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Effects of the Different Solid Deposits on the Corrosion Behavior of Pure Fe in Water Vapor at 500 degrees C
Tang, Yanbing1,2; Shen, Xinwang3; Liu, Zhihong3; Li, Ying1
通讯作者Li, Ying(liying@imr.ac.cn)
2020-09-11
发表期刊SCANNING
ISSN0161-0457
卷号2020页码:8
摘要A comprehensive corrosion investigation of pure Fe in an environment of solid sodium salt deposit (i.e., NaCl or Na2SO4) with mixtures of H2O and O(2)at 500 degrees C was conducted by mass gain measurement, X-ray diffraction (XRD), scanning electron microscope (SEM), potentiodynamic polarization, and electrochemical impedance spectroscopy (EIS). The results showed that corrosion rates were accelerated with solid NaCl or Na2SO4 deposit due to their reaction with the formed protective scale of Fe2O3 and subsequently resulted in its breakdown. The corrosion rate of pure Fe with solid NaCl is higher than that with solid Na2SO4 because of the lower activation energy (Ea) for chemical reaction of Fe in solid NaCl+H2O+O-2 (i.e., 140.5 kJ/mol) than that in solid Na2SO4+H2O+O-2 (i.e., 200.9 kJ/mol). Notably, the electrochemical corrosion rate of pure Fe with solid NaCl deposit,1.16x10(-4) A/cm(2), was a little lower than that with solid Na2SO4 deposit.
资助者National Natural Science Fund of China
DOI10.1155/2020/6280725
收录类别SCI
语种英语
资助项目National Natural Science Fund of China[51371181] ; National Natural Science Fund of China[51671198]
WOS研究方向Instruments & Instrumentation ; Microscopy
WOS类目Instruments & Instrumentation ; Microscopy
WOS记录号WOS:000574323400001
出版者WILEY-HINDAWI
引用统计
被引频次:1[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/140705
专题中国科学院金属研究所
通讯作者Li, Ying
作者单位1.Chinese Acad Sci, Inst Met Res, Shenyang 110016, Peoples R China
2.Jiangsu Univ Sci & Technol, Marine Equipment & Technol Inst, Zhenjiang 212003, Jiangsu, Peoples R China
3.Jiangsu Univ Sci & Technol, Sch Mat Sci & Technol, Zhenjiang 212003, Jiangsu, Peoples R China
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Tang, Yanbing,Shen, Xinwang,Liu, Zhihong,et al. Effects of the Different Solid Deposits on the Corrosion Behavior of Pure Fe in Water Vapor at 500 degrees C[J]. SCANNING,2020,2020:8.
APA Tang, Yanbing,Shen, Xinwang,Liu, Zhihong,&Li, Ying.(2020).Effects of the Different Solid Deposits on the Corrosion Behavior of Pure Fe in Water Vapor at 500 degrees C.SCANNING,2020,8.
MLA Tang, Yanbing,et al."Effects of the Different Solid Deposits on the Corrosion Behavior of Pure Fe in Water Vapor at 500 degrees C".SCANNING 2020(2020):8.
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