| Enhanced electromagnetic wave absorption of hybrid-architectures Co@SiOxC | |
| Ge, Jianwen1; Cui, Yu2; Liu, Li1; Li, Rui1; Meng, Fandi1; Wang, Fuhui1 | |
| Corresponding Author | Liu, Li(liuli@mail.neu.edu.cn) |
| 2020-08-05 | |
| Source Publication | JOURNAL OF ALLOYS AND COMPOUNDS
 |
| ISSN | 0925-8388 |
| Volume | 831Pages:12 |
| Abstract | Rational design on the well wrapped core-shell microstructure of Co@SiOxC composites was successfully conducted through reduction process of cobalt, efficient condensation reaction of KH-550 silane coupling agent as well as high temperature calcination. The SiOxC shell possessed 3D cross-linked network structure consisting of dielectric carbon and silicon composition for optimal electromagnetic matching. The microstructure, morphology, elements distribution, electromagnetic property and microwave absorption performance were fully characterized, respectively. This SiOxC shell effectively inhibited the agglomeration of cobalt particles, and regulated the complex electromagnetic parameters by decreasing permittivity and introducing polarization relaxation, all of which determined the efficient reflection loss with RLmin value of -60.3 dB at 16.2 GHz and matching thickness of only 2.05 mm. Meanwhile, the effective absorption band is up to 7.1 GHz at 2.3 mm. By optimizing of core-shell structure and material components, the high-absorption performance was obtained through impedance matching, multi-interfacial polarizations, dipole (or defects) polarization and magnetic loss. Therefore, the Co@ SiOxC composites present a facile and promising route toward the design of large-scale-preparation and excellent microwave absorbing materials. (C) 2020 Elsevier B.V. All rights reserved. |
| Keyword | Co@SiOxC composites KH-550 Carbon Microwave absorption performance |
| Funding Organization | National Natural Science Foundation of China ; Fundamental Research Funds for the Central Universities ; Liao Ning Revitalization Talents Program |
| DOI | 10.1016/j.jallcom.2020.154442 |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | National Natural Science Foundation of China[51622106] ; Fundamental Research Funds for the Central Universities[2017YFB0702303] ; Liao Ning Revitalization Talents Program[XLYC1807076] |
| WOS Research Area | Chemistry ; Materials Science ; Metallurgy & Metallurgical Engineering |
| WOS Subject | Chemistry, Physical ; Materials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering |
| WOS ID | WOS:000531727400004 |
| Publisher | ELSEVIER SCIENCE SA |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.imr.ac.cn/handle/321006/138826 |
| Collection | 中国科学院金属研究所 |
| Corresponding Author | Liu, Li |
| Affiliation | 1.Northeastern Univ, Shenyang Natl Lab Mat Sci, Shenyang 110819, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang 110016, Peoples R China |
| Recommended Citation GB/T 7714 | Ge, Jianwen,Cui, Yu,Liu, Li,et al. Enhanced electromagnetic wave absorption of hybrid-architectures Co@SiOxC[J]. JOURNAL OF ALLOYS AND COMPOUNDS,2020,831:12. |
| APA | Ge, Jianwen,Cui, Yu,Liu, Li,Li, Rui,Meng, Fandi,&Wang, Fuhui.(2020).Enhanced electromagnetic wave absorption of hybrid-architectures Co@SiOxC.JOURNAL OF ALLOYS AND COMPOUNDS,831,12. |
| MLA | Ge, Jianwen,et al."Enhanced electromagnetic wave absorption of hybrid-architectures Co@SiOxC".JOURNAL OF ALLOYS AND COMPOUNDS 831(2020):12. |
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