| Fabrication of mesoporous MOF nanosheets via surfactant-template method for C-S coupling reactions | |
| Wang, Sha1; Wang, Tieqiang1; Zheng, Huayu1; Fan, Fuqiang1; Gu, Zhida1; He, Wenxiu1; Zhang, Bing1; Shao, Lei1; Chen, Huan1; Li, Yunong1; Zhang, Xuemin1; Zhang, Liying1; Fu, Yu1; Qi, Wei2 | |
| Corresponding Author | Fu, Yu(fuyu@mail.neu.edu.cn) ; Qi, Wei(wqi@imr.ac.cn) |
| 2020-08-15 | |
| Source Publication | MICROPOROUS AND MESOPOROUS MATERIALS
 |
| ISSN | 1387-1811 |
| Volume | 303Pages:7 |
| Abstract | Pore size enlargement plays a vital role in the catalytic applications of metal-organic frameworks (MOFs). There is still a big challenge in achieving two-dimension (2D) ultrathin MOF nanosheets with controllable meso-pores, although it has huge demanding. In this work, various kinds of mesoporous MOF nanosheets with uniform mesopore channels and crystallized microporous frameworks were constructed using surfactants (cetyltrimethyl ammonium bromide, CTAB) as sacrificial templates. CTAB was firstly introduced into MOF nanosheet structure during the formation of MOF nanosheets, and mesopores could be produced by removing CTAB from MOF nanosheets. Remarkably, the integration of ultrathin nanosheets and mesoporous property enables mesoporous CuBDC nanosheets enhanced catalytic activity for C-S cross-coupling reaction, providing a new concept and feasible strategy for highly efficient mesoporous MOF catalyst synthesis. |
| Keyword | Mesoporous 2D MOF nanosheets Ultrathin C-S cross-coupling reaction |
| Funding Organization | National Natural Science Foundation of China ; Fundamental Research Funds for the Central Universities ; Open Project of State Key Laboratory of Supramolecular Structure and Materials |
| DOI | 10.1016/j.micromeso.2020.110254 |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | National Natural Science Foundation of China[21761132010] ; National Natural Science Foundation of China[91645114] ; National Natural Science Foundation of China[21573256] ; National Natural Science Foundation of China[21805028] ; National Natural Science Foundation of China[21805029] ; Fundamental Research Funds for the Central Universities[N160504002] ; Fundamental Research Funds for the Central Universities[N170503010] ; Fundamental Research Funds for the Central Universities[N180705004] ; Fundamental Research Funds for the Central Universities[N180504005] ; Fundamental Research Funds for the Central Universities[N180504007] ; Open Project of State Key Laboratory of Supramolecular Structure and Materials[sklssm202008] ; Open Project of State Key Laboratory of Supramolecular Structure and Materials[sklssm202042] ; Open Project of State Key Laboratory of Supramolecular Structure and Materials[sklssm202027] |
| WOS Research Area | Chemistry ; Science & Technology - Other Topics ; Materials Science |
| WOS Subject | Chemistry, Applied ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary |
| WOS ID | WOS:000535938200015 |
| Publisher | ELSEVIER |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.imr.ac.cn/handle/321006/139038 |
| Collection | 中国科学院金属研究所 |
| Corresponding Author | Fu, Yu; Qi, Wei |
| Affiliation | 1.Northeastern Univ, Coll Sci, Dept Chem, Shenyang 110819, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China |
| Recommended Citation GB/T 7714 | Wang, Sha,Wang, Tieqiang,Zheng, Huayu,et al. Fabrication of mesoporous MOF nanosheets via surfactant-template method for C-S coupling reactions[J]. MICROPOROUS AND MESOPOROUS MATERIALS,2020,303:7. |
| APA | Wang, Sha.,Wang, Tieqiang.,Zheng, Huayu.,Fan, Fuqiang.,Gu, Zhida.,...&Qi, Wei.(2020).Fabrication of mesoporous MOF nanosheets via surfactant-template method for C-S coupling reactions.MICROPOROUS AND MESOPOROUS MATERIALS,303,7. |
| MLA | Wang, Sha,et al."Fabrication of mesoporous MOF nanosheets via surfactant-template method for C-S coupling reactions".MICROPOROUS AND MESOPOROUS MATERIALS 303(2020):7. |
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