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Electrospun carbon nanofibers with MnS sulfiphilic sites as efficient polysulfide barriers for high-performance wide-temperature-range Li-S batteries
Wang, Xin1; Zhao, Xiaosen1; Ma, Chenhui1; Yang, Zhenzhen1,4; Chen, Gang1; Wang, Lei2; Yue, Huijuan3; Zhang, Dong1; Sun, Zhenhua4
Corresponding AuthorZhang, Dong(dongzhang@jlu.edu.cn) ; Sun, Zhenhua(zhsun@imr.ac.cn)
2020-01-21
Source PublicationJOURNAL OF MATERIALS CHEMISTRY A
ISSN2050-7488
Volume8Issue:3Pages:1212-1220
AbstractLithium-sulfur (Li-S) batteries have the advantages of high theoretical capacity and energy density, which are considered as promising for future energy storage. Besides, the high gravimetric energy density makes Li-S batteries more suitable as power sources for apparatuses such as high-altitude drones and space vehicles. For these applications, the batteries should have a low self-discharge and a wide temperature range. Herein, we introduce carbon nanofibers with MnS sulfiphilic sites as flexible interlayers into Li-S batteries, reducing the shuttle effect and accelerating the reaction kinetics through physical inhibition, chemical adsorption and conversion that promote synergy. The self-discharge of the cell is significantly weakened. The voltage is maintained at 2.37 V during 150 hours resting after 20 cycles. For a sulfur loading of 2 mg cm(-2), the capacity is as high as 714 mA h g(-1) after 400 cycles at 1C at room temperature. Besides, the operating temperature of the cell is broadened. At 55 degrees C and 0 degrees C, the capacity can be stabilized at 894 mA h g(-1) and 853 mA h g(-1) after 100 cycles at 0.5C, respectively. This work can gain wide research interest toward lithium-sulfur batteries for applications in extreme environments.
Funding Organization973 project ; National Natural Science Foundation of China ; S&T Development Program of Jilin Province ; Jilin Provincial Department of Education 13th Five-Year scientific research project ; Youth Innovation Promotion Association of the Chinese Academy of Sciences ; China Petrochemical Cooperation
DOI10.1039/c9ta12137d
Indexed BySCI
Language英语
Funding Project973 project[2015CB251103] ; National Natural Science Foundation of China[51972313] ; National Natural Science Foundation of China[21771086] ; S&T Development Program of Jilin Province[20160101320JC] ; S&T Development Program of Jilin Province[20180101293JC] ; Jilin Provincial Department of Education 13th Five-Year scientific research project[JJKH20180116KJ] ; Youth Innovation Promotion Association of the Chinese Academy of Sciences[2015150] ; China Petrochemical Cooperation[218025]
WOS Research AreaChemistry ; Energy & Fuels ; Materials Science
WOS SubjectChemistry, Physical ; Energy & Fuels ; Materials Science, Multidisciplinary
WOS IDWOS:000508855700028
PublisherROYAL SOC CHEMISTRY
Citation statistics
Cited Times:15[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/136642
Collection中国科学院金属研究所
Corresponding AuthorZhang, Dong; Sun, Zhenhua
Affiliation1.Jilin Univ, Coll Phys, Key Lab Phys & Technol Adv Batteries, Minist Educ, Changchun 130012, Jilin, Peoples R China
2.Qingdao Univ Sci & Technol, Coll Chem & Mol Engn, Key Lab Ecochem Engn, Minist Educ, Qingdao 266042, Shandong, Peoples R China
3.Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Jilin, Peoples R China
4.Chinese Acad Sci, Shenyang Natl Lab Mat Sci, Inst Met Res, Shenyang 110016, Liaoning, Peoples R China
Recommended Citation
GB/T 7714
Wang, Xin,Zhao, Xiaosen,Ma, Chenhui,et al. Electrospun carbon nanofibers with MnS sulfiphilic sites as efficient polysulfide barriers for high-performance wide-temperature-range Li-S batteries[J]. JOURNAL OF MATERIALS CHEMISTRY A,2020,8(3):1212-1220.
APA Wang, Xin.,Zhao, Xiaosen.,Ma, Chenhui.,Yang, Zhenzhen.,Chen, Gang.,...&Sun, Zhenhua.(2020).Electrospun carbon nanofibers with MnS sulfiphilic sites as efficient polysulfide barriers for high-performance wide-temperature-range Li-S batteries.JOURNAL OF MATERIALS CHEMISTRY A,8(3),1212-1220.
MLA Wang, Xin,et al."Electrospun carbon nanofibers with MnS sulfiphilic sites as efficient polysulfide barriers for high-performance wide-temperature-range Li-S batteries".JOURNAL OF MATERIALS CHEMISTRY A 8.3(2020):1212-1220.
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