Metallic Nanoporous Aluminum-Magnesium Alloy for UV-Enhanced Spectroscopy | |
Ponzellini, Paolo1; Giovannini, Giorgia1; Cattarin, Sandro2; Zaccaria, Remo Proietti1,3; Marras, Sergio1; Prato, Mirko1; Schirato, Andrea4; D'Amico, Francesco5; Calandrini, Eugenio1; De Angelis, Francesco1; Yang, Wei6; Jin, Hai Jun6; Alabastri, Alessandro4; Garoli, Denis1 | |
Corresponding Author | Garoli, Denis(denis.garoli@iit.it) |
2019-08-22 | |
Source Publication | JOURNAL OF PHYSICAL CHEMISTRY C
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ISSN | 1932-7447 |
Volume | 123Issue:33Pages:20287-20296 |
Abstract | We report the first preparation of nanoporous Al-Mg alloy films by selective dissolution of Mg from a Mg-rich alloy AlxMg1-x We show how to tune the stoichiometry, the porosity, and the oxide contents in the final film by modulating the starting ratio between Al and Mg and the dealloying procedure. The obtained porous metal can be exploited for enhanced UV spectroscopy. In this respect, we experimentally demonstrate its efficacy in enhancing fluorescence and surface Raman scattering for excitation wavelengths of 360 and 257 nm, respectively. Finally, we numerically show the superior performance of the nanoporous Al-Mg alloy in the UV range when compared to equivalent porous gold structures. The large area to surface ratio provided by this material makes it a promising platform for a wide range of applications in UV/deep-UV plasmonics. |
Funding Organization | European Research Council under the Horizon 2020 Program, FET-Open: PROSEQO |
DOI | 10.1021/acs.jpcc.9b04230 |
Indexed By | SCI |
Language | 英语 |
Funding Project | European Research Council under the Horizon 2020 Program, FET-Open: PROSEQO[687089] |
WOS Research Area | Chemistry ; Science & Technology - Other Topics ; Materials Science |
WOS Subject | Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary |
WOS ID | WOS:000482545700024 |
Publisher | AMER CHEMICAL SOC |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.imr.ac.cn/handle/321006/135375 |
Collection | 中国科学院金属研究所 |
Corresponding Author | Garoli, Denis |
Affiliation | 1.Ist Italiano Tecnol, Via Morego 30, I-16163 Genoa, Italy 2.CNR, ICMATE, Corso Stati Uniti 4, I-35127 Padua, Italy 3.Chinese Acad Sci, Cixi Inst Biomed Engn, Ningbo Inst Ind Technol, 1219 Zhongguan West Rd, Ningbo 315201, Zhejiang, Peoples R China 4.Rice Univ, Elect & Comp Engn, 6100 Main St MS 378, Houston, TX 77005 USA 5.Elettra Sincrotrone Trieste Area Sci Pk, SS 14 Km 163,5, I-34012 Trieste, Italy 6.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, 72 Wenhua Rd, Shenyang 110016, Liaoning, Peoples R China |
Recommended Citation GB/T 7714 | Ponzellini, Paolo,Giovannini, Giorgia,Cattarin, Sandro,et al. Metallic Nanoporous Aluminum-Magnesium Alloy for UV-Enhanced Spectroscopy[J]. JOURNAL OF PHYSICAL CHEMISTRY C,2019,123(33):20287-20296. |
APA | Ponzellini, Paolo.,Giovannini, Giorgia.,Cattarin, Sandro.,Zaccaria, Remo Proietti.,Marras, Sergio.,...&Garoli, Denis.(2019).Metallic Nanoporous Aluminum-Magnesium Alloy for UV-Enhanced Spectroscopy.JOURNAL OF PHYSICAL CHEMISTRY C,123(33),20287-20296. |
MLA | Ponzellini, Paolo,et al."Metallic Nanoporous Aluminum-Magnesium Alloy for UV-Enhanced Spectroscopy".JOURNAL OF PHYSICAL CHEMISTRY C 123.33(2019):20287-20296. |
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