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TEM study on the microstructure of the interface at the scale of nanometer formed between Cu-8 wt.% Ti melt and C/C preform
Zhang, K. X.1,2; Guo, X. S.3; Zhao, W. K.4; Zhang, F. Q.4; He, L. L.2
通讯作者He, L. L.(llhe@imr.ac.cn)
2020-05-01
发表期刊MATERIALS CHEMISTRY AND PHYSICS
ISSN0254-0584
卷号246页码:8
摘要Carbon/copper composites have been widely used in a variety of fields, for example electrical contact devices by taking advantages of both carbon and Cu simultaneously. However, the interfacial reaction and microstructure of these composites are not well known yet in the nanometer scale, especially involving the interaction between active alloy melt and carbon, which remains an important question in composites technology. In this study, we employ transmission electron microscopy (TEM) to investigate the interfacial microstructures, which are formed in the course of infiltration of carbon/carbon (C/C) composites preform by molten Cu-8 wt.% Ti at 1373 K. The results show that in the short-cut fiber web zone, there are two types of interfaces: (i) the mixture of fine-grained (FG) TiC and nano-sized Cu particles and (ii) a "Cu layer" with a thickness of no more than 500 nm at the pyrolytic carbon (PyC)/coarse-grained (CG) TiC interface. The main bonding mechanisms for the two interfaces are the formation of PyC/TiC and PyC/Cu2O interfaces, and the PyC/Cu2O interface, respectively. In the non-woven cloth zone, only Cu2O layer is found between Cu and PyC without any TiC layer due to the depletion of Ti.
关键词Metal matrix composites C/C preform Reactive melt infiltration Interfacial microstructure
资助者National Basic Research Program of China (973 Program)
DOI10.1016/j.matchemphys.2020.122795
收录类别SCI
语种英语
资助项目National Basic Research Program of China (973 Program)[2011CB605803]
WOS研究方向Materials Science
WOS类目Materials Science, Multidisciplinary
WOS记录号WOS:000525781100045
出版者ELSEVIER SCIENCE SA
引用统计
被引频次:7[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/138274
专题中国科学院金属研究所
通讯作者He, L. L.
作者单位1.Guilin Univ Elect Technol, Guangxi Collaborat Innovat Ctr Struct & Property, Sch Mat Sci & Engn, Guangxi Key Lab Informat Mat, Guilin 541004, Peoples R China
2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China
3.Pingxiang Univ, Engn & Technol Res Ctr Environm Protect Mat & Equ, Pingxiang 337055, Peoples R China
4.Cent South Univ, Sci & Technol High Strength Struct Mat Lab, Changsha 410083, Peoples R China
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Zhang, K. X.,Guo, X. S.,Zhao, W. K.,et al. TEM study on the microstructure of the interface at the scale of nanometer formed between Cu-8 wt.% Ti melt and C/C preform[J]. MATERIALS CHEMISTRY AND PHYSICS,2020,246:8.
APA Zhang, K. X.,Guo, X. S.,Zhao, W. K.,Zhang, F. Q.,&He, L. L..(2020).TEM study on the microstructure of the interface at the scale of nanometer formed between Cu-8 wt.% Ti melt and C/C preform.MATERIALS CHEMISTRY AND PHYSICS,246,8.
MLA Zhang, K. X.,et al."TEM study on the microstructure of the interface at the scale of nanometer formed between Cu-8 wt.% Ti melt and C/C preform".MATERIALS CHEMISTRY AND PHYSICS 246(2020):8.
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