Effects of the Different Solid Deposits on the Corrosion Behavior of Pure Fe in Water Vapor at 500 degrees C | |
Tang, Yanbing1,2; Shen, Xinwang3; Liu, Zhihong3; Li, Ying1 | |
Corresponding Author | Li, Ying(liying@imr.ac.cn) |
2020-09-11 | |
Source Publication | SCANNING
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ISSN | 0161-0457 |
Volume | 2020Pages:8 |
Abstract | A comprehensive corrosion investigation of pure Fe in an environment of solid sodium salt deposit (i.e., NaCl or Na2SO4) with mixtures of H2O and O(2)at 500 degrees C was conducted by mass gain measurement, X-ray diffraction (XRD), scanning electron microscope (SEM), potentiodynamic polarization, and electrochemical impedance spectroscopy (EIS). The results showed that corrosion rates were accelerated with solid NaCl or Na2SO4 deposit due to their reaction with the formed protective scale of Fe2O3 and subsequently resulted in its breakdown. The corrosion rate of pure Fe with solid NaCl is higher than that with solid Na2SO4 because of the lower activation energy (Ea) for chemical reaction of Fe in solid NaCl+H2O+O-2 (i.e., 140.5 kJ/mol) than that in solid Na2SO4+H2O+O-2 (i.e., 200.9 kJ/mol). Notably, the electrochemical corrosion rate of pure Fe with solid NaCl deposit,1.16x10(-4) A/cm(2), was a little lower than that with solid Na2SO4 deposit. |
Funding Organization | National Natural Science Fund of China |
DOI | 10.1155/2020/6280725 |
Indexed By | SCI |
Language | 英语 |
Funding Project | National Natural Science Fund of China[51371181] ; National Natural Science Fund of China[51671198] |
WOS Research Area | Instruments & Instrumentation ; Microscopy |
WOS Subject | Instruments & Instrumentation ; Microscopy |
WOS ID | WOS:000574323400001 |
Publisher | WILEY-HINDAWI |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.imr.ac.cn/handle/321006/140705 |
Collection | 中国科学院金属研究所 |
Corresponding Author | Li, Ying |
Affiliation | 1.Chinese Acad Sci, Inst Met Res, Shenyang 110016, Peoples R China 2.Jiangsu Univ Sci & Technol, Marine Equipment & Technol Inst, Zhenjiang 212003, Jiangsu, Peoples R China 3.Jiangsu Univ Sci & Technol, Sch Mat Sci & Technol, Zhenjiang 212003, Jiangsu, Peoples R China |
Recommended Citation GB/T 7714 | Tang, Yanbing,Shen, Xinwang,Liu, Zhihong,et al. Effects of the Different Solid Deposits on the Corrosion Behavior of Pure Fe in Water Vapor at 500 degrees C[J]. SCANNING,2020,2020:8. |
APA | Tang, Yanbing,Shen, Xinwang,Liu, Zhihong,&Li, Ying.(2020).Effects of the Different Solid Deposits on the Corrosion Behavior of Pure Fe in Water Vapor at 500 degrees C.SCANNING,2020,8. |
MLA | Tang, Yanbing,et al."Effects of the Different Solid Deposits on the Corrosion Behavior of Pure Fe in Water Vapor at 500 degrees C".SCANNING 2020(2020):8. |
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