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Tuning the interlayer spacing of graphene laminate films for efficient pore utilization towards compact capacitive energy storage
Li, Zhuangnan1,2; Gadipelli, Srinivas3,4; Li, Hucheng2,5; Howard, Christopher A.6; Brett, Dan J. L.3; Shearing, Paul R.3; Guo, Zhengxiao1,7,8,9; Parkin, Ivan P.1; Li, Feng2,5
Corresponding AuthorGuo, Zhengxiao(z.x.guo@ucl.ac.uk) ; Parkin, Ivan P.(i.p.parkin@ucl.ac.uk) ; Li, Feng(fli@imr.ac.cn)
2020-02-01
Source PublicationNATURE ENERGY
ISSN2058-7546
Volume5Issue:2Pages:160-168
AbstractThe volumetric performance of supercapacitors needs to be improved, but the usual trade-off between porosity and density is a problem. Here the authors develop a graphene laminate film with tunable porosity that leads to a volumetric energy density of 88.1 Wh l(-1) at the device level. Supercapacitors have shown extraordinary promise for miniaturized electronics and electric vehicles, but are usually limited by electrodes with rather low volumetric performance, which is largely due to the inefficient utilization of pores in charge storage. Herein, we design a freestanding graphene laminate film electrode with highly efficient pore utilization for compact capacitive energy storage. The interlayer spacing of this film can be precisely adjusted, which enables a tunable porosity. By systematically tailoring the pore size for the electrolyte ions, pores are utilized optimally and thereby the volumetric capacitance is maximized. Consequently, the fabricated supercapacitor delivers a stack volumetric energy density of 88.1 Wh l(-1) in an ionic liquid electrolyte, representing a critical breakthrough for optimizing the porosity towards compact energy storage. Moreover, the optimized film electrode is assembled into an ionogel-based, all-solid-state, flexible smart device with multiple optional outputs and superior stability, demonstrating enormous potential as a portable power supply in practical applications.
Funding OrganizationNational Science Foundation of China ; Ministry of Science and Technology of China ; Strategic Priority Research Programme of Chinese Academy of Science ; Key Research Programme of the Chinese Academy of Sciences ; EPSRC ; Royal Academy of Engineering
DOI10.1038/s41560-020-0560-6
Indexed BySCI
Language英语
Funding ProjectNational Science Foundation of China[51525206] ; National Science Foundation of China[51521091] ; National Science Foundation of China[51372253] ; Ministry of Science and Technology of China[2016YFA0200100] ; Ministry of Science and Technology of China[2016YFB0100100] ; Strategic Priority Research Programme of Chinese Academy of Science[XDA22010602] ; Key Research Programme of the Chinese Academy of Sciences[KGZD-EW-T06] ; EPSRC[EP/R020973/1] ; EPSRC[EP/P009050/1] ; EPSRC[EP/L018330/1] ; EPSRC[EP/K002252/1] ; EPSRC[EP/M009394/1] ; Royal Academy of Engineering
WOS Research AreaEnergy & Fuels ; Materials Science
WOS SubjectEnergy & Fuels ; Materials Science, Multidisciplinary
WOS IDWOS:000514052800001
PublisherNATURE PUBLISHING GROUP
Citation statistics
Cited Times:116[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/137325
Collection中国科学院金属研究所
Corresponding AuthorGuo, Zhengxiao; Parkin, Ivan P.; Li, Feng
Affiliation1.UCL, Dept Chem, London, England
2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang, Peoples R China
3.UCL, Dept Chem Engn, London, England
4.Sichuan Univ, Coll Phys, Chengdu, Peoples R China
5.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang, Peoples R China
6.UCL, Dept Phys & Astron, London, England
7.Univ Hong Kong, Dept Chem, Hong Kong, Peoples R China
8.Univ Hong Kong, Dept Mech Engn, Hong Kong, Peoples R China
9.Univ Hong Kong, HKU Zhejiang Inst Res & Innovat, Hangzhou, Peoples R China
Recommended Citation
GB/T 7714
Li, Zhuangnan,Gadipelli, Srinivas,Li, Hucheng,et al. Tuning the interlayer spacing of graphene laminate films for efficient pore utilization towards compact capacitive energy storage[J]. NATURE ENERGY,2020,5(2):160-168.
APA Li, Zhuangnan.,Gadipelli, Srinivas.,Li, Hucheng.,Howard, Christopher A..,Brett, Dan J. L..,...&Li, Feng.(2020).Tuning the interlayer spacing of graphene laminate films for efficient pore utilization towards compact capacitive energy storage.NATURE ENERGY,5(2),160-168.
MLA Li, Zhuangnan,et al."Tuning the interlayer spacing of graphene laminate films for efficient pore utilization towards compact capacitive energy storage".NATURE ENERGY 5.2(2020):160-168.
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