019-08-01 | |
| Source Publication | JOURNAL OF THE AMERICAN CERAMIC SOCIETY
 |
| ISSN | 0002-7820 |
| Volume | 102Issue:8Pages:4688-4697 |
| Abstract | Ceramic photonic crystals have wide application potentials for THz technology due to their characteristic strong chemical stability and high temperature resistance for demanding environment. However, it is still a challenge to modulate the THz properties of as-prepared ceramic TPCs via post-creation treatments to satisfy different application requirements. In this work, the THz properties of rutile TiO2 ceramic 3D-TPCs were modulated by non-metal anion doping of either carbon or nitrogen, which was firstly created by the direct-writing technique with a TiO2 sol-gel ink followed by the high temperature sintering process at 1200 degrees C. Calcination of the pristine rutile TiO2 ceramic 3D-TPCs in either CO or NH3 atmosphere successfully doped either C or N dopants into rutile TiO2 ceramic 3D-TPCs, respectively, which changed their dielectric properties and subsequently induced different THz properties on these ceramic 3D-TPCs with the same structure. Their THz properties were found to be largely affected by the specific nature of the dopant. Compared with the pristine rutile TiO2 ceramic 3D-TPC, the bandgap positions of both C-doped and N-doped rutile TiO2 ceramic 3D-TPCs largely shifted toward the higher frequency, while the N-doped sample demonstrated a much broader bandgap. Thus, non-metal anion doping could be an effective post-creation approach to modulate the THz properties of ceramic TPCs. |
| Keyword | 3D-terahertz photonic crystals anion doping direct-writing rutile TiO2 sol-gel ink |
| Funding Organization | Science and Technology Plan of Shenzhen City ; Basic Science Innovation Program of Shenyang National Laboratory for Materials Science ; Instrument Development Program of Shenyang National Laboratory for Materials Science ; National Key Research and Development Program of China ; National Natural Science Foundation of China |
| DOI | 10.1111/jace.16346 |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | Science and Technology Plan of Shenzhen City[JCYJ20170412171554022] ; Basic Science Innovation Program of Shenyang National Laboratory for Materials Science[2017RP290] ; Instrument Development Program of Shenyang National Laboratory for Materials Science[2017EP04] ; National Key Research and Development Program of China[2017YFB0406300] ; National Natural Science Foundation of China[51672283] ; National Natural Science Foundation of China[51602316] |
| WOS Research Area | Materials Science |
| WOS Subject | Materials Science, Ceramics |
| WOS ID | WOS:000470016900033 |
| Publisher | WILEY |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.imr.ac.cn/handle/321006/133714 |
| Collection | 中国科学院金属研究所 |
| Corresponding Author | Li, Qi |
| Affiliation | 1.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Environm Funct Mat Div, Shenyang, Liaoning, Peoples R China 2.Tsinghua Univ, Div Energy & Environm, Grad Sch Shenzhen, Shenzhen, Peoples R China 3.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang, Liaoning, Peoples R China |
| Recommended Citation GB/T 7714 | Wang, Rong,Yang, Weiyi,Gao, Shuang,et al. Modulation of terahertz properties of 3D ceramic photonic crystals via post-creation non-metal anion doping treatment[J]. JOURNAL OF THE AMERICAN CERAMIC SOCIETY,2019,102(8):4688-4697. |
| APA | Wang, Rong.,Yang, Weiyi.,Gao, Shuang.,Ju, Xiaojing.,Zhu, Pengfei.,...&Li, Qi.(2019).Modulation of terahertz properties of 3D ceramic photonic crystals via post-creation non-metal anion doping treatment.JOURNAL OF THE AMERICAN CERAMIC SOCIETY,102(8),4688-4697. |
| MLA | Wang, Rong,et al."Modulation of terahertz properties of 3D ceramic photonic crystals via post-creation non-metal anion doping treatment".JOURNAL OF THE AMERICAN CERAMIC SOCIETY 102.8(2019):4688-4697. |
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