| Creation of N-C=O active groups on N-doped CNT as an efficient CarboCatalyst for solvent-free aerobic coupling of benzylamine | |
| Wei, Hua1,2,3,4; Ma, Ying2,5; Luo, Jingjie6; Wu, Kuang-Hsu1; Xie, Wei7; Wen, Guodong1; Chiang, Chao-Lung8; Yan, Wensheng9; Perathoner, Siglinda3,4; Centi, Gabriele3,4; Liu, Yuefeng2 | |
| Corresponding Author | Luo, Jingjie(jingjie.luo@dlut.edu.cn) ; Liu, Yuefeng(yuefeng.liu@dicp.ac.cn) |
| 2020-12-01 | |
| Source Publication | CARBON
 |
| ISSN | 0008-6223 |
| Volume | 170Pages:338-346 |
| Abstract | The creation of specific catalytic functionalities in the nanocarbon materials is an important approach to develop the metal-free nanocarbon materials (carbocatalysts). We report herein a functionalization strategy by treatment of N-doped carbon nanotubes (NCNT) with ozone/water to create oxygen groups nearby the N groups (N-C=O). These groups, different from those present in conventionally oxidized NCNT, show peculiar catalytic behavior. The N atom adjacent to carbonyl group (N-C=O) modifies the reactivity of carbonyl towards C-H activation and simultaneously activate O-2 molecule for bifunctionality. Efficient performance for oxidative coupling of benzylamine to imine (>99% imine selectivity) can be obtained under solvent-free conditions at ambient pressure. The benzylamine productivity reaches as high as 131.3 mmol m(-2) h(-1), which is the highest among any other reported carbon-based catalysts. This work not only highlights a sustainable strategy for tuned surface chemistry of carbon materials by using mild ozonation process, but also reports a novel green aerobic synthesis method of benzylamine using tailored metal-free carbon nanomaterials. (C) 2020 Elsevier Ltd. All rights reserved. |
| Keyword | Oxygenated functional groups Nitrogen/oxygen atoms co-doping H2O-Assisted ozone treatment Carbocatalyst Oxidative coupling reaction |
| Funding Organization | NSFC of China ; LiaoNing Revitalization Talents Program ; CAS Youth Innovation Promotion Association ; Talents Innovation Project of Dalian city ; SINCHEMJoint Doctorate programme selected under the Erasmus Mundus Action 1 Programme |
| DOI | 10.1016/j.carbon.2020.08.018 |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | NSFC of China[21802015] ; NSFC of China[21872144] ; NSFC of China[21606243] ; LiaoNing Revitalization Talents Program[XLYC1907053] ; CAS Youth Innovation Promotion Association[2018220] ; Talents Innovation Project of Dalian city[2017RQ032] ; Talents Innovation Project of Dalian city[2016RD04] ; SINCHEMJoint Doctorate programme selected under the Erasmus Mundus Action 1 Programme[FPA 2013-0037] |
| WOS Research Area | Chemistry ; Materials Science |
| WOS Subject | Chemistry, Physical ; Materials Science, Multidisciplinary |
| WOS ID | WOS:000579779800033 |
| Publisher | PERGAMON-ELSEVIER SCIENCE LTD |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.imr.ac.cn/handle/321006/141058 |
| Collection | 中国科学院金属研究所 |
| Corresponding Author | Luo, Jingjie; Liu, Yuefeng |
| Affiliation | 1.Chinese Acad Sci, Inst Met Res, 72 Wenhua Rd, Shenyang 110016, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy DNL, 457 Zhongshan Rd, Dalian 116023, Peoples R China 3.Univ Messina, Dept ChiBioFarAm, Vle F Stagno Dalcontres 31, I-98166 Messina, Italy 4.Univ Messina, Dept MIFT, Vle F Stagno Dalcontres 31, I-98166 Messina, Italy 5.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 6.Dalian Univ Technol, Sch Chem Engn, Panjin 124221, Peoples R China 7.Kyushu Univ, INAMORI Frontier Res Ctr, Nishi Ku, 744 Motooka, Fukuoka 8190395, Japan 8.Natl Synchrotron Radiat Res Ctr, Hsinchu Sci Pk, Hsinchu 30076, Taiwan 9.Univ Sci & Technol China, Natl Synchrotron Radiat Lab, Hefei 230029, Peoples R China |
| Recommended Citation GB/T 7714 | Wei, Hua,Ma, Ying,Luo, Jingjie,et al. Creation of N-C=O active groups on N-doped CNT as an efficient CarboCatalyst for solvent-free aerobic coupling of benzylamine[J]. CARBON,2020,170:338-346. |
| APA | Wei, Hua.,Ma, Ying.,Luo, Jingjie.,Wu, Kuang-Hsu.,Xie, Wei.,...&Liu, Yuefeng.(2020).Creation of N-C=O active groups on N-doped CNT as an efficient CarboCatalyst for solvent-free aerobic coupling of benzylamine.CARBON,170,338-346. |
| MLA | Wei, Hua,et al."Creation of N-C=O active groups on N-doped CNT as an efficient CarboCatalyst for solvent-free aerobic coupling of benzylamine".CARBON 170(2020):338-346. |
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