A dopamine-based high redox potential catholyte for aqueous organic redox flow battery | |
Liu, Quanbing1,2; Li, Xiangrong1; Yan, Chuanwei1,2; Tang, Ao1,2 | |
Corresponding Author | Li, Xiangrong(xrli@imr.ac.cn) ; Tang, Ao(a.tang@imr.ac.cn) |
2020-06-01 | |
Source Publication | JOURNAL OF POWER SOURCES
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ISSN | 0378-7753 |
Volume | 460Pages:9 |
Abstract | Organic redox flow batteries with many technological advantages over conventional metal-based flow batteries represent a new generation flow battery technology for electric grid storage applications. Herein, we report a dopamine-based catholyte with a high redox potential of 0.77 V for aqueous organic redox flow batteries. In sulfuric acid, the dopamine exhibits an excellent combination of good electrochemical reversibility and high solubility up to 0.7 M, and undergoes a fast two-electron transfer redox reaction with a rate constant of 1.82 x 10(-3) cm s(-1). Paired with V3+/V2+, the dopamine-vanadium full cell delivers an average round-trip efficiency of 65% at 20 mA cm(-2) and achieves a capacity retention of 50% for 100 consecutive charge-discharge cycles. Moreover, an energy efficiency of 51.3% can be steadily realized at an increased current density of 60 mA cm(-2), while an enhanced capacity retention over extended 200 charge-discharge cycles is also observed by introducing saturated ammonium chloride into sulfuric acid. The proposed dopamine-based catholyte not only successfully offers a new alternative for aqueous organic redox flow batteries, but its performance can be also further promoted by rational molecule design and optimizations in mass transfer and electrode kinetics. |
Keyword | Organic aqueous flow battery Dopamine Organic catholyte Electrochemistry High redox potential |
Funding Organization | National Natural Science Foundation of China ; Institute of Metal Research, Chinese Academy of Sciences |
DOI | 10.1016/j.jpowsour.2020.228124 |
Indexed By | SCI |
Language | 英语 |
Funding Project | National Natural Science Foundation of China[21805290] ; National Natural Science Foundation of China[21706266] ; Institute of Metal Research, Chinese Academy of Sciences |
WOS Research Area | Chemistry ; Electrochemistry ; Energy & Fuels ; Materials Science |
WOS Subject | Chemistry, Physical ; Electrochemistry ; Energy & Fuels ; Materials Science, Multidisciplinary |
WOS ID | WOS:000528272200015 |
Publisher | ELSEVIER |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.imr.ac.cn/handle/321006/138656 |
Collection | 中国科学院金属研究所 |
Corresponding Author | Li, Xiangrong; Tang, Ao |
Affiliation | 1.Chinese Acad Sci, Inst Met Res, Shenyang, Peoples R China 2.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang, Peoples R China |
Recommended Citation GB/T 7714 | Liu, Quanbing,Li, Xiangrong,Yan, Chuanwei,et al. A dopamine-based high redox potential catholyte for aqueous organic redox flow battery[J]. JOURNAL OF POWER SOURCES,2020,460:9. |
APA | Liu, Quanbing,Li, Xiangrong,Yan, Chuanwei,&Tang, Ao.(2020).A dopamine-based high redox potential catholyte for aqueous organic redox flow battery.JOURNAL OF POWER SOURCES,460,9. |
MLA | Liu, Quanbing,et al."A dopamine-based high redox potential catholyte for aqueous organic redox flow battery".JOURNAL OF POWER SOURCES 460(2020):9. |
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