Effects of the Different Solid Deposits on the Corrosion Behavior of Pure Fe in Water Vapor at 500 degrees C | |
Tang, Yanbing1,2; Shen, Xinwang3; Liu, Zhihong3; Li, Ying1 | |
通讯作者 | Li, Ying(liying@imr.ac.cn) |
2020-09-11 | |
发表期刊 | SCANNING
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ISSN | 0161-0457 |
卷号 | 2020页码:8 |
摘要 | A comprehensive corrosion investigation of pure Fe in an environment of solid sodium salt deposit (i.e., NaCl or Na2SO4) with mixtures of H2O and O(2)at 500 degrees C was conducted by mass gain measurement, X-ray diffraction (XRD), scanning electron microscope (SEM), potentiodynamic polarization, and electrochemical impedance spectroscopy (EIS). The results showed that corrosion rates were accelerated with solid NaCl or Na2SO4 deposit due to their reaction with the formed protective scale of Fe2O3 and subsequently resulted in its breakdown. The corrosion rate of pure Fe with solid NaCl is higher than that with solid Na2SO4 because of the lower activation energy (Ea) for chemical reaction of Fe in solid NaCl+H2O+O-2 (i.e., 140.5 kJ/mol) than that in solid Na2SO4+H2O+O-2 (i.e., 200.9 kJ/mol). Notably, the electrochemical corrosion rate of pure Fe with solid NaCl deposit,1.16x10(-4) A/cm(2), was a little lower than that with solid Na2SO4 deposit. |
资助者 | National Natural Science Fund of China |
DOI | 10.1155/2020/6280725 |
收录类别 | SCI |
语种 | 英语 |
资助项目 | National Natural Science Fund of China[51371181] ; National Natural Science Fund of China[51671198] |
WOS研究方向 | Instruments & Instrumentation ; Microscopy |
WOS类目 | Instruments & Instrumentation ; Microscopy |
WOS记录号 | WOS:000574323400001 |
出版者 | WILEY-HINDAWI |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.imr.ac.cn/handle/321006/140705 |
专题 | 中国科学院金属研究所 |
通讯作者 | Li, Ying |
作者单位 | 1.Chinese Acad Sci, Inst Met Res, Shenyang 110016, Peoples R China 2.Jiangsu Univ Sci & Technol, Marine Equipment & Technol Inst, Zhenjiang 212003, Jiangsu, Peoples R China 3.Jiangsu Univ Sci & Technol, Sch Mat Sci & Technol, Zhenjiang 212003, Jiangsu, Peoples R China |
推荐引用方式 GB/T 7714 | Tang, Yanbing,Shen, Xinwang,Liu, Zhihong,et al. Effects of the Different Solid Deposits on the Corrosion Behavior of Pure Fe in Water Vapor at 500 degrees C[J]. SCANNING,2020,2020:8. |
APA | Tang, Yanbing,Shen, Xinwang,Liu, Zhihong,&Li, Ying.(2020).Effects of the Different Solid Deposits on the Corrosion Behavior of Pure Fe in Water Vapor at 500 degrees C.SCANNING,2020,8. |
MLA | Tang, Yanbing,et al."Effects of the Different Solid Deposits on the Corrosion Behavior of Pure Fe in Water Vapor at 500 degrees C".SCANNING 2020(2020):8. |
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