Fabrication of mesoporous MOF nanosheets via surfactant-template method for C-S coupling reactions

doi:10.1016/j.micromeso.2020.110254

IMR OpenIR

	Fabrication of mesoporous MOF nanosheets via surfactant-template method for C-S coupling reactions
	Wang, Sha 1; Wang, Tieqiang 1; Zheng, Huayu 1; Fan, Fuqiang 1; Gu, Zhida 1; He, Wenxiu 1; Zhang, Bing 1; Shao, Lei 1; Chen, Huan 1; Li, Yunong 1; Zhang, Xuemin 1; Zhang, Liying 1; Fu, Yu 1; Qi, Wei 2
通讯作者	Fu, Yu(fuyu@mail.neu.edu.cn) ; Qi, Wei(wqi@imr.ac.cn)
	2020-08-15
发表期刊	MICROPOROUS AND MESOPOROUS MATERIALS
ISSN	1387-1811
卷号	303 页码:7
摘要	Pore size enlargement plays a vital role in the catalytic applications of metal-organic frameworks (MOFs). There is still a big challenge in achieving two-dimension (2D) ultrathin MOF nanosheets with controllable meso-pores, although it has huge demanding. In this work, various kinds of mesoporous MOF nanosheets with uniform mesopore channels and crystallized microporous frameworks were constructed using surfactants (cetyltrimethyl ammonium bromide, CTAB) as sacrificial templates. CTAB was firstly introduced into MOF nanosheet structure during the formation of MOF nanosheets, and mesopores could be produced by removing CTAB from MOF nanosheets. Remarkably, the integration of ultrathin nanosheets and mesoporous property enables mesoporous CuBDC nanosheets enhanced catalytic activity for C-S cross-coupling reaction, providing a new concept and feasible strategy for highly efficient mesoporous MOF catalyst synthesis.
关键词	Mesoporous 2D MOF nanosheets Ultrathin C-S cross-coupling reaction
资助者	National Natural Science Foundation of China ; Fundamental Research Funds for the Central Universities ; Open Project of State Key Laboratory of Supramolecular Structure and Materials
DOI	10.1016/j.micromeso.2020.110254
收录类别	SCI
语种	英语
资助项目	National Natural Science Foundation of China[21761132010] ; National Natural Science Foundation of China[91645114] ; National Natural Science Foundation of China[21573256] ; National Natural Science Foundation of China[21805028] ; National Natural Science Foundation of China[21805029] ; Fundamental Research Funds for the Central Universities[N160504002] ; Fundamental Research Funds for the Central Universities[N170503010] ; Fundamental Research Funds for the Central Universities[N180705004] ; Fundamental Research Funds for the Central Universities[N180504005] ; Fundamental Research Funds for the Central Universities[N180504007] ; Open Project of State Key Laboratory of Supramolecular Structure and Materials[sklssm202008] ; Open Project of State Key Laboratory of Supramolecular Structure and Materials[sklssm202042] ; Open Project of State Key Laboratory of Supramolecular Structure and Materials[sklssm202027]
WOS研究方向	Chemistry ; Science & Technology - Other Topics ; Materials Science
WOS类目	Chemistry, Applied ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
WOS记录号	WOS:000535938200015
出版者	ELSEVIER
引用统计	被引频次：19[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/139038
专题	中国科学院金属研究所
通讯作者	Fu, Yu; Qi, Wei
作者单位	1.Northeastern Univ, Coll Sci, Dept Chem, Shenyang 110819, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China
推荐引用方式 GB/T 7714	Wang, Sha,Wang, Tieqiang,Zheng, Huayu,et al. Fabrication of mesoporous MOF nanosheets via surfactant-template method for C-S coupling reactions[J]. MICROPOROUS AND MESOPOROUS MATERIALS,2020,303:7.
APA	Wang, Sha.,Wang, Tieqiang.,Zheng, Huayu.,Fan, Fuqiang.,Gu, Zhida.,...&Qi, Wei.(2020).Fabrication of mesoporous MOF nanosheets via surfactant-template method for C-S coupling reactions.MICROPOROUS AND MESOPOROUS MATERIALS,303,7.
MLA	Wang, Sha,et al."Fabrication of mesoporous MOF nanosheets via surfactant-template method for C-S coupling reactions".MICROPOROUS AND MESOPOROUS MATERIALS 303(2020):7.