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Factors of Kinetics Processes in Lithium-Sulfur Reactions
Tang, Xiaonan1,2; Xu, Zichen1; Sun, Zhenhua2,3; Zhou, Jin1; Wu, Xiaozhong1; Lin, Hongtao1; Rong, Junfeng4; Zhuo, Shuping1; Li, Feng2,3
Corresponding AuthorZhuo, Shuping(zhuosp_academic@yahoo.com) ; Li, Feng(fli@imr.ac.cn)
2019-09-26
Source PublicationENERGY TECHNOLOGY
ISSN2194-4288
Pages17
AbstractLithium-Sulfur (Li-S) batteries are among the most promising next-generation secondary battery technologies due to their high theoretical energy density. However, the Li-S reaction is a multistep process and a solid-liquid-solid phase transition process, relating to complex reaction kinetics. Moreover, the poor conductivity of sulfur hinders effective electron transport, and large volume expansion leads to electrode pulverization, causing the electrode to lose effective electrical contact, which decreases the kinetics. In this review, the factors influencing kinetics processes in Li-S electrochemistry are reviewed, starting from the design of sulfur host materials, along with electrode structure. Then, the cell design including electrolyte, interlayer, etc., is discussed further. Finally, insights on how to improve the kinetics are provided, which is expected to provide direction for further kinetic investigation of Li-S batteries.
Keywordcell design electrode structures kinetics process lithium-sulfur batteries sulfur host materials
Funding OrganizationNational Key R&D Program of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of Chinese Academy of Sciences ; Youth Innovation Promotion Association of the Chinese Academy of Sciences ; Natural Science Foundation of Shandong Province ; China Petrochemical Cooperation
DOI10.1002/ente.201900574
Indexed BySCI
Language英语
Funding ProjectNational Key R&D Program of China[2016YFB0100100] ; National Key R&D Program of China[2016YFA0200100] ; National Natural Science Foundation of China[51525206] ; National Natural Science Foundation of China[21576159] ; National Natural Science Foundation of China[21576158] ; National Natural Science Foundation of China[51521091] ; National Natural Science Foundation of China[51972313] ; Strategic Priority Research Program of Chinese Academy of Sciences[XDA22010602] ; Youth Innovation Promotion Association of the Chinese Academy of Sciences[2015150] ; Natural Science Foundation of Shandong Province[ZR2017JL014] ; China Petrochemical Cooperation[218025]
WOS Research AreaEnergy & Fuels
WOS SubjectEnergy & Fuels
WOS IDWOS:000487781800001
PublisherWILEY-V C H VERLAG GMBH
Citation statistics
Cited Times:6[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/135475
Collection中国科学院金属研究所
Corresponding AuthorZhuo, Shuping; Li, Feng
Affiliation1.Shandong Univ Technol, Sch Chem Engn, Zibo 255049, Peoples R China
2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Liaoning, Peoples R China
3.Univ Sci & Technol China, Sch Mat Sci & Engn, 72 Wenhua Rd, Shenyang 110016, Liaoning, Peoples R China
4.Sinopec, Res Inst Petr Proc, Beijing 100083, Peoples R China
Recommended Citation
GB/T 7714
Tang, Xiaonan,Xu, Zichen,Sun, Zhenhua,et al. Factors of Kinetics Processes in Lithium-Sulfur Reactions[J]. ENERGY TECHNOLOGY,2019:17.
APA Tang, Xiaonan.,Xu, Zichen.,Sun, Zhenhua.,Zhou, Jin.,Wu, Xiaozhong.,...&Li, Feng.(2019).Factors of Kinetics Processes in Lithium-Sulfur Reactions.ENERGY TECHNOLOGY,17.
MLA Tang, Xiaonan,et al."Factors of Kinetics Processes in Lithium-Sulfur Reactions".ENERGY TECHNOLOGY (2019):17.
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