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Low-pressure-induced giant barocaloric effect in an all-d-metal Heusler Ni35.5Co14.5Mn35Ti15 magnetic shape memory alloy
Wei, Zhiyang1,2,3; Shen, Yi1,2,3; Zhang, Zhe4,5; Guo, Jianping1,2; Li, Bing4,5; Liu, Enke6; Zhang, Zhidong4,5; Liu, Jian1,2,3,7
Corresponding AuthorLi, Bing(bingli@imr.ac.cn) ; Liu, Jian(liujian@nimte.ac.cn)
2020-05-01
Source PublicationAPL MATERIALS
ISSN2166-532X
Volume8Issue:5Pages:9
AbstractThe clean and energy-efficient solid-state refrigeration based on magnetostructural phase transformation is a promising alternative technology for vapor-compression refrigeration. Herein, using a unique quasi-direct calorimetric method in a high hydrostatic pressure condition, we have studied the barocaloric effect for a Ni35.5Co14.5Mn35Ti15 all-d-metal Heusler alloy that undergoes a martensitic transformation accompanied by a large magnetization change. The martensitic transformation is found to be sensitive to either applied pressure or magnetic field with the large transformation temperature driving rates of 5.8 K kbar(-1) and 2.0 K T-1. Such a sensitive response to external stimuli originates from the large lattice/volume- and magnetization-discontinuity on the phase transformation. The Ni35.5Co14.5Mn35Ti15 alloy exhibits a large barocaloric effect with an isothermal entropy change of -24.2 J kg(-1) K(-1)and an adiabatic temperature change of 4.2 K, concomitant with a relatively low pressure change of 1 kbar, appearing to be the largest values among those of reported magnetic shape memory alloys. Moreover, by virtue of the strong magnetostructural coupling in the Ni35.5Co14.5Mn35Ti15 alloy, we propose a strategy of applying/releasing pressure and magnetic field in a proper sequence to eliminate the hysteresis and effectively enhance the reproducibility of the barocaloric effect.
Funding OrganizationNational Key Research and Development Program of China ; International Partnership Program of Chinese Academy of Sciences ; National Natural Science Foundation of China ; China Postdoctoral Science Foundation ; Major Fundamental Research Program of Chinese Academy of Sciences
DOI10.1063/5.0005021
Indexed BySCI
Language英语
Funding ProjectNational Key Research and Development Program of China[2017YFB0702703] ; International Partnership Program of Chinese Academy of Sciences[174433KYSB20180040] ; National Natural Science Foundation of China[51801225] ; National Natural Science Foundation of China[51771218] ; National Natural Science Foundation of China[51722106] ; China Postdoctoral Science Foundation[2018M632512] ; Major Fundamental Research Program of Chinese Academy of Sciences[ZDBS-LY-JSC002]
WOS Research AreaScience & Technology - Other Topics ; Materials Science ; Physics
WOS SubjectNanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied
WOS IDWOS:000531250300001
PublisherAMER INST PHYSICS
Citation statistics
Cited Times:17[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/138747
Collection中国科学院金属研究所
Corresponding AuthorLi, Bing; Liu, Jian
Affiliation1.Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, CAS Key Lab Magnet Mat & Devices, Ningbo 315201, Peoples R China
2.Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Zhejiang Prov Key Lab Magnet Mat & Applicat Techn, Ningbo 315201, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
4.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab SYNL Mat Sci, Shenyang 110016, Peoples R China
5.Univ Sci & Technol China, Sch Mat Sci & Engn, Hefei, Peoples R China
6.Chinese Acad Sci, Beijing Natl Lab Condensed Matter Phys, Inst Phys, State Key Lab Magnetism, Beijing 100190, Peoples R China
7.Univ Chinese Acad Sci, Ctr Mat Sci & Optoelect Engn, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Wei, Zhiyang,Shen, Yi,Zhang, Zhe,et al. Low-pressure-induced giant barocaloric effect in an all-d-metal Heusler Ni35.5Co14.5Mn35Ti15 magnetic shape memory alloy[J]. APL MATERIALS,2020,8(5):9.
APA Wei, Zhiyang.,Shen, Yi.,Zhang, Zhe.,Guo, Jianping.,Li, Bing.,...&Liu, Jian.(2020).Low-pressure-induced giant barocaloric effect in an all-d-metal Heusler Ni35.5Co14.5Mn35Ti15 magnetic shape memory alloy.APL MATERIALS,8(5),9.
MLA Wei, Zhiyang,et al."Low-pressure-induced giant barocaloric effect in an all-d-metal Heusler Ni35.5Co14.5Mn35Ti15 magnetic shape memory alloy".APL MATERIALS 8.5(2020):9.
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