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Metallic Nanoporous Aluminum-Magnesium Alloy for UV-Enhanced Spectroscopy
Ponzellini, Paolo1; Giovannini, Giorgia1; Cattarin, Sandro2; Zaccaria, Remo Proietti1,3; Marras, Sergio1; Prato, Mirko1; Schirato, Andrea4; D'Amico, Francesco5; Calandrini, Eugenio1; De Angelis, Francesco1; Yang, Wei6; Jin, Hai Jun6; Alabastri, Alessandro4; Garoli, Denis1
通讯作者Garoli, Denis(denis.garoli@iit.it)
2019-08-22
发表期刊JOURNAL OF PHYSICAL CHEMISTRY C
ISSN1932-7447
卷号123期号:33页码:20287-20296
摘要We report the first preparation of nanoporous Al-Mg alloy films by selective dissolution of Mg from a Mg-rich alloy AlxMg1-x We show how to tune the stoichiometry, the porosity, and the oxide contents in the final film by modulating the starting ratio between Al and Mg and the dealloying procedure. The obtained porous metal can be exploited for enhanced UV spectroscopy. In this respect, we experimentally demonstrate its efficacy in enhancing fluorescence and surface Raman scattering for excitation wavelengths of 360 and 257 nm, respectively. Finally, we numerically show the superior performance of the nanoporous Al-Mg alloy in the UV range when compared to equivalent porous gold structures. The large area to surface ratio provided by this material makes it a promising platform for a wide range of applications in UV/deep-UV plasmonics.
资助者European Research Council under the Horizon 2020 Program, FET-Open: PROSEQO
DOI10.1021/acs.jpcc.9b04230
收录类别SCI
语种英语
资助项目European Research Council under the Horizon 2020 Program, FET-Open: PROSEQO[687089]
WOS研究方向Chemistry ; Science & Technology - Other Topics ; Materials Science
WOS类目Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
WOS记录号WOS:000482545700024
出版者AMER CHEMICAL SOC
引用统计
被引频次:30[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/135375
专题中国科学院金属研究所
通讯作者Garoli, Denis
作者单位1.Ist Italiano Tecnol, Via Morego 30, I-16163 Genoa, Italy
2.CNR, ICMATE, Corso Stati Uniti 4, I-35127 Padua, Italy
3.Chinese Acad Sci, Cixi Inst Biomed Engn, Ningbo Inst Ind Technol, 1219 Zhongguan West Rd, Ningbo 315201, Zhejiang, Peoples R China
4.Rice Univ, Elect & Comp Engn, 6100 Main St MS 378, Houston, TX 77005 USA
5.Elettra Sincrotrone Trieste Area Sci Pk, SS 14 Km 163,5, I-34012 Trieste, Italy
6.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, 72 Wenhua Rd, Shenyang 110016, Liaoning, Peoples R China
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Ponzellini, Paolo,Giovannini, Giorgia,Cattarin, Sandro,et al. Metallic Nanoporous Aluminum-Magnesium Alloy for UV-Enhanced Spectroscopy[J]. JOURNAL OF PHYSICAL CHEMISTRY C,2019,123(33):20287-20296.
APA Ponzellini, Paolo.,Giovannini, Giorgia.,Cattarin, Sandro.,Zaccaria, Remo Proietti.,Marras, Sergio.,...&Garoli, Denis.(2019).Metallic Nanoporous Aluminum-Magnesium Alloy for UV-Enhanced Spectroscopy.JOURNAL OF PHYSICAL CHEMISTRY C,123(33),20287-20296.
MLA Ponzellini, Paolo,et al."Metallic Nanoporous Aluminum-Magnesium Alloy for UV-Enhanced Spectroscopy".JOURNAL OF PHYSICAL CHEMISTRY C 123.33(2019):20287-20296.
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