A Deoximation Method for Deprotection of Ketones and Aldhydes Using a Graphene-Oxide-Based Co-catalysts System | |
Tong, Qiaolin1; Liu, Yang1; Gao, Xuezhi1; Fan, Zhanfang1; Liu, Tianfu2; Li, Bo2; Su, Dangsheng2,3; Wang, Qinghe1; Cheng, Maosheng1 | |
通讯作者 | Liu, Yang(y.liu@syphu.edu.cn) ; Wang, Qinghe(qinghe-wang@163.com) ; Cheng, Maosheng(mscheng@syphu.edu.cn) |
2019-07-02 | |
发表期刊 | ADVANCED SYNTHESIS & CATALYSIS
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ISSN | 1615-4150 |
卷号 | 361期号:13页码:3137-3145 |
摘要 | The deoximation of a wide range of ketoximes and aldoximes to their corresponding carbonyl compounds with high yields has been achieved using graphene oxide (GO) and sodium nitrite (NaNO2) as highly efficient catalysts and air as the green oxidant under mild conditions. The mechanism of deprotection and recycling use of catalyst were revealed in deep experiment. The carboxylic acid groups on the GO were essential for high catalytic activity. |
关键词 | Deoximation Graphene oxide Sodium nitrite Air Oximes |
资助者 | National Natural Science Foundation of China ; Program for Liaoning Innovative Talents in University ; Career Development Support Plan for Young and Middle-aged Teachers in Shenyang Pharmaceutical University |
DOI | 10.1002/adsc.201900202 |
收录类别 | SCI |
语种 | 英语 |
资助项目 | National Natural Science Foundation of China[81473087] ; National Natural Science Foundation of China[81872752] ; Program for Liaoning Innovative Talents in University[LR2017043] ; Career Development Support Plan for Young and Middle-aged Teachers in Shenyang Pharmaceutical University[ZQN2016005] |
WOS研究方向 | Chemistry |
WOS类目 | Chemistry, Applied ; Chemistry, Organic |
WOS记录号 | WOS:000484142600013 |
出版者 | WILEY-V C H VERLAG GMBH |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.imr.ac.cn/handle/321006/135256 |
专题 | 中国科学院金属研究所 |
通讯作者 | Liu, Yang; Wang, Qinghe; Cheng, Maosheng |
作者单位 | 1.Shenyang Pharmaceut Univ, Sch Pharmaceut Engn, Minist Educ, Key Lab Struct Based Drug Design & Discovery, Shenyang 110016, Liaoning, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang 110016, Liaoning, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China |
推荐引用方式 GB/T 7714 | Tong, Qiaolin,Liu, Yang,Gao, Xuezhi,et al. A Deoximation Method for Deprotection of Ketones and Aldhydes Using a Graphene-Oxide-Based Co-catalysts System[J]. ADVANCED SYNTHESIS & CATALYSIS,2019,361(13):3137-3145. |
APA | Tong, Qiaolin.,Liu, Yang.,Gao, Xuezhi.,Fan, Zhanfang.,Liu, Tianfu.,...&Cheng, Maosheng.(2019).A Deoximation Method for Deprotection of Ketones and Aldhydes Using a Graphene-Oxide-Based Co-catalysts System.ADVANCED SYNTHESIS & CATALYSIS,361(13),3137-3145. |
MLA | Tong, Qiaolin,et al."A Deoximation Method for Deprotection of Ketones and Aldhydes Using a Graphene-Oxide-Based Co-catalysts System".ADVANCED SYNTHESIS & CATALYSIS 361.13(2019):3137-3145. |
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